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Chloromethyl ethyl ether

Chloromethyl ethyl ether Structure
CAS No.
3188-13-4
Chemical Name:
Chloromethyl ethyl ether
Synonyms
(chloromethoxy)ethane;Chloromethoxyethane;chloromethoxy-ethane;ClCH2OC2H5;Ethoxychloromethane;ethoxymethylchloride;Chloromethyl ethyl e;(chloromethoxy)-ethan;Ethoxymethyl chloride;chloromethylethylester
CBNumber:
CB6853484
Molecular Formula:
C3H7ClO
Molecular Weight:
94.54
MOL File:
3188-13-4.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:38

Chloromethyl ethyl ether Properties

Melting point -104°C
Boiling point 82 °C(lit.)
Density 1.019 g/mL at 25 °C(lit.)
refractive index n20/D 1.404(lit.)
Flash point 67 °F
storage temp. 0-6°C
solubility Chloroform (Soluble), Ethyl Acetate (Slightly)
form Liquid
color Clear colorless to pale yellow
Specific Gravity 1.019
InChI InChI=1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
InChIKey FCYRSDMGOLYDHL-UHFFFAOYSA-N
SMILES CCOCCl
CAS DataBase Reference 3188-13-4(CAS DataBase Reference)
NIST Chemistry Reference Ethane, (chloromethoxy)-(3188-13-4)
EPA Substance Registry System Ethane, (chloromethoxy)- (3188-13-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H302+H312+H332-H319-H351
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P308+P313
Hazard Codes  F,Xn
Risk Statements  11-20/21/22-36-40
Safety Statements  16-36/37-9-45-29
RIDADR  UN 2354 3/PG 2
WGK Germany  3
HazardClass  6.1(a)
PackingGroup  I
HS Code  29091990
NFPA 704
3
2 0

Chloromethyl ethyl ether price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 142670 Chloromethyl ethyl ether 95% 3188-13-4 25G ₹11528.63 2022-06-14 Buy
TCI Chemicals (India) C0201 Chloromethyl Ethyl Ether min. 96.0 % 3188-13-4 25G ₹7300 2022-05-26 Buy
TCI Chemicals (India) C0201 Chloromethyl Ethyl Ether min. 96.0 % 3188-13-4 100G ₹11100 2022-05-26 Buy
TCI Chemicals (India) C0201 Chloromethyl Ethyl Ether min. 96.0 % 3188-13-4 500G ₹32700 2022-05-26 Buy
Product number Packaging Price Buy
142670 25G ₹11528.63 Buy
C0201 25G ₹7300 Buy
C0201 100G ₹11100 Buy
C0201 500G ₹32700 Buy

Chloromethyl ethyl ether Chemical Properties,Uses,Production

Chemical Properties

clear colorless to pale yellow liquid

Uses

Chloromethyl ethyl ether can be used to prepare:

  • 6-Benzyl-1-(ethoxymethyl)-5-iodopyrimidine-2,4(1H,3H)-dione, a key intermediate in the preparation of MKC-442 analog.
  • Acylation catalyst for alcohols named 1,3-bis-[(R)-1-(2-naphthyl)ethyl]imidazoliumchloride by reacting with glyoxal-bis-[(R)-1-(2-naphthyl)ethyl]imine.

General Description

A colorless liquid. Slightly denser than water and insoluble in water. Flash point below 73°F. May be moderately toxic by ingestion, inhalation or skin absorption. Severely irritates skin, eyes and mucous membranes.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Chloromethyl ethyl ether tends to form unstable peroxides when exposed to oxygen or air. These products can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Forms salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. I

Health Hazard

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Global( 162)Suppliers
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(chloromethoxy)-ethan 1-(Chloromethoxy)ethane chloromethylethylester ClCH2OC2H5 Ether, chloromethyl ethyl Ethoxychloromethane Chloromethyl ethyl ether, tech. 80% CHLOROMETHYL ETHYL ETHER Chloromethyl ethyl ether, tech., stabilized, 80% Ethoxymethyl chloride ethoxymethylchloride Ethyl chloromethyl ether ethylchloromethylether Chloromethyl ethyl ether, 80%, stabilized, tech. Chloromethyl ethyl ether, contains ca 12% chloroethyl methyl ether,80%,tech. Chloromethyl ethyl ether,80%,tech., stabilized Chloromethyl ethyl e ChloroMethyl ethyl ether, tech., stabilized, 80% 25ML ChloroMethyl Ethyl Ether 90% ChloroMethyl ethyl ether, 96%+ Chloromethyl Ethyl Ether > Ethane, (chloromethoxy)- chloromethoxy-ethane Chloromethoxyethane (chloromethoxy)ethane Lercanidipine Impurity 38 Pantoprazole Impurity 75 3188-13-4 C2H5OCH2Cl Synthetic Reagents Others Protection and Derivatization Protecting and Derivatizing Reagents API Intermediate Others Protecting and Derivatizing Reagents Protection and Derivatization