p-Tolunitrile
- CAS No.
- 104-85-8
- Chemical Name:
- p-Tolunitrile
- Synonyms
- CNT;4-METHYLBENZONITRILE;4-TOLUNITRILE;P-CYANO TOLUENE;4-methylcyanobenzene;p-Tolunitril;P-Tounitrile;P-TOLUNITRILE;p-Tolumitrile;p-Toluonitril
- CBNumber:
- CB8223531
- Molecular Formula:
- C8H7N
- Molecular Weight:
- 117.15
- MOL File:
- 104-85-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/5 17:42:12
| Melting point | 26-28 °C(lit.) |
|---|---|
| Boiling point | 103-106 °C20 mm Hg(lit.) |
| Density | 0.981 g/mL at 25 °C(lit.) |
| refractive index | 1.5285-1.5305 |
| Flash point | 185 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: very soluble |
| form | Viscous Liquid |
| color | Clear |
| Specific Gravity | 0.981 |
| Water Solubility | <0.1 g/100 mL at 17 ºC |
| Merck | 14,9538 |
| BRN | 507386 |
| Exposure limits | NIOSH: IDLH 25 mg/m3 |
| Stability | Stable. Incompatible with strong oxidizing agents, strong bases. |
| InChIKey | VCZNNAKNUVJVGX-UHFFFAOYSA-N |
| CAS DataBase Reference | 104-85-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzonitrile, 4-methyl-(104-85-8) |
| EPA Substance Registry System | p-Tolunitrile (104-85-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H334-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P302+P352-P304+P340+P312-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-43-36/38 | |||||||||
| Safety Statements | 26-36/37-37-36 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | XV0700000 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29269095 | |||||||||
| NFPA 704 |
|
p-Tolunitrile price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 132330 | p-Tolunitrile 98% | 104-85-8 | 25G | ₹3431.53 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 132330 | p-Tolunitrile 98% | 104-85-8 | 100G | ₹3864.53 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 132330 | p-Tolunitrile 98% | 104-85-8 | 500G | ₹11474.5 | 2022-06-14 | Buy |
| ALFA India | ALF-B23029-30 | p-Tolunitrile, 98+% | 104-85-8 | 250g | ₹5749 | 2022-05-26 | Buy |
| ALFA India | ALF-B23029-18 | p-Tolunitrile, 98+% | 104-85-8 | 50g | ₹2862 | 2022-05-26 | Buy |
p-Tolunitrile Chemical Properties,Uses,Production
Chemical Properties
This substance is a clear colorless liquid or beige solid that exhibits toxicity and flammability. It should avoid contact with the skin.
Uses
p-Tolunitrile is a reagent used in the preparation of 1H-Indazoles from imidates and nitrosobenzenes.
General Description
Beige solid at 62.6° F.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Nitriles, such as p-Tolunitrile, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.
Fire Hazard
p-Tolunitrile is combustible.
Purification Methods
Melt the nitrile, dry it with MgSO4, fractionally crystallise it from its melt, then fractionally distil it under reduced pressure in a 6-in spinning band column. [Brown J Am Chem Soc 81 3232 1959.] It can also be crystallised from *benzene/pet ether (b 40-60o). [Beilstein 9 H 489, 9 I 194, 9 II 330, 9 III 2348, 9 IV 1738.]
p-Tolunitrile Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Anami Organics | +91-9662506075 +91-9825113634 | Gujarat, India | 58 | 58 | Inquiry |
| Snap Intermediates | 08048372491Ext 383 | Mumbai, India | 110 | 58 | Inquiry |
| Spectrochem Private Limited | 08048372608Ext 246 | Maharashtra, India | 1056 | 58 | Inquiry |
| Azole Rasayanas India Private Limited | 91-40-29707735 | Hyderabad, India | 684 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Innovative Synthetic Molecules | +91 40-24111684 | Hyderabad, India | 527 | 58 | Inquiry |
| Anand Agencies | 91-20-24454597 | Maharashtra, India | 2337 | 58 | Inquiry |
| P C Chem | +91-8046061281 | Mumbai, India | 676 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| JSK Chemicals | 58 |
| Anami Organics | 58 |
| Snap Intermediates | 58 |
| Spectrochem Private Limited | 58 |
| Azole Rasayanas India Private Limited | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Innovative Synthetic Molecules | 58 |
| Anand Agencies | 58 |
| P C Chem | 58 |