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trans-Cinnamaldehyde

trans-Cinnamaldehyde Structure
CAS No.
14371-10-9
Chemical Name:
trans-Cinnamaldehyde
Synonyms
(E)-Cinnamaldehyde;3-Phenyl-2-propenal;STYRONE;(2E)-3-Phenylprop-2-enal;FEMA 2286;3-PHENYLPROPENAL;(E)-3-Phenylpropenal;trans-Cinnamylaldehyde;(e)-3-phenyl-2-propenal;Cinna-mal
CBNumber:
CB9168460
Molecular Formula:
C9H8O
Molecular Weight:
132.16
MOL File:
14371-10-9.mol
MSDS File:
SDS
Modify Date:
2024/4/26 17:21:34

trans-Cinnamaldehyde Properties

Melting point −9-−4 °C(lit.)
Boiling point 250-252 °C(lit.)
Density 1.05 g/mL at 25 °C(lit.)
vapor density 4.6 (vs air)
refractive index n20/D 1.622(lit.)
FEMA 2286 | CINNAMALDEHYDE
Flash point 160 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), DMSO (Sparingly), Methanol (Slightly)
form Liquid
color Clear yellow
Odor at 10.00 % in dipropylene glycol. sweet spice candy cinnamon red hots warm
Odor Type spicy
Water Solubility 1.1 g/L (20 ºC)
Sensitive Air Sensitive
Merck 14,2297
JECFA Number 656
BRN 1071571
Dielectric constant 16.899999999999999
Stability Hygroscopic
LogP 1.820
CAS DataBase Reference 14371-10-9(CAS DataBase Reference)
NIST Chemistry Reference Cinnamaldehyde, (E)-(14371-10-9)
EPA Substance Registry System trans-Cinnamaldehyde (14371-10-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-43-21
Safety Statements  26-36/37-37/39-24
WGK Germany  3
RTECS  GD6476000
10-23
HS Code  29122990
NFPA 704
2
2 1

trans-Cinnamaldehyde price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W228605 trans-Cinnamaldehyde FCC, FG 14371-10-9 1SAMPLE-K ₹5141.88 2022-06-14 Buy
Sigma-Aldrich(India) W228605 trans-Cinnamaldehyde FCC, FG 14371-10-9 1KG ₹6852.23 2022-06-14 Buy
Sigma-Aldrich(India) W228605 trans-Cinnamaldehyde FCC, FG 14371-10-9 10KG ₹22418.58 2022-06-14 Buy
Sigma-Aldrich(India) W228605 trans-Cinnamaldehyde FCC, FG 14371-10-9 25KG ₹41697.9 2022-06-14 Buy
Sigma-Aldrich(India) C80687 trans-Cinnamaldehyde 99% 14371-10-9 25G ₹2284.08 2022-06-14 Buy
Product number Packaging Price Buy
W228605 1SAMPLE-K ₹5141.88 Buy
W228605 1KG ₹6852.23 Buy
W228605 10KG ₹22418.58 Buy
W228605 25KG ₹41697.9 Buy
C80687 25G ₹2284.08 Buy

trans-Cinnamaldehyde Chemical Properties,Uses,Production

Chemical Properties

trans-Cinnamaldehyde is the main component of cassia oil (about 90%) and Sri Lanka cinnamon bark oil (about 75%). Smaller quantities are found in many other essential oils. In nature, the trans-isomer is predominant.
trans-Cinnamaldehyde is a yellowish liquid with a characteristic spicy odor, strongly reminiscent of cinnamon. Being an ??,??-unsaturated aldehyde, it undergoes many reactions, of which hydrogenation to cinnamic alcohol, dihydrocinnamaldehyde, and dihydrocinnamic alcohol is important. Cinnamic acid is formed by autoxidation.
On an industrial scale, cinnamaldehyde is prepared almost exclusively by alkaline condensation of benzaldehyde and acetaldehyde. Self-condensation of acetaldehyde can be avoided by using an excess of benzaldehyde and by slowly adding acetaldehyde.
Cinnamaldehyde is used in many compositions for creating spicy and oriental notes (e.g., soap perfumes). It is the main component of artificial cinnamon oil. In addition, it is an important intermediate in the synthesis of cinnamic alcohol and dihydrocinnamic alcohol.

Uses

trans-Cinnamaldehyde is used in the flavor and perfume industry. It is also used in medicine. It reacts with glutathione to get an adduct 1'-(glutathion-S-yl)-dihydrocinnamaldehyde. It is used to prepare cinnamylidene-bisacetamide by reacting with acetamide. Further, it inhibits xanthine oxidase.

Definition

ChEBI: The E (trans) stereoisomer of cinnamaldehyde, the parent of the class of cinnamaldehydes.

General Description

Clear yellow liquid with an odor of cinnamon and a sweet taste.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

trans-Cinnamaldehyde is incompatible with strong oxidizing agents and strong bases. trans-Cinnamaldehyde can also react with sodium hydroxide.

Fire Hazard

trans-Cinnamaldehyde is combustible.

Potential Exposure

Botanical fungicide and insecticide. Used as an antifungal agent, corn rootworm attractant, and dog and cat repellent. Can be used on soil casing for mushrooms, row crops, turf, and all food commodities. Not listed for use in EU countries.

Shipping

UN1989 Aldehydes, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid

Incompatibilities

Aldehydes are frequently involved in selfcondensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, ketones, azo dyes, caustics, boranes, hydrazines

Waste Disposal

Incineration. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Global( 372)Suppliers
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