alpha-Amylcinnamaldehyde
- CAS No.
- 122-40-7
- Chemical Name:
- alpha-Amylcinnamaldehyde
- Synonyms
- ACA;Flomine;NSC6649;JASMINAL;NSC 6649;NSC-6649;FEMA 2061;alpha-Amyl;AMYL CINNAMAL;FEMA No. 2061
- CBNumber:
- CB2169958
- Molecular Formula:
- C14H18O
- Molecular Weight:
- 202.29
- MOL File:
- 122-40-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/3 13:03:20
| Melting point | 80°C |
|---|---|
| Boiling point | 287-290 °C(lit.) |
| Density | 0.97 g/mL at 25 °C(lit.) |
| vapor pressure | 0.133Pa at 25℃ |
| FEMA | 2061 | ALPHA-AMYLCINNAMALDEHYDE |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in alcohol and perfume materials. Insoluble in water. |
| color | Pale-yellow oil or liquid |
| Odor | floral jasmine odor |
| Odor Type | floral |
| Water Solubility | 181.69mg/L at 25℃ |
| JECFA Number | 685 |
| LogP | 2.498 at 25℃ |
| CAS DataBase Reference | 122-40-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Heptanal, 2-(phenylmethylene)-(122-40-7) |
| EPA Substance Registry System | 2-(Phenylmethylene)heptanal (122-40-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H411 | |||||||||
| Precautionary statements | P280 | |||||||||
| Hazard Codes | Xi,N | |||||||||
| Risk Statements | 36/37/38-51/53-43 | |||||||||
| Safety Statements | 26-37/39-61-36/37 | |||||||||
| RIDADR | UN 3082 9 / PGIII | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | GD6825000 | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29122990 | |||||||||
| Toxicity | LD50 orl-rat: 3730 mg/kg FCTXAV 2,327,64 | |||||||||
| NFPA 704 |
|
alpha-Amylcinnamaldehyde price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W206120 | α-Amylcinnamaldehyde mixture of cis and trans, ≥97%, natural, FG | 122-40-7 | 1SAMPLE-K | ₹5196 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W206120 | α-Amylcinnamaldehyde mixture of cis and trans, ≥97%, natural, FG | 122-40-7 | 100G | ₹8486.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W206105 | α-Amylcinnamaldehyde mixture of cis and trans, ≥97%, stabilized, FG | 122-40-7 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W206120 | α-Amylcinnamaldehyde mixture of cis and trans, ≥97%, natural, FG | 122-40-7 | 1KG | ₹48236.2 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W206105 | α-Amylcinnamaldehyde mixture of cis and trans, ≥97%, stabilized, FG | 122-40-7 | 1KG | ₹7339.35 | 2022-06-14 | Buy |
alpha-Amylcinnamaldehyde Chemical Properties,Uses,Production
Description
Amylcinnamic aldehyde is an oxidation product of amylcinnamic alcohol, one component of the "fragrance mix" and can be found as a sensitizer in cases of contact dermatitis in bakers.
Chemical Properties
alpha-Amylcinnamaldehyde has been identified
as an aroma volatile of black tea. It is a light yellow liquid with a floral, slightly
fatty odor, which becomes reminiscent of jasmine when diluted.The aldehyde is
relatively unstable and must be stabilized by antioxidants.
It is prepared from benzaldehyde and heptanal in the same way as cinnamaldehyde.
??-Amylcinnamaldehyde is a very popular fragrance substance for creating jasmine
notes. It is stable to alkali and long-lasting; large quantities are used, particularly
in soap perfumes.
Occurrence
Reported found in black tea and soybean
Uses
amyl cinnamal is used as a fragrance. Although it is naturally occurring in some plants, it is most often synthetically derived when used in cosmetic products.
Preparation
By condensation of n-amyl aldehyde with cinnamic aldehyde. This method of condensation of aromatic aldehydes with aliphatic aldehydes has the maximum yield in α-amylcinnamic aldehyde with little formation of the inferior homologs. The methyl, ethyl and propyl amylcinnamic aldehyde analogs exhibit a characteristic scent.
General Description
The short-term feeding studies in rats was carried out using α-amylcinnamaldehyde, a flavouring matter.
Contact allergens
a-Amyl-cinnamic aldehyde is an oxidation product of amylcinnamic alcohol, a sensitizing fragrance, and one component of the “fragrance mix.” It can also be a sensitizer in bakers. It has to be mentioned by name in cosmetics within the EU.
Safety Profile
Moderately toxic by ingestion. A severe skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
Metabolism
So far as is known, all aromatic aldehydes are metabolized in the animal body by oxidation to the corresponding acids. In some instances, the aldehydes are excreted as glucuronides. Cinnamic aldehyde is oxidized to cinnamic acid which is then degraded to benzoic acid, but ethyl cinnamic aldehyde is oxidized to the corresponding acid and is not further metabolized(Williams, 1959).
alpha-Amylcinnamaldehyde Preparation Products And Raw materials
Raw materials
1of2
chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Rsum Industries Pvt. Ltd. | +91-91062685255 +91-91062685255 | New Delhi, India | 29 | 58 | Inquiry |
| Nagar Haveli Perfumes & Aromatics | +917506551149 | Mumbai, India | 230 | 58 | Inquiry |
| HJ AROCHEM | +91-8690768060 +91-9724420086 | Ahmedabad, India | 171 | 58 | Inquiry |
| Mruchem | +91-8087147166 +91-8087147166 | Gujarat, India | 52 | 58 | Inquiry |
| Eco Organics | +91-9412251810 +91-9720999980 | Uttar Pradesh, India | 23 | 58 | Inquiry |
| U K Aromatics And Chemicals | +91-9820021461 +91-7057388635 | Maharashtra, India | 29 | 58 | Inquiry |
| Garuda Chemicals | +91-8097853976 +91-8097853975 | Maharashtra, India | 58 | 58 | Inquiry |
| Neelam Aqua & Speciality Chem. (P) Ltd. | +91-9829069545 +91-9829060543 | Rajasthan, India | 38 | 58 | Inquiry |
| Acme Synthetic Chemicals | 08046060410 | Mumbai, India | 51 | 58 | Inquiry |
| Lakshmi Synthesis | 08068442255Ext 604 | Nagpur, India | 20 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Rsum Industries Pvt. Ltd. | 58 |
| Nagar Haveli Perfumes & Aromatics | 58 |
| HJ AROCHEM | 58 |
| Mruchem | 58 |
| Eco Organics | 58 |
| U K Aromatics And Chemicals | 58 |
| Garuda Chemicals | 58 |
| Neelam Aqua & Speciality Chem. (P) Ltd. | 58 |
| Acme Synthetic Chemicals | 58 |
| Lakshmi Synthesis | 58 |