Titanium tetraisopropanolate
![Titanium tetraisopropanolate Structure](CAS/GIF/546-68-9.gif)
- CAS No.
- 546-68-9
- Chemical Name:
- Titanium tetraisopropanolate
- Synonyms
- TITANIUM ISOPROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM TETRAISOPROPOXIDE;TTIP;tetraisopropoxytitanium;TETRAISOPROPYL TITANATE;ISOPROPYL TITANATE;Titanium(Ⅳ) isopropoxide;TETRAISOPROPYL ORTHOTITANATE;TITANIUM(IV) TETRAISOPROPOXIDE
- CBNumber:
- CB3363214
- Molecular Formula:
- C12H28O4Ti
- Molecular Weight:
- 284.22
- MOL File:
- 546-68-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/22 17:53:22
Melting point | 14-17 °C(lit.) |
---|---|
Boiling point | 232 °C(lit.) |
Density | 0.96 g/mL at 20 °C(lit.) |
vapor pressure | 60.2hPa at 25℃ |
refractive index |
n |
Flash point | 72 °F |
storage temp. | Flammables area |
solubility | Soluble in anhydrous ethanol, ether, benzene and chloroform. |
form | Liquid |
Specific Gravity | 0.955 |
color | Colorless to pale yellow |
Water Solubility | HYDROLYSIS |
FreezingPoint | 14.8℃ |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
Merck | 14,9480 |
BRN | 3679474 |
Stability | Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable. |
InChIKey | VXUYXOFXAQZZMF-UHFFFAOYSA-N |
LogP | 0.05 |
CAS DataBase Reference | 546-68-9(CAS DataBase Reference) |
EPA Substance Registry System | 2-Propanol, titanium(4+) salt (546-68-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H226-H319-H336 | |||||||||
Precautionary statements | P210-P233-P240-P241-P242-P305+P351+P338 | |||||||||
Hazard Codes | Xi,F | |||||||||
Risk Statements | 10-36-36/37/38-11-67 | |||||||||
Safety Statements | 16-26-36/37/39-7/9 | |||||||||
RIDADR | UN 2413 3/PG 3 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | NT8060000 | |||||||||
F | 21 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29051900 | |||||||||
NFPA 704 |
|
Titanium tetraisopropanolate price More Price(29)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 87560 | Titanium(IV) isopropoxide ≥97.0% | 546-68-9 | 100ML | ₹8465.15 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 87560 | Titanium(IV) isopropoxide ≥97.0% | 546-68-9 | 500ML | ₹14115.8 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 377996 | Titanium(IV) isopropoxide 99.999% trace metals basis | 546-68-9 | 5ML | ₹5900 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 205273 | Titanium(IV) isopropoxide 97% | 546-68-9 | 100ML | ₹2067.58 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 205273 | Titanium(IV) isopropoxide 97% | 546-68-9 | 500ML | ₹4286.7 | 2022-06-14 | Buy |
Titanium tetraisopropanolate Chemical Properties,Uses,Production
Chemical Properties
colourless to light yellow liquid
Uses
Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
Definition
ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.
General Description
Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity Profile
Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Purification Methods
Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]
Titanium tetraisopropanolate Preparation Products And Raw materials
Raw materials
1of2
chevron_rightPreparation Products
1of2
chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
ULTIMA CHEMICALS | +91 7208029458 | Mumbai, India | 95 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
Om Titanates | +91-9821431234 +91-9821431234 | Gujarat, India | 5 | 58 | Inquiry |
Polygel Industries Pvt Ltd | +91-9819976506 +91-9819976506 | Maharashtra, India | 10 | 58 | Inquiry |
Nath Titanates Pvt Ltd | +91 7588534055 | Maharashtra, India | 4 | 58 | Inquiry |
Super Urecoat Industries | +91-9904933318 +91-9904933318 | Gujarat, India | 7 | 58 | Inquiry |
Synthochem Pvt Ltd | +91-9826270234 +91-9826270234 | Madhya Pradesh, India | 12 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Supplier | Advantage |
---|---|
ULTIMA CHEMICALS | 58 |
JSK Chemicals | 58 |
Om Titanates | 58 |
Polygel Industries Pvt Ltd | 58 |
Nath Titanates Pvt Ltd | 58 |
Super Urecoat Industries | 58 |
Synthochem Pvt Ltd | 58 |
CLEARSYNTH LABS LTD. | 58 |
A.J Chemicals | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |