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1-Naphthol-4-sulfonic acid

1-Naphthol-4-sulfonic acid  Structure
CAS No.
84-87-7
Chemical Name:
1-Naphthol-4-sulfonic acid
Synonyms
Neville acid;1,4-Oxy Acid;Nevile-Winther acid;Nevile-Winthers acid;1-Naphthol-4-sulfoni;HIGH-PURITY N.W. ACID;Nevileandwinther’sacid;Neville and winther acid;Naphthol-4-sulfonic acid;1-Naphthol-4-sulfonicaci
CBNumber:
CB5743566
Molecular Formula:
C10H8O4S
Molecular Weight:
224.23
MOL File:
84-87-7.mol
MSDS File:
SDS
Modify Date:
2024/5/31 17:33:32

1-Naphthol-4-sulfonic acid Properties

Melting point 170℃
Boiling point 335.63°C (rough estimate)
Density 1.4643 (rough estimate)
refractive index 1.7040 (estimate)
pka 0.73±0.40(Predicted)
form solid
form solid
color white to yellow
InChI InChI=1S/C10H8O4S/c11-9-5-6-10(15(12,13)14)8-4-2-1-3-7(8)9/h1-6,11H,(H,12,13,14)
InChIKey HGWQOFDAUWCQDA-UHFFFAOYSA-N
SMILES C1(S(O)(=O)=O)=C2C(C=CC=C2)=C(O)C=C1
CAS DataBase Reference 84-87-7(CAS DataBase Reference)
EPA Substance Registry System 1-Naphthalenesulfonic acid, 4-hydroxy- (84-87-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

1-Naphthol-4-sulfonic acid Chemical Properties,Uses,Production

Chemical Properties

Transparent flake crystal. soluble in water. 1-Hydroxynaphthalene- 4 -sulfonic acid [84-87-7]. (4-hydroxynaphthalene-1-sulfonic acid), Nevile and Winther’s acid, NW acid, C10H8O4S, Mr 224.23, and its salts are water soluble, but the sodium salt may be precipitated from solution by salting out. Coupling with diazo compounds takes place in the 2-position. Nitration yields 2,4-dinitro-1-naphthol, whereas nitrosation gives 2-nitroso-1-hydroxynaphthalene-4-sulfonic acid. Sulfonation leads to a mixture of 1-hydroxynaphthalene-2,4-di- and 2,4,7- trisulfonic acids.

Preparation

After drying under vacuum, the resulting filter cake contains 1-naphthol-4-sulphonic acid in a yield of 92% of theory and <0.5% 1-naphthol-2-sulphonic acid and 3% of 1-naphthol-2,4-disulphonic acid based on the weight of 1-naphthol-4-sulphonic acid.

84-87-7.png

1-Naphthol-4-sulfonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Naphthalenesulfonicacid,4-hydroxy- 4-hydroxy-1-naphthalenesulfonicaci 4-hydroxynaphthalene-1-sulphonicacid Nevileandwinther’sacid N-(M-SULFOPHENYL) GAMMA ACID 4-Hydroxy-1-naphthalenesulfonic acid 1-NAPHTHOL-4-SULFONIC ACID Nevile-Winthers acid Meville-winter acid(1-naphthol-4-sulfonic acid,NW-acid) 4-hydroxynaphthalene-1-sulfonic acid NEVILLE-WINTHER ACID (NA SALT) 1-Hydroxy-4-sulfonaphthalene HIGH-PURITY N.W. ACID 1-Hydroxy-4-naphthalenesulfonic acid Neville acid Neville and winther acid 1,4-Oxy Acid a-Naphthol-4-sulfonic acid Nevile-Winther acid 1-Naphthol-4-sulfoni Naphthol-4-sulfonic acid 1-Naphthol-4-sulfonicaci 1-Naphthol-4-sulfonic acid ISO 9001:2015 REACH 4-Hydroxynaphthalene-1-sulfonicacid hydrate 84-87-7 C10H8O4S Intermediates of Dyes and Pigments