1-Naphthol-4-sulfonic acid
![1-Naphthol-4-sulfonic acid Structure](CAS/GIF/84-87-7.gif)
- CAS No.
- 84-87-7
- Chemical Name:
- 1-Naphthol-4-sulfonic acid
- Synonyms
- Neville acid;1,4-Oxy Acid;Nevile-Winther acid;Nevile-Winthers acid;1-Naphthol-4-sulfoni;HIGH-PURITY N.W. ACID;Nevileandwinther’sacid;Neville and winther acid;Naphthol-4-sulfonic acid;1-Naphthol-4-sulfonicaci
- CBNumber:
- CB5743566
- Molecular Formula:
- C10H8O4S
- Molecular Weight:
- 224.23
- MOL File:
- 84-87-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/31 17:33:32
Melting point | 170℃ |
---|---|
Boiling point | 335.63°C (rough estimate) |
Density | 1.4643 (rough estimate) |
refractive index | 1.7040 (estimate) |
pka | 0.73±0.40(Predicted) |
form | solid |
form | solid |
color | white to yellow |
InChI | InChI=1S/C10H8O4S/c11-9-5-6-10(15(12,13)14)8-4-2-1-3-7(8)9/h1-6,11H,(H,12,13,14) |
InChIKey | HGWQOFDAUWCQDA-UHFFFAOYSA-N |
SMILES | C1(S(O)(=O)=O)=C2C(C=CC=C2)=C(O)C=C1 |
CAS DataBase Reference | 84-87-7(CAS DataBase Reference) |
EPA Substance Registry System | 1-Naphthalenesulfonic acid, 4-hydroxy- (84-87-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
1-Naphthol-4-sulfonic acid Chemical Properties,Uses,Production
Chemical Properties
Transparent flake crystal. soluble in water. 1-Hydroxynaphthalene- 4 -sulfonic acid [84-87-7]. (4-hydroxynaphthalene-1-sulfonic acid), Nevile and Winther’s acid, NW acid, C10H8O4S, Mr 224.23, and its salts are water soluble, but the sodium salt may be precipitated from solution by salting out. Coupling with diazo compounds takes place in the 2-position. Nitration yields 2,4-dinitro-1-naphthol, whereas nitrosation gives 2-nitroso-1-hydroxynaphthalene-4-sulfonic acid. Sulfonation leads to a mixture of 1-hydroxynaphthalene-2,4-di- and 2,4,7- trisulfonic acids.
Preparation
After drying under vacuum, the resulting filter cake contains 1-naphthol-4-sulphonic acid in a yield of 92% of theory and <0.5% 1-naphthol-2-sulphonic acid and 3% of 1-naphthol-2,4-disulphonic acid based on the weight of 1-naphthol-4-sulphonic acid.
1-Naphthol-4-sulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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