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4-bromo-2,1,3-benzothiadiazole

4-bromo-2,1,3-benzothiadiazole Structure
CAS No.
22034-13-5
Chemical Name:
4-bromo-2,1,3-benzothiadiazole
Synonyms
BT-BR;AKOS BBS-00002903;IFLAB-BB F1918-0061;4-BROMO-2,1,3-BENZOTHIAZOLE;4-bromo-2,1,3-benzothiadiazoL;4-BROMO-2,1,3-BENZOTHIADIAZOLE;4-Bromobenzo[2,1,3]thiadiazole;4-Bromo-benzo[1,2,5]thiadiazole;2,1,3-Benzothiadiazole, 4-bromo-;4-BroMobenzo[c][1,2,5]thiadiazole
CBNumber:
CB8376884
Molecular Formula:
C6H3BrN2S
Molecular Weight:
215.07
MOL File:
22034-13-5.mol
MSDS File:
SDS
Modify Date:
2024/2/19 11:36:23

4-bromo-2,1,3-benzothiadiazole Properties

Melting point 80 °C
Boiling point 272.2±13.0 °C(Predicted)
Density 1.859±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka -1.02±0.45(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  Xi,Xn
Risk Statements  22
HS Code  2934999090

4-bromo-2,1,3-benzothiadiazole Chemical Properties,Uses,Production

Uses

The Sonogashira cross-coupling reaction between 4-bromo-2, 1,3-benzothiadiazole, and the respective para-substituted phenylethynyl derivatives could synthesize the BTDs. In addition, the BTD-Ph is prepared by reacting 4-bromo-2,1,3-benzothiadiazole (Br-BTD)and palladium-MAI catalyst, and the dynamic phenylboronic acid reagent in the starting system or dynamic o-amino pyridine reagent[1-2].

References

[1] Pradhan, Asit Kumar et al. “Effects of donor and acceptor substituents on the photophysics of 4-ethynyl-2,1,3-benzothiadiazole derivatives?.” Physical Chemistry Chemical Physics 42 (2023): 29327–29340.
[2] AMARO DA SILVEIRA NETO B; CORREA J R; OLIVEIRA CARVALHO T; PIMENTA ROCHA CARVALHO P. "Selective cellular markers in selective cellular imaging of organelles such as mitochondria, nucleus and other organelles, are derived from 4-bromo-2,1,3-benzothiadiazole nucleus via homogeneous catalysis of palladium complex" BR102016025541(A2)

4-bromo-2,1,3-benzothiadiazole Preparation Products And Raw materials

4-bromo-2,1,3-benzothiadiazole Suppliers

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IFLAB-BB F1918-0061 4-BROMO-2,1,3-BENZOTHIADIAZOLE AKOS BBS-00002903 4-BROMO-2,1,3-BENZOTHIAZOLE 4-BroMobenzo[c][1,2,5]thiadiazole 4-Bromo-benzo[1,2,5]thiadiazole 4-Bromobenzo[2,1,3]thiadiazole BT-BR 6-bromobenzo[c][1,2,5]7-thiadiazole 4-bromo-2,1,3-benzothiadiazoL 2,1,3-Benzothiadiazole, 4-bromo- 22034-13-5 2034-13-5 Pyridines Halides Oxadiazoles & Thiadiazoles Oxadiazoles & Thiadiazoles