4-Aminodiphenylamine
- CAS No.
- 101-54-2
- Chemical Name:
- 4-Aminodiphenylamine
- Synonyms
- N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
- CBNumber:
- CB9418967
- Molecular Formula:
- C12H12N2
- Molecular Weight:
- 184.24
- MOL File:
- 101-54-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/21 22:41:43
Melting point | 69 °C |
---|---|
Boiling point | 354 °C |
Density | 1.09 |
vapor pressure | 1 hPa |
refractive index | 1.6266 (estimate) |
Flash point | 193°C |
storage temp. | Store below +30°C. |
solubility | ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution) |
Colour Index | 37240 |
pka | 5.20±0.10(Predicted) |
form | Liquid |
color | Clear |
PH | 8.9 (0.5g/l, H2O, 20℃) |
Water Solubility | Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol. |
BRN | 908935 |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics. |
LogP | 1.82 at 20℃ and pH7 |
Dissociation constant | 5.45-5.47 at 20℃ |
CAS DataBase Reference | 101-54-2(CAS DataBase Reference) |
NIST Chemistry Reference | 1,4-Benzenediamine, N-phenyl-(101-54-2) |
EPA Substance Registry System | p-Aminodiphenylamine (101-54-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS09 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H317-H319-H411 | |||||||||
Precautionary statements | P261-P273-P280-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xn,Xi,N | |||||||||
Risk Statements | 22-36-43-42/43-36/37/38-20/22-50/53 | |||||||||
Safety Statements | 26-36-45-36/37/39-61-60-36/37 | |||||||||
RIDADR | UN3077 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | ST3150000 | |||||||||
F | 8 | |||||||||
Autoignition Temperature | >500 °C | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HazardClass | 9 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29215990 | |||||||||
Toxicity | LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg | |||||||||
NFPA 704 |
|
4-Aminodiphenylamine price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 241393 | N-Phenyl-p-phenylenediamine 98% | 101-54-2 | 100G | ₹2089.23 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 241393 | N-Phenyl-p-phenylenediamine 98% | 101-54-2 | 100G | ₹2089.23 | 2022-06-14 | Buy |
Sigma-Aldrich | 241393 | N-Phenyl-p-phenylenediamine 98% | 101-54-2 | 1KG | ₹7133.68 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 241393 | N-Phenyl-p-phenylenediamine 98% | 101-54-2 | 1KG | ₹7133.68 | 2022-06-14 | Buy |
ALFA India | ALF-B23867-30 | N-Phenyl-p-phenylenediamine, 98% | 101-54-2 | 250g | ₹3076 | 2022-05-26 | Buy |
4-Aminodiphenylamine Chemical Properties,Uses,Production
Description
p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.
Chemical Properties
Dark grey flake
Uses
4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.
Definition
ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.
General Description
Odorless purple-black solid or flake or dark purple chips.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.
Fire Hazard
4-Aminodiphenylamine is combustible.
Contact allergens
This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.
Purification Methods
It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]
4-Aminodiphenylamine Preparation Products And Raw materials
Raw materials
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chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Krishna Industries | +91-7922822554 +91-7922822554 | Gujarat, India | 235 | 58 | Inquiry |
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
A. B. Enterprises | +91-8048077585 | Mumbai, India | 1396 | 58 | Inquiry |
Krishna Industries | 08047651231 | Ahmedabad, India | 64 | 58 | Inquiry |
ALLCHEM LIFESCIENCE PVT. LTD | +91 957 472 2211 | New Delhi, India | 322 | 58 | Inquiry |
Oxford laboratories | +91 250 239 0032 | Maharashtra, India | 652 | 58 | Inquiry |
Supplier | Advantage |
---|---|
Krishna Industries | 58 |
CHEMSWORTH | 30 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Otto Chemie Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
Central Drug House(P) Ltd. | 58 |
A. B. Enterprises | 58 |
Krishna Industries | 58 |
ALLCHEM LIFESCIENCE PVT. LTD | 58 |
Oxford laboratories | 58 |
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