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2,3-Dimethylmaleic anhydride

2,3-Dimethylmaleic anhydride Structure
CAS No.
766-39-2
Chemical Name:
2,3-Dimethylmaleic anhydride
Synonyms
DIMETHYLMALEIC ANHYDRIDE;Pyrocinchonic anhydride;3,4-Dimethyl-2,5-furandione;2,5-Furandione,3,4-dimethyl-;2,2’-Dimethylmaleinsαureanhydrid;eic Anhydride;pyrocinchonicanhydride;dimethyl-maleicanhydrid;3,4-dimethyl-5-furandione;TwoMethyl Maleic anhydride
CBNumber:
CB7179895
Molecular Formula:
C6H6O3
Molecular Weight:
126.11
MOL File:
766-39-2.mol
MSDS File:
SDS
Modify Date:
2023/5/25 18:01:17

2,3-Dimethylmaleic anhydride Properties

Melting point 93-96 °C (lit.)
Boiling point 223 °C (lit.)
Density 1.107 g/cm3 (100℃)
refractive index 1.5627 (estimate)
Flash point 222-223°C
storage temp. Store below +30°C.
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Solid
color White to Off-White
Water Solubility Soluble in ethanol, ether and chloroform. Slightly soluble in water.
Sensitive Moisture Sensitive
BRN 112044
LogP 0.183 (est)
CAS DataBase Reference 766-39-2(CAS DataBase Reference)
NIST Chemistry Reference 2,5-Furandione, 3,4-dimethyl-(766-39-2)
EPA Substance Registry System 2,5-Furandione, 3,4-dimethyl- (766-39-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P501
Hazard Codes  Xn,Xi
Risk Statements  22
Safety Statements  45-36/37/39-28A-26
WGK Germany  3
RTECS  ON4025000
9-21
TSCA  Yes
HS Code  2917 19 80
NFPA 704
1
3 1

2,3-Dimethylmaleic anhydride price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D167800 2,3-Dimethylmaleic anhydride 98% 766-39-2 5G ₹4394.95 2022-06-14 Buy
Sigma-Aldrich(India) D167800 2,3-Dimethylmaleic anhydride 98% 766-39-2 100G ₹80364.8 2022-06-14 Buy
Sigma-Aldrich(India) 8.41502 2,3-Dimethylmaleic anhydride for synthesis 766-39-2 5G ₹7479.99 2022-06-14 Buy
TCI Chemicals (India) D3473 2,3-Dimethylmaleic Anhydride min. 98.0 % 766-39-2 5G ₹4300 2022-05-26 Buy
TCI Chemicals (India) D3473 2,3-Dimethylmaleic Anhydride min. 98.0 % 766-39-2 25G ₹8800 2022-05-26 Buy
Product number Packaging Price Buy
D167800 5G ₹4394.95 Buy
D167800 100G ₹80364.8 Buy
8.41502 5G ₹7479.99 Buy
D3473 5G ₹4300 Buy
D3473 25G ₹8800 Buy

2,3-Dimethylmaleic anhydride Chemical Properties,Uses,Production

Chemical Properties

white to beige crystals or cryst. powder

Uses

2,3-Dimethylmaleic anhydride can be usually used in the synthesis of maleimides and as an amino group protecting agent for superoxide dismutase. It is also used in the preparation of dimethylmaleic acid dimethyl ester. Further, it serves as a reactant in the dissociation of ribosomal proteins. In addition to this, The isolated molecule 2, 3-dimethylmaleic anhydride showed potent insecticidal activity in fumigation bioassay against several insect species, viz., adults of houseflies, cockroaches and stored-product insects.

Definition

ChEBI: 2,3-Dimethylmaleic anhydride is a butenolide. It is a 5-membered cyclic anhydride with a double bond between carbon atoms C2 and C3. The double bond locks the molecule in a planar conformation and stabilizes the acid anhydride against hydration. It was used as linker to a cell penetrating peptidebased nanoparticle.

Safety Profile

Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also ANHYDRIDES.

Purification Methods

Distil the anhydride from *benzene/ligroin and sublime in a vacuum. [Beilstein 17/11 V 69.]

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3,4-dimethyl-2,5-furanedione 3,4-dimethyl-5-furandione alpha,beta-Dimethylmaleic anhydride 2,3-Dimethylmaleic anhydride,97% 2,3-Dimethylmaleic anhydride ,96% TwoMethyl Maleic anhydride 2,3-DiMethylMaleic anhydride 98% 3,4-Dimethylfuran-2,5-dione, 2,5-Dihydro-3,4-dimethyl-2,5-dioxofuran 2,3-DiMethylMaleic anhydride, 97% 50GR 2,3-DiMethylMaleic anhydride, 97% 5GR alpha,beta-dimethylmaleicanhydride Anhydride of dimethylmaleic acid Dimethylmaleic acid anhydride dimethylmaleicacidanhydride dimethyl-maleicanhydrid Maleic anhydride, dimethyl- pyrocinchonicanhydride 2,3-DIMETHYLMALEIC ANHYDRIDE DIMETHYLMALEIC ANHYDRIDE CRYSTALLINE 4,5-DIMETHYL-1,3-DIOXA-2-OXO-CYCLOPENTENE 2,5-Dihydro-3,4-dimethylfuran-2,5-dione 3,4-DIMETHYL-2,5-DIHYDROFURAN-2,5-DIONE eic Anhydride 2,3-Dimethylmaleic anhydride, 96%, for synthesis 2,3-DimethylmaleicAnhydride> 2,3-DIMETHYLMALEIC ANHYDRIDE FOR SYNTHES 2,2’-Dimethylmaleinsαureanhydrid 2,5-Furandione,3,4-dimethyl- 3,4-Dimethyl-2,5-furandione Pyrocinchonic anhydride DIMETHYLMALEIC ANHYDRIDE 766-39-2 Organic Building Blocks Building Blocks Carbonyl Compounds Carboxylic Acid Anhydrides Heterocycles series Carbonyl Compounds Carboxylic Acid Anhydrides Organic Building Blocks