Tetrabutyl titanate
- CAS No.
- 5593-70-4
- Chemical Name:
- Tetrabutyl titanate
- Synonyms
- TITANIUM BUTOXIDE;TNBT;TETRA-N-BUTYL TITANATE;tetrabutoxytitanium;BUTYL TITANATE;TITANIUM(IV) BUTOXIDE;TITANIUM TETRABUTOXIDE;TETRABUTYL ORTHOTITANATE;Tyzor TBT;titaniuM salt
- CBNumber:
- CB6222404
- Molecular Formula:
- C16H36O4Ti
- Molecular Weight:
- 340.32
- MOL File:
- 5593-70-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/6 14:33:24
| Melting point | -55°C |
|---|---|
| Boiling point | 206 °C/10 mmHg (lit.) |
| Density | 1.00 g/mL at 20 °C (lit.) |
| vapor pressure | 5.6 hPa (20 °C) |
| refractive index |
n |
| Flash point | 55 °F |
| storage temp. | Store at +2°C to +8°C. |
| solubility | Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents. |
| form | Liquid |
| Specific Gravity | 0.998 |
| color | Pale yellow |
| explosive limit | 2.0-12.0%(V) |
| Water Solubility | RAPIDLY HYDROLIZED |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 4148236 |
| Stability | Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids. |
| InChIKey | YHWCPXVTRSHPNY-UHFFFAOYSA-N |
| LogP | 0.84 at 25℃ |
| CAS DataBase Reference | 5593-70-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Tetrabutoxytitanium(5593-70-4) |
| EPA Substance Registry System | Tetrabutyl titanate (5593-70-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H315-H318-H335-H336 | |||||||||
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,T | |||||||||
| Risk Statements | 10-36/37/38-67-41-37/38-45 | |||||||||
| Safety Statements | 16-26-39-24/25-53 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | XR1585000 | |||||||||
| F | 21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29051900 | |||||||||
| Toxicity | LD50 orally in Rabbit: 3122 mg/kg | |||||||||
| NFPA 704 |
|
Tetrabutyl titanate price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 86910 | Titanium(IV) butoxide purum, ≥97.0% (gravimetric) | 5593-70-4 | 250ML | ₹5618.18 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.21084 | Tetra-n-butyl orthotitanate for synthesis | 5593-70-4 | 100ML | ₹5760.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 86910 | Titanium(IV) butoxide purum, ≥97.0% (gravimetric) | 5593-70-4 | 1L | ₹11171.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.21084 | Tetra-n-butyl orthotitanate for synthesis | 5593-70-4 | 500ML | ₹14630 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.21084 | Tetra-n-butyl orthotitanate for synthesis | 5593-70-4 | 10KG | ₹43080.01 | 2022-06-14 | Buy |
Tetrabutyl titanate Chemical Properties,Uses,Production
Chemical Properties
colourless to light yellow viscous liquid
Uses
Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.
General Description
A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.
Air & Water Reactions
Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.
Reactivity Profile
Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.
Health Hazard
LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting.
Fire Hazard
Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode.
Safety Profile
Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
Purification Methods
Dissolve it in *C6H6, filter if solid is present, evaporate and vacuum fractionate through a Widmer 24inch column (p 11). The ester hydrolyses when exposed to air to give hydrated ortho-titanic acid. The titanium content can be determined thus: weigh a sample (ca 0.25g) into a weighed crucible and cover it with 10mL of H2O and a few drops of conc HNO3. Heat (hot plate) carefully till most of the H2O has evaporated. Cool and add more H2O (10mL) and conc HNO3 (2mL), and evaporate carefully (no spillage) to dryness and ignite the residue at 600-650o/1hour. Weigh the residual TiO2. [Bradley et al. J Chem Soc 2773 1952, Speer J Org Chem 14 655 1949, Beilstein 1 II 398, 1 III 1515, 1 IV 1415.]
Tetrabutyl titanate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Polygel Industries Pvt Ltd | +91-9819976506 +91-9819976506 | Maharashtra, India | 10 | 58 | Inquiry |
| Nath Titanates Pvt Ltd | +91 7588534055 | Maharashtra, India | 4 | 58 | Inquiry |
| Super Urecoat Industries | +91-9904933318 +91-9904933318 | Gujarat, India | 7 | 58 | Inquiry |
| Om Titanates | +91-9821431234 +91-9821431234 | Gujarat, India | 5 | 58 | Inquiry |
| Synthochem Pvt Ltd | +91-9826270234 +91-9826270234 | Madhya Pradesh, India | 12 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| MORYA CHEMICALS | 08048361378Ext 364 | Maharashtra, India | 9 | 58 | Inquiry |
| Bhalla Chemical Works Private Limited | 09971110681 | Haryana, India | 8 | 58 | Inquiry |
| C. J. Chemicals Private Limited | 08048372638Ext 579 | Hyderabad, India | 24 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Polygel Industries Pvt Ltd | 58 |
| Nath Titanates Pvt Ltd | 58 |
| Super Urecoat Industries | 58 |
| Om Titanates | 58 |
| Synthochem Pvt Ltd | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| Triveni chemicals | 58 |
| MORYA CHEMICALS | 58 |
| Bhalla Chemical Works Private Limited | 58 |
| C. J. Chemicals Private Limited | 58 |
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