(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Structure
CAS No.
16854-32-3
Chemical Name:
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Synonyms
thiomicamine;L-THIOMICAMINE;Einecs 240-878-4;(1S,2S)-(+)-THIOMICAMINE;(1S,2S)-(+)-Thiomicamine 99%;2-Amino-1-(4-methylthliophenyl)-1,3-propanediol;2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol;(1S,2S)-2-aMino-1-(4-(Methylthio)phenyl)propane-1,3-diol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol
CBNumber:
CB6358080
Molecular Formula:
C10H15NO2S
Molecular Weight:
213.3
MOL File:
16854-32-3.mol
MSDS File:
SDS
Modify Date:
2022/12/30 16:20:48

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Properties

Melting point 151-154 °C(lit.)
Boiling point 428.2±45.0 °C(Predicted)
Density 1.25±0.1 g/cm3(Predicted)
pka 11.75±0.45(Predicted)
optical activity [α]25/D +25°, c = 1 in ethanol
CAS DataBase Reference 16854-32-3(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HS Code  2930909899

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Chemical Properties,Uses,Production

Uses

(1S,2S)-(+)-Thiomicamine can be used:

  • As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
  • As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
  • As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Suppliers

Global( 50)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
SIMAGCHEM CORP +86-13806087780 China 17367 58 Inquiry
Mainchem Co., Ltd. +86-86-05926210733 +8618030271905 China 6572 58 Inquiry
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Sigma-Aldrich 021-61415566 800-8193336 China 51471 80 Inquiry
Shanghai Kaiwei Chemical Technology Co., Ltd. 021-58461859 15821823057 China 49323 58 Inquiry
Aikon International Limited 025-58859352 18068836627 China 15085 58 Inquiry
Shanghai Yingxin laboratory equipment Co., Ltd 021-021-59178156 15300768757 China 10678 58 Inquiry
(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol Einecs 240-878-4 (1S,2S)-2-Amino-1-[4-(methylsulfanyl)phenyl]propane-1,3-diol (1S,2S)-2-aMino-1-(4-(Methylthio)phenyl)propane-1,3-diol (1S,2S)-(+)-Thiomicamine 99% 2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol [S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol L-THIOMICAMINE (1S,2S)-(+)-THIOMICAMINE (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL thiomicamine (1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol 2-Amino-1-(4-methylthliophenyl)-1,3-propanediol 1,3-Propanediol, 2-amino-1-[4-(methylthio)phenyl]-, (1S,2S)- 16854-32-3 4CH3SC6H4CHOHCHNH2CH2OH AMINE Amino Alcohols Asymmetric Synthesis Chiral Building Blocks Organic Building Blocks