alpha-Hexylcinnamaldehyde
- CAS No.
- 101-86-0
- Chemical Name:
- alpha-Hexylcinnamaldehyde
- Synonyms
- HCA;HEXYL CINNAMIC ALDEHYDE;HEXYL CINNAMAL;JASMONAL H;HEXYLCINNAMALDEHYDE;FEMA 2569;2-Benzylideneoctanal;α-Hexylcinnamaldehyde;n-Hexyl cinnamaldehyde;2-(phenylmethylene)-Octanal
- CBNumber:
- CB2154127
- Molecular Formula:
- C15H20O
- Molecular Weight:
- 216.32
- MOL File:
- 101-86-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/19 22:55:17
| Boiling point | 174-176 °C/15 mmHg (lit.) |
|---|---|
| Density | 0.95 g/mL at 25 °C (lit.) |
| FEMA | 2569 | ALPHA-HEXYLCINNAMALDEHYDE |
| refractive index |
n |
| Flash point | 200 °F |
| storage temp. | -20°C |
| solubility | water: soluble0.005g/L at 25°C |
| form | Oil |
| color | Clear Yellow |
| Odor | at 100.00 %. fresh floral green jasmin herbal waxy |
| Odor Type | floral |
| JECFA Number | 686 |
| Stability | Hygroscopic |
| LogP | 5.33 |
| CAS DataBase Reference | 101-86-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Octanal, 2-(phenylmethylene)-(101-86-0) |
| EPA Substance Registry System | .alpha.-Hexylcinnamaldehyde (101-86-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H410 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 36/37/38-34-43-52/53 | |||||||||
| Safety Statements | 26-36/37/39-45-36-36/37-61 | |||||||||
| RIDADR | UN 3265 8/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | GD6560000 | |||||||||
| HS Code | 29122990 | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 3.1 g/kg (2.45-3.75 g/kg) (Moreno, 1971). The acute dermal LD50 value in rabbits was reported as > 3 g/kg (Moreno, 1971). | |||||||||
| NFPA 704 |
|
alpha-Hexylcinnamaldehyde price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W256900 | α-Hexylcinnamaldehyde ≥95%, stabilized, FG | 101-86-0 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256900 | α-Hexylcinnamaldehyde ≥95%, stabilized, FG | 101-86-0 | 1KG | ₹6852.23 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256900 | α-Hexylcinnamaldehyde ≥95%, stabilized, FG | 101-86-0 | 5KG | ₹18218.48 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256900 | α-Hexylcinnamaldehyde ≥95%, stabilized, FG | 101-86-0 | 10KG | ₹32236.85 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | CRM40685 | alpha-Hexylcinnamaldehyde solution certified reference material, 2000?μg/mL in methanol, ampule of 1?mL | 101-86-0 | 1ML | ₹9443 | 2022-06-14 | Buy |
alpha-Hexylcinnamaldehyde Chemical Properties,Uses,Production
Description
α-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.
Chemical Properties
alpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.
Occurrence
Reported found in cooked, scented rice.
Uses
α-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.
Preparation
By condensation of octylaldehyde with benzaldehyde
Definition
ChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.
General Description
Solubilization of α-hexylcinnamaldehyde by the ionic surfactants, sodium dodecyl sulfate and dodecyltrimethylammonium chloride and a non-ionic surfactant such as dodecyl polyoxyethylene ethers has been investigated.
Hazard
Combustible.
Contact allergens
Hexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.
Solubility in organics
Insoluble in Propylene glycol and Glycerin. Soluble in alcohol, miscible with oils.
alpha-Hexylcinnamaldehyde Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Jayshree Aromatics Pvt.Ltd. | +91-9925031256 +91-9925031256 | Gujarat, India | 89 | 58 | Inquiry |
| Nagar Haveli Perfumes & Aromatics | +917506551149 | Mumbai, India | 230 | 58 | Inquiry |
| Eternis Fine Chemicals Ltd | +91-2266513400 +91-2266513400 | Maharashtra, India | 9 | 58 | Inquiry |
| Pharmaffiliates Analytics & Synthetics (P) Ltd. | 91-172-5066494 | Haryana, India | 631 | 58 | Inquiry |
| Fine Fragrances Pvt. Ltd. | 91-22-22023834 | Maharashtra, India | 15 | 58 | Inquiry |
| Global Flavors and Fragrances | +91-22-2407 7476 | Mumbai, India | 45 | 58 | Inquiry |
| Nagar Haveli Perfumes & Aromatics | +91 9867078149 | Mumbai, India | 149 | 58 | Inquiry |
| Oswal Chemicals | 08047634574 | Ahmedabad, India | 40 | 58 | Inquiry |
| Eternis Fine Chemicals Ltd | 91-22-66513400 | Maharashtra, India | 6 | 58 | Inquiry |
| Associate Allied Chemicals (India) Pvt., Ltd. | 91-22-24198800 | Maharashtra, India | 36 | 58 | Inquiry |