Benzyl cinnamate
- CAS No.
- 103-41-3
- Chemical Name:
- Benzyl cinnamate
- Synonyms
- CINNAMEIN;FEMA 2142;Benzyl ciamate;guisuanbianzhi;BENZYL CINNAMATE;Benzylcinnamoate;BENZYL CINNAMATE(P);Benzyl cinnamate,99%;BENZYL CINNAMATE(SG);Benzyl Cinnamate >
- CBNumber:
- CB7413201
- Molecular Formula:
- C16H14O2
- Molecular Weight:
- 238.28
- MOL File:
- 103-41-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/5 12:01:54
| Melting point | 34-37 °C (lit.) |
|---|---|
| Boiling point | 195-200 °C/5 mmHg (lit.) |
| Density | 1.11 |
| vapor pressure | <0.1 hPa (20 °C) |
| FEMA | 2142 | BENZYL CINNAMATE |
| refractive index | 1.4025-1.4045 |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble(lit.) |
| form | Crystalline Mass or Liquid After Melting |
| color | Clear colorless to yellow |
| Odor | aromatic odor |
| Odor Type | balsamic |
| Water Solubility | PRACTICALLY INSOLUBLE |
| Merck | 14,1130 |
| JECFA Number | 670 |
| BRN | 2051339 |
| LogP | 4.18 at 23.7℃ |
| CAS DataBase Reference | 103-41-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzyl cinnamate(103-41-3) |
| EPA Substance Registry System | Benzyl cinnamate (103-41-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H410 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 22-24/25 | |||||||||
| RIDADR | 3077 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | GD8400000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163900 | |||||||||
| Toxicity | LD50 orally in rats: 5530 mg/kg (Jenner) | |||||||||
| NFPA 704 |
|
Benzyl cinnamate price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W214205 | Benzyl cinnamate ≥98%, stabilized | 103-41-3 | 1SAMPLE-K | ₹4990.33 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W214205 | Benzyl cinnamate ≥98%, stabilized | 103-41-3 | 1KG | ₹15306.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W214205 | Benzyl cinnamate ≥98%, stabilized | 103-41-3 | 5KG | ₹53259 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W214205 | Benzyl cinnamate ≥98%, stabilized | 103-41-3 | 10KG | ₹76770.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 234214 | Benzyl cinnamate 99% | 103-41-3 | 100G | ₹3593.9 | 2022-06-14 | Buy |
Benzyl cinnamate Chemical Properties,Uses,Production
Chemical Properties
Benzyl Cinnamate occurs in balsams and balsam oils. It forms white, sweet-balsamic-smelling crystals (mp 35-36°C). Benzyl cinnamate is used as a fixative in perfumes and as a component of heavy, oriental perfumes.
Occurrence
Reported found in Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituent of copaiba balsam.
Uses
Benzyl cinnamate has been employed as internal standard during the determination of compounds commonly added to personal care products such as UV filters and antimicrobial agents in environmental samples.
Uses
Mild. sweet-balsamic and somewhat floral
odor of great tenacity. Used quite frequently in perfumery, mainly
as a fixative, and particularly in perfumes for Talcum (powders). It blends well with floral
bases, spicy fragrances and Ambre types.
Used in flavor compositions for imitation
Apricot, Cherry, Chocolate, Honey, Peach,
Pineapple, Liquor, Raspberry, Rum, Prune,
etc.
Concentration may be little more than
traces, usually about 6 ppm, except in chewing
gum: up to 125 ppm.
Production Methods
Benzyl cinnamate is produced by the direct esterification of benzyl alcohol with cinnamic acid.
Preparation
By heating benzyl chloride and excess sodium cinnamate in water to 100 to 115°C; by heating sodium cinnamate with an excess of benzyl chloride in the presence of diethylamine.
General Description
Benzyl cinnamate is widely used as a fragrance ingredient.
Hazard
Moderately toxic.
Safety Profile
Moderately toxic by ingestion. Amild allergen and skin irritant. Combustible liquid. When heated to decomposition it emits acridsmoke and irritating fumes.
Metabolism
See monograph on Benzyl alcohol (p. 1011).
Purification Methods
Recrystallise the ester to a constant melting point from 95% EtOH. It has the odour of balsam. Alternatively dissolve it in Et2O, wash it with 10% aqueous Na2CO3, H2O, dry (Na2SO4), evaporate and fractionate it under reduced pressure using a short Vigreux column (p 11). It decomposes when boiled at atmospheric pressure. [Eliel & Anderson J Am Chem Soc 74 547 1952, Bender & Zerner J Am Chem Soc 84 2550 1962, Beilstein 9 IV 2012.]
Benzyl cinnamate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Silverline Chemicals | +91-9810339289 +91-9810339289 | Haryana, India | 71 | 58 | Inquiry |
| A.B.ENTERPRISES | +91-9223381464 +91-9223381464 | Maharashtra, India | 78 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Pharmaffiliates Analytics and Synthetics P. Ltd | +91-172-5066494 | Haryana, India | 6773 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| Khushi Chemworth | 08048372766Ext 769 | Vadodara, India | 72 | 58 | Inquiry |
| S H Kelkar and Company Limited | 91-22-22069609 | Maharashtra, India | 62 | 58 | Inquiry |
| Omkar fine organics pvt Ltd. | 91-413-2661301 | Tamil Nadu, India | 87 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Silverline Chemicals | 58 |
| A.B.ENTERPRISES | 58 |
| Clearsynth Labs | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Pharmaffiliates Analytics and Synthetics P. Ltd | 58 |
| Triveni chemicals | 58 |
| Khushi Chemworth | 58 |
| S H Kelkar and Company Limited | 58 |
| Omkar fine organics pvt Ltd. | 58 |
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