ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Ethers >(S)-(+)-Benzyl glycidyl ether
(S)-(+)-Benzyl glycidyl ether
- CAS No.
- 16495-13-9
- Chemical Name:
- (S)-(+)-Benzyl glycidyl ether
- Synonyms
- (S)-BENZYL GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;BENZYL (S)-(+)-GLYCIDYL ETHER;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
- CBNumber:
- CB8164324
- Molecular Formula:
- C10H12O2
- Molecular Weight:
- 164.2
- MOL File:
- 16495-13-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| alpha | 5.1 º (c=5 in toluene) |
|---|---|
| Boiling point | 130 °C (0.1 mmHg) |
| Density | 1.072 g/mL at 20 °C(lit.) |
| refractive index |
n |
| Flash point | >110°C |
| storage temp. | 2-8°C |
| solubility | Chloroform, Ethanol |
| form | Oil |
| color | Colourless |
| Specific Gravity | 1.077 |
| optical activity | [α]20/D +5.1°, c = 5 in toluene |
| BRN | 5246495 |
| CAS DataBase Reference | 16495-13-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TX2860030 | |||||||||
| HS Code | 29109000 | |||||||||
| Toxicity | mic-sat 660 nmol/plate MUREAV 298,197,1993 | |||||||||
| NFPA 704 |
|
(S)-(+)-Benzyl glycidyl ether price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 363537 | (S)-(+)-Glycidyl benzyl ether 99% | 16495-13-9 | 1G | ₹2695.43 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 363537 | (S)-(+)-Glycidyl benzyl ether 99% | 16495-13-9 | 1G | ₹2695.43 | 2022-06-14 | Buy |
| TCI Chemicals (India) | B2239 | Benzyl (S)-(+)-Glycidyl Ether min. 98.0 % | 16495-13-9 | 1G | ₹3400 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B2239 | Benzyl (S)-(+)-Glycidyl Ether min. 98.0 % | 16495-13-9 | 5G | ₹5000 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B2239 | Benzyl (S)-(+)-Glycidyl Ether min. 98.0 % | 16495-13-9 | 25G | ₹11900 | 2022-05-26 | Buy |
(S)-(+)-Benzyl glycidyl ether Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.
General Description
(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.
Safety Profile
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 266)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| ALTAIR ALCHEMY Laboratories | 91--9014276848 | Hyderabad, India | 324 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Supplier | Advantage |
|---|---|
| CHEMSWORTH | 30 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| A.J Chemicals | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| Reax Chemicals | 58 |
| ALTAIR ALCHEMY Laboratories | 58 |
| Clearsynth Labs | 58 |
| Souvenier Chemicals | 58 |
| Capot Chemical Co.,Ltd. | 60 |
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Benzyl (S)-(+)-Glycidyl Ether >
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(S)-BENZYL GLYCIDYL ETHER
(2S)-2-[(Benzyloxy)methyl]oxirane
(+)-Benzyl glycidyl ether
(S)-Benzylglycidyether
16495-13-9
Cd0H12O2
Asymmetric Synthesis
Epoxides
Organic Building Blocks
Oxiranes
Glycidyl Compounds, etc. (Chiral)
Simple 3-Membered Ring Compounds
Chiral Building Blocks
CHIRAL COMPOUNDS
Glycidyl Compounds, etc. (Chiral)
Oxiranes
Simple 3-Membered Ring Compounds
Synthetic Organic Chemistry
Chiral Compound
chiral
Chiral Building Blocks