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4-Hydroxy-3-methoxystyrene

4-Hydroxy-3-methoxystyrene Structure
CAS No.
7786-61-0
Chemical Name:
4-Hydroxy-3-methoxystyrene
Synonyms
2-METHOXY-4-VINYLPHENOL;4-VINYLGUAIACOL;p-Vinylguaiacol;4-VINYL-2-METHOXYPHENOL;4-Ethenyl-2-methoxyphenol;FEMA 2675;p-Vinyl guaicol;Methoxy-4-vinylphe;3-Methoxy-4-hydroxystyrene;Phenol, 4-ethenyl-2-methoxy-
CBNumber:
CB8172282
Molecular Formula:
C9H10O2
Molecular Weight:
150.17
MOL File:
7786-61-0.mol
MSDS File:
SDS
Modify Date:
2024/7/17 18:13:28

4-Hydroxy-3-methoxystyrene Properties

Melting point 25-29°C
Boiling point 224 °C(lit.)
Density 1.11 g/mL at 25 °C(lit.)
FEMA 2675 | 2-METHOXY-4-VINYLPHENOL
refractive index n20/D 1.582(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka 10.00±0.31(Predicted)
form Liquid
color Colourless to Off-White Oil
Odor at 0.10 % in dipropylene glycol. sweet spicy clove carnation phenolic peppery smoky woody powdery
Odor Type spicy
Water Solubility Miscible with water.
JECFA Number 725
BRN 2044521
Stability Light Sensitive
LogP 1.93
CAS DataBase Reference 7786-61-0(CAS DataBase Reference)
NIST Chemistry Reference 2-Methoxy-4-vinylphenol(7786-61-0)
EPA Substance Registry System Phenol, 4-ethenyl-2-methoxy- (7786-61-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  SL8205000
TSCA  Yes
HS Code  29095000
NFPA 704
0
2 0

4-Hydroxy-3-methoxystyrene price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W267511 2-Methoxy-4-vinylphenol ≥98%, FG 7786-61-0 1SAMPLE-K ₹15414.8 2022-06-14 Buy
Sigma-Aldrich(India) W267511 2-Methoxy-4-vinylphenol ≥98%, FG 7786-61-0 25G ₹18683.95 2022-06-14 Buy
Sigma-Aldrich(India) W267511 2-Methoxy-4-vinylphenol ≥98%, FG 7786-61-0 100G ₹45778.93 2022-06-14 Buy
Sigma-Aldrich(India) W267511 2-Methoxy-4-vinylphenol ≥98%, FG 7786-61-0 1KG ₹153476.85 2022-06-14 Buy
Sigma-Aldrich(India) 89189 2-Methoxy-4-vinylphenol analytical standard, contains 100?ppm BHT as inhibitor 7786-61-0 100MG ₹5260.95 2022-06-14 Buy
Product number Packaging Price Buy
W267511 1SAMPLE-K ₹15414.8 Buy
W267511 25G ₹18683.95 Buy
W267511 100G ₹45778.93 Buy
W267511 1KG ₹153476.85 Buy
89189 100MG ₹5260.95 Buy

4-Hydroxy-3-methoxystyrene Chemical Properties,Uses,Production

Chemical Properties

2-Methoxy-4-vinylphenol has a powerful, spicy, apple, rum, roasted peanut aroma.

Occurrence

Reported found among the steam-distillable phenols from the alcoholic fermentation of cereal grains, especially corn; probably formed from ferulic acid. Reported found in tobacco, beans, coffee, malt, apple, grapefruit juice, grapes, raspberry, strawberry, asparagus, kohlrabi, carrot, celery, tomato, rye bread, smoked fish, cured pork, beer, cognac, rum, cider, sherry, grape wines, coffee, tea, peanut, popcorn,soybean, passion fruit, beans,starfruit,sesame seed, mango, cauliflower, tamarind, fig, corianderseed, rice, quince, rhubarb, dill, lovage root, corn oil, sweet corn, malt, wort, Texas sage, okra, cuttlefish and Chinese quince.

Uses

p-Vinylguaiacol is an aromatic substance and one of the compounds responsible for the natural aroma of buckwheat. It is also one of the major pyrolytic products of (E)-N-[(4-hydroxy-3-methoxy)-phenethyl]-3-[(3-methoxy-4-O-β-D-glucopyranosyloxy) phenyl] acrylamide; a new gycloside in tobacco.

Preparation

From vanillin by reacting with acetic anhydride and sodium acetate yielding 3-methoxy-4-hydroxycinnamic acid on sub sequent hydrolysis; the latter, heated with quinoline in the presence of hydroquinone, is decarboxylated to 4-vinylguaiacol.

Definition

ChEBI: A member of the class of phenols that is guaiacol in which the hydrogen para- to the hydroxy group is replaced by a vinyl group.

General Description

2-Methoxy-4-vinylphenol is one of the key volatile aroma compounds of buckwheat and okra.

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2-methoxy-4-vinyl-pheno 2-methoxy-4-vinylphenol (vinylguaiacol) 2-metoxy-4-vinyl-phenol 4-ethenyl-2-methoxy-pheno 4-ethenyl-2-methoxy-Phenol 4-Vinyl-2-methoxyphenol (4-vinylguaiacol) o-methoxy-p-vinylphenol Phenol, 2-methoxy-4-ethenyl Phenol, 2-methoxy-4-vinyl- Phenol, 4-vinyl, 2-methoxy P-VINYL CATECHOL-O-METHYL ETHER VINYL GUAIACOL 2-Methoxy-4-vinylphenol, stab. with 0.01% BHT 4-HYDROXY-3-METHOXYSTYRENE 4-Hydroxy-3-methoxystyrene~4-Vinylguaiacol 4-Vinyl guaicol 2-METHOXY-4-VINYLPHENOL 98+% p-vinylguaiacol,2-methoxy-4-vinylphenol,p-vinylcatechol-o-methylether,4-ethenyl-2-methoxyphenol 3-Methoxy-4-vinylphenol 2-Methoxy-4-vinylphenol, 97%, stabilized 2-Methoxy-4-vinylphenol, 97%, stab. with 0.01% BHT 4-VINYL GUAIACOL 1% IN P.G. NATURAL 4-VINYL GUAIACOL NATURAL 4-VINYLGUAIACOL IN 10% P.G. 4-VINYLGUAIACOL PURE 2-Methoxy-4-ethenylphenol 2-Methoxy-4-vinylphenol, stabilized with 0.01% BHT 2-Methoxy-4-vinylphenol, 98%, stabilized with 0.01% BHT 4-ethenyl-2-meth 4-Hydroxy-3-methoxystyrene phenols 2-Methoxy-4-vinyL 4-Hydroxy-3-methoxystyrene USP/EP/BP 4-VINYL GUAIACOL10%PG Guaiacol Impurity 1 2-Methoxy-4-vinylphenol (4-vinylguaiacol) 4-Ethenyl-2-methoxyphenol Phenol, 4-ethenyl-2-methoxy- p-Vinyl guaicol p-Vinylguaiacol 2-METHOXY-4-VINYLPHENOL 4-VINYL-2-METHOXYPHENOL 4-VINYLGUAIACOL FEMA 2675 Methoxy-4-vinylphe 3-Methoxy-4-hydroxystyrene 2-Methoxy-4-vinylphenol, 97%, stabilized with 0.01% BHT 7786-61-0 CH3OC6H3CHCH2OH Alphabetical Listings Flavors and Fragrances M-N phenol Flavor Aromatic Phenols Pharmaceutical Raw Materials