Methyl cinnamate
- CAS No.
- 103-26-4
- Chemical Name:
- Methyl cinnamate
- Synonyms
- METHYL TRANS-CINNAMATE;METHYL 3-PHENYLACRYLATE;Methyl Cinamate;CINNAMIC ACID METHYL ESTER;FEMA 2698;Methyl cinmate;METHYL CINNAMATE;methyl cinanmate;Methyl Cimnamate;Ethyl trans-&beta
- CBNumber:
- CB5206328
- Molecular Formula:
- C10H10O2
- Molecular Weight:
- 162.19
- MOL File:
- 103-26-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/18 20:13:21
| Melting point | 33-38 °C (lit.) |
|---|---|
| Boiling point | 260-262 °C (lit.) |
| Density | 1.092 |
| vapor pressure | 0.73Pa at 25℃ |
| refractive index | 1.5771 |
| FEMA | 2698 | METHYL CINNAMATE |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly), soluble in alcohol, Propylene glycol, Mineral oil and oils. |
| form | Fused Crystalline Mass |
| color | White to light yellow |
| Specific Gravity | 1.092 |
| Odor | at 100.00 %. sweet balsam strawberry cherry cinnamon |
| Odor Type | balsamic |
| Water Solubility | insoluble |
| Merck | 14,2299 |
| JECFA Number | 658 |
| BRN | 386468 |
| InChIKey | CCRCUPLGCSFEDV-BQYQJAHWSA-N |
| LogP | 2.68 at 25℃ |
| CAS DataBase Reference | 103-26-4(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Propenoic acid, 3-phenyl-, methyl ester(103-26-4) |
| EPA Substance Registry System | Methyl cinnamate (103-26-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317 | |||||||||
| Precautionary statements | P280 | |||||||||
| Safety Statements | 22-24/25 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | GE0190000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163990 | |||||||||
| Toxicity | Moderately toxic by ingestion . The oral LD50 for rats is 2610 mg / kg . It is combustible as a liquid, and when heated to decomposition it emits acrid smoke and irritating fumes. | |||||||||
| NFPA 704 |
|
Methyl cinnamate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W269816 | Methyl cinnamate natural, ≥98%, FCC, FG | 103-26-4 | 1SAMPLE-K | ₹5347.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W269816 | Methyl cinnamate natural, ≥98%, FCC, FG | 103-26-4 | 100G | ₹18943.75 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W269816 | Methyl cinnamate natural, ≥98%, FCC, FG | 103-26-4 | 1KG | ₹101397.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 96410 | Methyl cinnamate ≥99.0% (GC) | 103-26-4 | 100G | ₹2522.23 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 80835 | Methyl cinnamate analytical standard | 103-26-4 | 250MG | ₹7079.55 | 2022-06-14 | Buy |
Methyl cinnamate Chemical Properties,Uses,Production
Description
Methyl cinnamate is the methyl ester of cinnamic acid and is a white or transparent solid with a strong, aromatic odor. It is found naturally in a variety of plants, including in fruits, like strawberry, and some culinary spices, such as Sichuan pepper and some varieties of basil. Eucalyptus olida has the highest known concentrations of methyl cinnamate (98 %) with a 2 - 6 % fresh weight yield in the leaf and twigs.
Methyl cinnamate is used in the flavor and perfume industries. The flavor is fruity and strawberry-like; and the odor is sweet, balsamic with fruity odor, reminiscent of cinnamon and strawberry.
It is known to attract males of various orchid bees, such as Aglae caerulea.
Methyl cinnamate crystals extracted using steam distillation from Eucalyptus olida.
Chemical Properties
Methyl cinnamate has a fruity, balsamic odor similar to strawberry and a corresponding sweet taste.
Occurrence
Reported found in the oil from rhizomes of Alpinia malaccensis, in the oil from leaves of Ocimum canum Sims.; in the oil of Narcissus jonquilla L.; in the oil from rhizomes of Gastrochilus panduratum Ridl.; two isomers (cis- and trans-) exist in natural. Also reported found in cranberry, guava, pineapple, strawberry fruit and jam, cinnamon leaf, Camembert cheeses, cocoa, avocado, plum, prune, cloudberry, starfruit, plum brandy, rhubarb, beli (Aegle marmelos Correa), loquat and Bourbon vanilla.
Uses
Methyl cinnamate is used as a fragrance ingredient in cosmetics and household products.
Preparation
Methyl cinnamate is synthesized by esterification of cinnamic acid with methanol using HCl as catalyst, or by adding HCl to a boiling solution of cinnamyl nitrile in methanol.
General Description
Methyl cinnamate is an important flavoring agent and fragrance ingredient. It is one of the main aroma components of basil oil, Japanese and Korean matsutake mushrooms.
Safety Profile
Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Methyl cinnamate Preparation Products And Raw materials
Raw materials
Preparation Products
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| Supplier | Advantage |
|---|---|
| HRV Global Life Sciences | 58 |
| DU Organics Pvt Ltd | 58 |
| Aamirav Ingredients And Specialties Pvt Ltd | 58 |
| U K Aromatics And Chemicals | 58 |
| A.J Chemicals | 58 |
| CHEMSWORTH | 30 |
| CLEARSYNTH LABS LTD. | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Central Drug House(P) Ltd. | 58 |
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