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4-Aminodiphenylamine

4-Aminodiphenylamine Structure
CAS No.
101-54-2
Chemical Name:
4-Aminodiphenylamine
Synonyms
N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
CBNumber:
CB9418967
Molecular Formula:
C12H12N2
Molecular Weight:
184.24
MOL File:
101-54-2.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

4-Aminodiphenylamine Properties

Melting point 69 °C
Boiling point 354 °C
Density 1.09
vapor pressure 1 hPa
refractive index 1.6266 (estimate)
Flash point 193°C
storage temp. Store below +30°C.
solubility ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
Colour Index 37240
pka 5.20±0.10(Predicted)
form Liquid
color Clear
PH 8.9 (0.5g/l, H2O, 20℃)
Water Solubility Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
BRN 908935
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
LogP 1.82 at 20℃ and pH7
Dissociation constant 5.45-5.47 at 20℃
CAS DataBase Reference 101-54-2(CAS DataBase Reference)
NIST Chemistry Reference 1,4-Benzenediamine, N-phenyl-(101-54-2)
EPA Substance Registry System p-Aminodiphenylamine (101-54-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H317-H319-H411
Precautionary statements  P261-P273-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi,N
Risk Statements  22-36-43-42/43-36/37/38-20/22-50/53
Safety Statements  26-36-45-36/37/39-61-60-36/37
RIDADR  UN3077
WGK Germany  3
RTECS  ST3150000
8
Autoignition Temperature >500 °C
Hazard Note  Irritant
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29215990
Toxicity LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg
NFPA 704
1
2 0

4-Aminodiphenylamine price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 241393 N-Phenyl-p-phenylenediamine 98% 101-54-2 100G ₹2089.23 2022-06-14 Buy
Sigma-Aldrich(India) 241393 N-Phenyl-p-phenylenediamine 98% 101-54-2 100G ₹2089.23 2022-06-14 Buy
Sigma-Aldrich 241393 N-Phenyl-p-phenylenediamine 98% 101-54-2 1KG ₹7133.68 2022-06-14 Buy
Sigma-Aldrich(India) 241393 N-Phenyl-p-phenylenediamine 98% 101-54-2 1KG ₹7133.68 2022-06-14 Buy
ALFA India ALF-B23867-30 N-Phenyl-p-phenylenediamine, 98% 101-54-2 250g ₹3076 2022-05-26 Buy
Product number Packaging Price Buy
241393 100G ₹2089.23 Buy
241393 100G ₹2089.23 Buy
241393 1KG ₹7133.68 Buy
241393 1KG ₹7133.68 Buy
ALF-B23867-30 250g ₹3076 Buy

4-Aminodiphenylamine Chemical Properties,Uses,Production

Description

p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.

Chemical Properties

Dark grey flake

Uses

4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.

Definition

ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.

General Description

Odorless purple-black solid or flake or dark purple chips.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.

Fire Hazard

4-Aminodiphenylamine is combustible.

Contact allergens

This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.

Purification Methods

It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]

Global( 243)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Krishna Industries +91-7922822554 +91-7922822554 Gujarat, India 235 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Central Drug House(P) Ltd. 91-11-49404040 New Delhi, India 6160 58 Inquiry
A. B. Enterprises +91-8048077585 Mumbai, India 1396 58 Inquiry
Krishna Industries 08047651231 Ahmedabad, India 64 58 Inquiry
ALLCHEM LIFESCIENCE PVT. LTD +91 957 472 2211 New Delhi, India 322 58 Inquiry
Oxford laboratories +91 250 239 0032 Maharashtra, India 652 58 Inquiry
Acna Black DF Base 4-Aminodiphenylamine, N1-Phenylbenzene-1,4-diamine 4-Aminodiphenylamine N-Phenyl-1,4-phenylenediamine Variamine Blue RT 4-AMINODIPHENYLAMINE FOR SYNTHESIS N- phenyltwo of benzeneaMine Azoic Diazo CoMponent 22, 98.0%(LC&T N-Phenyl-p-phenylenediamine N-Phenyl-p-phenylenediamine Variamine Blue RT Base Azoic Diazo Component 22 4-(Phenylamino)aniline 4-amino-diphenylamin Fast Blue R Salt fastbluersalt FastblueRTbase Luxan Black R luxanblackr n-(4-aminophenyl)aniline n-(4-aminophenyl)aniline(ci n-(4-aminophenyl)aniline(ci76085) n,4’-bianiline N-4'-Bianiline Naphthoelan Navy Blue naphthoelannavyblue NCI-C02233 N-Fenyl-p-fenylendiamin n-phenyl-4-benzenediamine N-Phenyl-p-aminoaniline n-phenyl-p-phenylenediamin Oxy Acid Black Base oxyacidblackbase p-(Phenylamino)aniline p-Aminodifenylamin p-aminodifenylamin(czech) p-amino-diphenylamin p-Anilinoaniline Peltol BR Peltol BR II peltolbr peltolbrii p-Phenylenediamine, N-phenyl- p-Semidine rodolgraybbase acnablackdfbase Azosalt R azosaltr Benzenediamine, N-phenyl- blackbasep C.I. 76085 C.I. Azoic Diazo Component 22 C.I. Developer 15 C.I. Oxidation Base 2 c.i.76085 c.i.azoicdiazocomponent22 c.i.developer15 Semidin Semidine UBOB Variamine Blue Salt RT c.i.oxidationbase2