Ruthenium(III) chloride hydrate
- CAS No.
- 14898-67-0
- Chemical Name:
- Ruthenium(III) chloride hydrate
- Synonyms
- RUTHENIUM TRICHLORIDE HYDRATE;RUTHENIUM(III) CHLORIDE HYDRATE;RUTHENIUM CHLORIDE HYDRATE;Ruthenium(III) chloride xhydrate;RUTHENIUM(III) CHLORIDE HYDRATE14898-67-0;Aluminium oxide,active;RuodiuM Chloride Hydrate;Active oxidative aluminum;Ruthenium(3+) trichloride;Trichlororuthenium hydrate
- CBNumber:
- CB9142235
- Molecular Formula:
- Cl3H2ORu
- Molecular Weight:
- 225.44
- MOL File:
- 14898-67-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/16 17:35:19
| Melting point | >300°C |
|---|---|
| Density | 3.11 g/cm3 |
| storage temp. | Store at +5°C to +30°C. |
| solubility | Water (Slightly) |
| form | Powder |
| color | Dark brown to black |
| PH | <2 (H2O, 20℃)Aqueous solution |
| Water Solubility | soluble |
| Sensitive | Hygroscopic |
| Merck | 14,8302 |
| Stability | hygroscopic |
| InChI | InChI=1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3 |
| InChIKey | BIXNGBXQRRXPLM-UHFFFAOYSA-K |
| SMILES | [Ru](Cl)(Cl)Cl.O |
| CAS DataBase Reference | 14898-67-0(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314-H411 | |||||||||
| Precautionary statements | P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34-52/53-22 | |||||||||
| Safety Statements | 26-36/37/39-45-61 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | VM2650000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2843 90 90 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
Ruthenium(III) chloride hydrate price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 463779 | Ruthenium(III) chloride hydrate 99.98% trace metals basis | 14898-67-0 | 1G | ₹2510 | 2022-06-14 | Buy |
| Sigma-Aldrich | 206229 | Ruthenium(III) chloride hydrate ReagentPlus? | 14898-67-0 | 1G | ₹2630.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 206229 | Ruthenium(III) chloride hydrate ReagentPlus? | 14898-67-0 | 1G | ₹2630.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 463779 | Ruthenium(III) chloride hydrate 99.98% trace metals basis | 14898-67-0 | 5G | ₹8230 | 2022-06-14 | Buy |
| Sigma-Aldrich | 206229 | Ruthenium(III) chloride hydrate ReagentPlus? | 14898-67-0 | 5G | ₹8502.6 | 2022-06-14 | Buy |
Ruthenium(III) chloride hydrate Chemical Properties,Uses,Production
Chemical Properties
Ruthenium(III) chloride hydrate appears as dark brown to black powder. It cannot dissolve in cold water or carbon disulfide, but it can decompose in hot water. It is also insoluble in ethanol, but it can dissolve in hydrochloric acid. When combined with potassium iodide solution, it forms a precipitate of iodide. When reacted with hydrogen sulfide, it forms a precipitate of ruthenium trisulfide. It can react with ammonia, potassium cyanide, and potassium nitrite to form corresponding ammonia, cyanide, and nitroso complexes. It can also be reduced to blue divalent ruthenium ions by sodium amalgam or titanium trichloride.
Uses
Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.
Preparation
Ruthenium(III) chloride hydrate can be synthesized by directly combining ruthenium metal and chlorine at high temperature. Alternatively, adding hydrochloric acid to ruthenium hydroxide and subsequently evaporating, concentrating, and crystallizing the mixture can also produce the desired compound.
General Description
Ruthenium(III) chloride hydrate, also called Ruthenium(III) trichloride hydrate, is widely used as a starting material in Ruthenium chemistry. It is used in the determination of sulfites, the manufacture of chlororuthenates, and as an electrode coating material.
Purification Methods
Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].
Ruthenium(III) chloride hydrate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Johnson Matthey Chemicals India Pvt Ltd | +91-9820622275 +91-9711869003 | Maharashtra, India | 69 | 58 | Inquiry |
| Vineeth Precious Catalysts Pvt Ltd | +91-9049600004 +91-9049600004 | Mumbai, India | 29 | 58 | Inquiry |
| Dhara Industries | +91-9322395199 +91-9322395199 | Mumbai, India | 190 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Aritech Chemazone Private Limited | +91-9034345475 | Punjab, India | 684 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Evans Fine Chem | 58 |
| JSK Chemicals | 58 |
| Johnson Matthey Chemicals India Pvt Ltd | 58 |
| Vineeth Precious Catalysts Pvt Ltd | 58 |
| Dhara Industries | 58 |
| CHEMSWORTH | 30 |
| CLEARSYNTH LABS LTD. | 58 |
| Aritech Chemazone Private Limited | 58 |
| Central Drug House(P) Ltd. | 58 |
| Triveni chemicals | 58 |
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