Diphenyldiazomethane

Diphenyldiazomethane Structure
CAS No.
883-40-9
Chemical Name:
Diphenyldiazomethane
Synonyms
Diazodiphenylmethane;3,3-diphenyldiazirine;Bis(phenyl)diazomethane;(Diazomethylene)dibenzene;(diazo-phenyl-methyl)benzene;1,1-Diphenyldiazomethane (>INTERMEDIATEOFCEFOSELISSULFATE;1,1'-(Diazomethylene)bisbenzene;1,1-Diphenyldiazomethane (>90%);1,1'-(diazomethanediyl)dibenzene
CBNumber:
CB5949708
Molecular Formula:
C13H10N2
Molecular Weight:
0
MOL File:
883-40-9.mol
Modify Date:
2023/4/23 13:52:06

Diphenyldiazomethane Properties

Melting point 29-30 °C
Boiling point 320.68°C (rough estimate)
Density 1.1579 (rough estimate)
refractive index 1.5014 (estimate)
storage temp. -20°C, Light sensitive
solubility Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
color Red to Very Dark Purple
Stability Possibly shock sensitive

Diphenyldiazomethane Chemical Properties,Uses,Production

Description

A alkylating agent for carboxylic acids; reagent for the synthesis of diphenylcyclopropanes from alkenes.

Uses

1,1-Diphenyldiazomethane is used to synthesize tartaric acid analogs of FR258900 as glycogen phosphorylase inhibitors.

Preparation

Diphenyldiazomethane is prepared by the oxidation of benzophenone hydrazone.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 3, p. 351, 1955
The Journal of Organic Chemistry, 60, p. 4725, 1995 DOI: 10.1021/jo00120a013

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883-40-9(Diphenyldiazomethane)Related Search:

(diazo-phenyl-methyl)benzene 1,1'-(Diazomethylene)bisbenzene Diazodiphenylmethane INTERMEDIATEOFCEFOSELISSULFATE Bis(phenyl)diazomethane (3R)-tert-butyl 3-(3-bromo-2-oxopyrrolidin-1-yl)pyrrolidine-1-carboxylate Benzene, 1,1'-(diazoMethylene)bis- 3,3-diphenyldiazirine 1,1-Diphenyldiazomethane (> 1,1-Diphenyldiazomethane (>90%) 1,1'-(diazomethanediyl)dibenzene (Diazomethylene)dibenzene 1,1'-(Diazomethylene)bis[benzene 883-40-9