ChemicalBook > Product Catalog >Organic Chemistry >Amides >Naphthenic amines derivatives >2-Aminodiphenylamine
2-Aminodiphenylamine
- CAS No.
- 534-85-0
- Chemical Name:
- 2-Aminodiphenylamine
- Synonyms
- C.I. 50005;o-Semidine;TIMTEC-BB SBB000244;O-AMINODIPHENYLAMINE;2-AMINODIPHENYLAMINE;LABOTEST-BB LT00080731;N-Phenyl-2-aminoaniline;ORTHO-AMINODIPHENYLAMINE;N-(2-aminophenyl)aniline;2-Aminodiphenylamine >
- CBNumber:
- CB4767341
- Molecular Formula:
- C12H12N2
- Molecular Weight:
- 184.24
- MOL File:
- 534-85-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/24 17:31:20
| Melting point | 77-80 °C(lit.) |
|---|---|
| Boiling point | 108 °C / 0.4mmHg |
| Density | 1.1160 (rough estimate) |
| refractive index | 1.6266 (estimate) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 4.45±0.10(Predicted) |
| form | Crystalline Powder |
| color | Pink-violet or gray-brown |
| Water Solubility | Soluble in acetone, chloroform and benzene. Insoluble in water. |
| BRN | 908984 |
| InChIKey | NFCPRRWCTNLGSN-UHFFFAOYSA-N |
| CAS DataBase Reference | 534-85-0(CAS DataBase Reference) |
| NIST Chemistry Reference | 1,2-Benzenediamine, n-phenyl-(534-85-0) |
| EPA Substance Registry System | 1,2-Benzenediamine, N-phenyl- (534-85-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H332-H315 | |||||||||
| Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P304+P340+P312 | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/22-38-36/37/38 | |||||||||
| Safety Statements | 22-24-28A-26 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29215990 | |||||||||
| NFPA 704 |
|
2-Aminodiphenylamine price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | P28352 | N-Phenyl-o-phenylenediamine 98% | 534-85-0 | 10G | ₹7978.03 | 2022-06-14 | Buy |
| TCI Chemicals (India) | A2129 | 2-Aminodiphenylamine min. 98.0 % | 534-85-0 | 5G | ₹3100 | 2022-05-26 | Buy |
| TCI Chemicals (India) | A2129 | 2-Aminodiphenylamine min. 98.0 % | 534-85-0 | 25G | ₹8800 | 2022-05-26 | Buy |
| ALFA India | ALF-L11616-14 | N-Phenyl-o-phenylenediamine, 98% | 534-85-0 | 25g | ₹11418 | 2022-05-26 | Buy |
| ALFA India | ALF-L11616-06 | N-Phenyl-o-phenylenediamine, 98% | 534-85-0 | 5g | ₹3257 | 2022-05-26 | Buy |
2-Aminodiphenylamine Chemical Properties,Uses,Production
Chemical Properties
White to Light yellow to Light red powder to crystal
Uses
N-Phenyl-o-phenylenediamine is also used as an intermediate in organic synthesis and pharmaceuticals.
Synthesis
The synthesis of 2-Aminodiphenylamine is as folliows:
Reaction flask was added 0.108 g of o-phenylenediamine (1 mmol), phenylhydrazine0.216 g (2 mmol), CuPc 0.058 Ke (0.1 mmol), Cu (OAc) 2 0.02 g (0.1 mmol) and 10 ml ofacetonitrile, 15 °C reaction; TLC until the reaction was followed completely finished;the crude product after the reaction was subjected to column chromatography (petroleumether: ethyl acetate = 100: 1) to give the desired product (71% yield).
storage
Keep container tightly closed. Store in cool, dry conditions in well sealed containers. It is sensitive to light. Store at room temperature. Incompatible with acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.
Purification Methods
Crystallise the amine from H2O. [Beilstein 13 IV 43.]
2-Aminodiphenylamine Preparation Products And Raw materials
Raw materials
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Global( 273)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| SynthoCascade Research Laboratories | +91-9440962500 +91-9440962500 | Telangana, India | 284 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Survival Technologies Pvt Ltd | +91 (22) 4212-8221 | New Delhi, India | 290 | 50 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Chemsigma International Co., Ltd. | +86-18136843612 +86-19951791336 | China | 1229 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| SynthoCascade Research Laboratories | 58 |
| Reax Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Central Drug House(P) Ltd. | 58 |
| Survival Technologies Pvt Ltd | 50 |
| A.J Chemicals | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Chemsigma International Co., Ltd. | 58 |
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2-Aminodiphenylamine >
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534-85-0
535-85-0
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