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2,3-Dimethylaniline

2,3-Dimethylaniline Structure
CAS No.
87-59-2
Chemical Name:
2,3-Dimethylaniline
Synonyms
2,3-XYLIDINE;o-Xylidine;CN-CBL;AKOS 91128;2,3-XYLIDENE;2,3-Xylylamine;VIC-O-XYLIDINE;ortho-xylidine;XYLIDINE (MIXED);3-AMINO-O-XYLENE
CBNumber:
CB8256854
Molecular Formula:
C8H11N
Molecular Weight:
121.18
MOL File:
87-59-2.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

2,3-Dimethylaniline Properties

Melting point 2.5 °C (lit.)
Boiling point 221-222 °C (lit.)
Density 0.993 g/mL at 25 °C (lit.)
vapor density 4.2 (vs air)
vapor pressure 0.13 hPa (25 °C)
refractive index n20/D 1.569(lit.)
Flash point 205 °F
storage temp. Store below +30°C.
solubility 1.5g/l
pka pK1:4.70(+1) (25°C)
form Liquid
color Clear yellow to red-brown
explosive limit 1-2.7%(V)
Water Solubility 30 g/L (20 ºC)
Merck 14,10084
BRN 742174
Stability Stable. Combustible. Incompatible with strong oxidizing agents. Reacts with hypochlorite bleaches. May be light sensitive.
CAS DataBase Reference 87-59-2(CAS DataBase Reference)
NIST Chemistry Reference Benzenamine, 2,3-dimethyl-(87-59-2)
EPA Substance Registry System 2,3-Dimethylaniline (87-59-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H373-H411
Precautionary statements  P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314
Hazard Codes  T,N
Risk Statements  23/24/25-33-51/53
Safety Statements  28-36/37-45-61-28A
RIDADR  UN 1711 6.1/PG 2
WGK Germany  2
RTECS  ZE8750000
Autoignition Temperature 545 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214910
NFPA 704
1
3 0

2,3-Dimethylaniline price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D145807 2,3-Dimethylaniline 99% 87-59-2 100G ₹4037.73 2022-06-14 Buy
Sigma-Aldrich(India) D145807 2,3-Dimethylaniline 99% 87-59-2 500G ₹9471.88 2022-06-14 Buy
Sigma-Aldrich(India) 8.21222 2,3-Dimethylaniline for synthesis 87-59-2 5ML ₹4940 2022-06-14 Buy
Sigma-Aldrich(India) 8.21222 2,3-Dimethylaniline for synthesis 87-59-2 250ML ₹6280 2022-06-14 Buy
TCI Chemicals (India) D0666 2,3-Dimethylaniline min. 99.0 % 87-59-2 25G ₹1500 2022-05-26 Buy
Product number Packaging Price Buy
D145807 100G ₹4037.73 Buy
D145807 500G ₹9471.88 Buy
8.21222 5ML ₹4940 Buy
8.21222 250ML ₹6280 Buy
D0666 25G ₹1500 Buy

2,3-Dimethylaniline Chemical Properties,Uses,Production

Chemical Properties

brown liquid

Uses

Reagent used in the preparation of non-steroidal anti-inflammatory drugs, dyes and pesticides.

General Description

Dark brown liquid.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

2,3-Dimethylaniline reacts with strong oxidizing agents and hypochlorite bleaches . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

2,3-Dimethylaniline is combustible.

Safety Profile

A poison. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also other xylidine entries.

Purification Methods

Purify vic-xylidine by conversion into a derivative (see below), recrystallise the derivative, decompose the derivative with aqueous NaOH and fractionally distil the liquid base. The acetyl derivative has m 135o (from EtOH), and the formyl derivative has m 102o (from EtOH). [Beilstein 12 H 1101, 12 III 2438, 12 IV 2497.]

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1-AMINO-2,3-DIMETHYLBENZENE 2,3-DIMETHYLANILINE 2,3-Dimethylphenylamine 2,3-Xylylamine 2,3-XYLIDENE AKOS BBS-00003566 AKOS 91128 3-AMINO-O-XYLENE CN-CBL VIC-O-XYLIDINE XYLIDINE (MIXED) 1-AMINO-2,3-DIMETHYLAMINE 2,3-DIMETHYLANILINE / 2,3-XYLIDINE 2,3-DIMETHYLANALINE 2,3-XYLIDENE (2,3-DIMETHYLANILINE) Xylidine, o-: (2,3-Xylidine) 1-Amino-2,3-dimethylbenzene, 2,3-Xylidine, 3-Amino-o-xylene, CN-Cbl 2,3-Dimethylaniline,99% ,3-Dimethylaniline 2,3-Dimethylaniline,1-Amino-2,3-dimethylbenzene, 2,3-Xylidine, 3-Amino-o-xylene, CN-Cbl 2,3-DIMETHYLBENZAMINE 2,3-Dimethylanilin 2,3-DiMethylaniline, 99% 500ML 2,3-Xylidine vic-o-Xylidine 1-amino-2,3-dimethyl-benzen Benzenamine,2,3-dimethyl- ortho-xylidine 2,3-Dimethylaniline,98% 2,3-dimethyl-benzenamin 2,3-Dimethylbenzenamine 2,3-dimethyl-Benzenamine 2,3-Dimethylbenzeneamine 2,3-Dimethyianiline 2,3-Xylidine (NH2=1) 2,3-Dimethylaniline > 2,3-DIMETHYLANILINE FOR SYNTHESIS 2-2,3-Xylidine CAS No. 87-59-2 o-Xylidine 2,3-XYLIDINE Mefenamic Acid EP Impurity A Mefenamic Acid Impurity 1(Mefenamic Acid EP Impurity A) Mefenamic acid impurity A CRS Mefenamic Acid Impurity 1 CRS(Mefenamic Acid EP Impurity A CRS) 87-59-2 C8H12N 87592 Building Blocks Amines C8 Organic Building Blocks Nitrogen Compounds Intermediates Amines Aromatics Intermediates of Dyes and Pigments bc0001