Sodium trifluoroacetate
![Sodium trifluoroacetate Structure](CAS/GIF/2923-18-4.gif)
- CAS No.
- 2923-18-4
- Chemical Name:
- Sodium trifluoroacetate
- Synonyms
- Sodium 2,2,2-trifluoroacetate;Sodium trifL;Natriumtrifluoracetat;sodiumperfluoroacetate;SODIUMTRIFLUOR-ACETATE;SODIUM TRIFLUOROACETATE;Sodlium trifluoroacetate;SODIUMPERFLUOROACETICACID;Sodiumtrifluoroacetate,97+%;Sodium trifluoroacetate 97%
- CBNumber:
- CB6388786
- Molecular Formula:
- C2F3NaO2
- Molecular Weight:
- 136.01
- MOL File:
- 2923-18-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/9/4 16:41:41
Melting point | 205-207 °C (dec.) (lit.) |
---|---|
Density | 1.49 g/mL (lit.) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | H2O: 1 M at 20 °C, clear, colorless |
form | Crystalline Powder |
color | White |
Specific Gravity | 1.49 |
PH | 7 (H2O, 20℃) |
Water Solubility | 625 g/L (25 ºC) |
Sensitive | Hygroscopic |
Hydrolytic Sensitivity | 6: forms irreversible hydrate |
BRN | 3597949 |
Stability | Hygroscopic |
InChIKey | UYCAUPASBSROMS-UHFFFAOYSA-M |
LogP | 1.238 (est) |
CAS DataBase Reference | 2923-18-4(CAS DataBase Reference) |
EPA Substance Registry System | Acetic acid, trifluoro-, sodium salt (2923-18-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS09 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H411 | |||||||||
Precautionary statements | P273-P391-P501 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
RIDADR | 2811 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | AK0250000 | |||||||||
F | 3-10 | |||||||||
Hazard Note | Irritant/Hygroscopic | |||||||||
TSCA | T | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29159080 | |||||||||
NFPA 704 |
|
Sodium trifluoroacetate price More Price(9)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 132101 | Sodium trifluoroacetate 98% | 2923-18-4 | 25G | ₹2110 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 132101 | Sodium trifluoroacetate 98% | 2923-18-4 | 100G | ₹5810 | 2022-06-14 | Buy |
ALFA India | ALF-A14613-36 | Sodium trifluoroacetate, 98% | 2923-18-4 | 500g | ₹18222 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1336 | Sodium Trifluoroacetate | 2923-18-4 | 25G | ₹1800 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1336 | Sodium Trifluoroacetate | 2923-18-4 | 100G | ₹4400 | 2022-05-26 | Buy |
Sodium trifluoroacetate Chemical Properties,Uses,Production
Chemical Properties
Sodium trifluoroacetate is an organic metal compound with the chemical formula CF3COONa. It is a white crystalline powderr that easily absorbs moisture. This compound has the ability to add a trifluoromethyl group to halogenated aromatic hydrocarbons.
Uses
Sodium trifluoroacetate is used in acid catalyzed reactions. It is also used as an intermediate for active pharmaceutical ingredients (API). Further, it acts as a precursor for the trifluoromethylation of aldehydes using copper(I) halide as a catalyst.
Preparation
It can be obtained by reacting trifluoroacetic acid with sodium carbonate or sodium hydroxide.
Purification Methods
A possible contaminant is NaCl. The solid is treated with CF3CO2H and evaporated twice. Its solubility in CF3CO2H is 13.1% at 29.8o. The residue is crystallised from dilute EtOH, and the solid is dried in vacuum at 100o. [Hara & Cady J Am Chem Soc 76 4285 1954.] It can be precipitated from EtOH by adding dioxane, then recrystallising several times from hot absolute EtOH. Dry it at 120-130o/1mm. [Beilstein 2 IV 461.]
Sodium trifluoroacetate Preparation Products And Raw materials
Raw materials
Preparation Products
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