Barium oxide
![Barium oxide Structure](CAS/GIF/1304-28-5.gif)
- CAS No.
- 1304-28-5
- Chemical Name:
- Barium oxide
- Synonyms
- Baryta;Barsito;Oxobarium;BARIUM OXIDE;oxydedebaryum;calcinedbaryta;BARIUM MONOXIDE;bariumprotoxide;Calcined baryta;Oxyde de baryum
- CBNumber:
- CB6391366
- Molecular Formula:
- BaO
- Molecular Weight:
- 153.33
- MOL File:
- 1304-28-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/14 15:18:27
Melting point | 1920 °C |
---|---|
Boiling point | 2000 °C |
Density | 5.72 g/mL at 25 °C(lit.) |
refractive index | 1.98 |
solubility | soluble in dilute acid solutions, ethanol; insoluble in acetone |
form | Powder |
Specific Gravity | 5.72 |
color | Light yellow-greenish to grayish |
Water Solubility | Sparingly soluble in water. Soluble in ethanol, dilute mineral acids and alkali. |
Sensitive | Moisture Sensitive |
Merck | 14,986 |
Exposure limits |
ACGIH: TWA 0.5 mg/m3 NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 |
Stability | Stable. Incompatible with strong acids, water. Protect from moisture. |
CAS DataBase Reference | 1304-28-5(CAS DataBase Reference) |
EPA Substance Registry System | Barium oxide (1304-28-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS05,GHS06 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H301-H314-H332 | |||||||||
Precautionary statements | P260-P280-P301+P310+P330-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310 | |||||||||
Hazard Codes | T | |||||||||
Risk Statements | 20-25-34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 1884 6.1/PG 3 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | CQ9800000 | |||||||||
F | 3-9-34 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 28164000 | |||||||||
Toxicity | mouse,LD50,intraperitoneal,146mg/kg (146mg/kg),Current Toxicology. Vol. 1, Pg. 39, 1993. | |||||||||
NFPA 704 |
|
Barium oxide price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 554847 | Barium oxide 99.99% trace metals basis | 1304-28-5 | 5G | ₹6397.58 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 554847 | Barium oxide 99.99% trace metals basis | 1304-28-5 | 25G | ₹20058.73 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 288497 | Barium oxide 97% | 1304-28-5 | 50G | ₹15956.05 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 288497 | Barium oxide 97% | 1304-28-5 | 250G | ₹88905.73 | 2022-06-14 | Buy |
ALFA India | ALF-044440-22 | Barium oxide, 99.5% (metals basis excluding Sr), Sr <500ppm | 1304-28-5 | 100g | ₹205065 | 2022-05-26 | Buy |
Barium oxide Chemical Properties,Uses,Production
Physical properties
Barium Oxide is
a white, hygroscopic formed by the burning of Ba metal
in oxygen or the decomposition of the carbonate salt:
2Ba+ O2→2BaO
BaCO3→BaO+ CO2
It transforms into the hydroxide on contact with
water.
BaO+H2O→Ba(OH)2
It is soluble in
ethanol, dilute acids and alkalis but insoluble in acetone
and liquid ammonia.
The monoxide is formed when the metal burns
in air, but is usually prepared by the ignition of the
nitrate, oxygen and oxides of nitrogen being liberated.
It can also be obtained by the ignition of an intimate
mixture of the carbonate and carbon, and in small quantities
by the ignition of the iodate.
Uses
Barium oxide is used as a coating for “hot cathodes”
in a variety of electronic devices such as TV’s and lamps.
It replaced lead oxide in the production of certain kinds
of glass. While lead oxide raised the refractive index of
the glass, it also raised the dispersion, i.e refraction of
various colors of light resulting in distortion of images
which barium oxide does not alter. Barium oxide also
has use as an ethoxylation catalyst in the reaction of ethylene oxide and alcohols which takes place between
150 and 200°C.
The thermionic emission from thin evaporated films
of barium oxide has been studied extensively. Thin
barium oxide films have a good emission following
evaporation. The emission improves a little during
heat treatment, and is then similar to that from a sprayed
cathode coating of barium oxide.
Definition
barium oxide: A white or yellowishsolid, BaO, obtained by heating bariumin oxygen or by the thermal decompositionof barium carbonate ornitrate; cubic; r.d. 5.72; m.p. 1923°C;b.p. 2000°C. When barium oxide isheated in oxygen the peroxide, BaO2,is formed in a reversible reactionthat was once used as a method forobtaining oxygen (the Brin process).Barium oxide is now used in themanufacture of lubricating-oil additives.
Preparation
Barium oxide is made by heating barium carbonate with coke, carbon black or tar:
BaCO3 + C→ BaO + 2CO
It may be also prepared by thermal decomposition of barium nitrate.
General Description
A white to yellow powder. May be toxic by ingestion. Irritates skin, eyes and mucous membranes. Used as a drying agent for gasoline and solvents.
Air & Water Reactions
Hygroscopic. Reacts readily and exothermically with water to form a solution of corrosive barium hydroxide [Merck 11th ed. 1989].
Reactivity Profile
BARIUM OXIDE reacts as a strong base. Combines exothermically with all categories of acids. Reacts with carbon dioxide to form barium carbonate [Merck 11th ed. 1989]. Ignites hydroxylamine on contact [Mellor 8:291 1946-47]. Mixtures with mercurous or nickel oxide react vigorously with hydrogen sulfide in air. Explosions may result [Mellor 10:140 1946-47]. Can react, particularly in the presence of moisture, with aluminum and zinc)to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, peroxides, and hydroperoxides.
Hazard
Toxic by ingestion. See barium.
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Safety Profile
A poison via subcutaneous route. See also BARIUM COMPOUNDS (soluble). Combustible by spontaneous chemical reaction; produces heat on contact with water or steam. Reacts with H2O, Ba(OH)2. Incompatible with H2S, hydroxylamine, N2O4, triuranium octaoxide, so3.
Potential Exposure
It is used to dry gases and solvents and in producing detergents for lubricating oils.
Shipping
UN1884 Barium oxide, Hazard Class: 6.1; Labels: 6.1—Poisonous materials.
Incompatibilities
Reacts with water, forming the strong base, barium hydroxide. Keep away from acids, hydrogen sulfide, carbon dioxide; hydroxylamine, nitrogen tetroxide; sulfur trioxide; since violent reactions occur. Reacts with triuranium. Never pour water into this chemical.
Barium oxide Preparation Products And Raw materials
Raw materials
Preparation Products
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