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METHYL ALPHA-CHLOROACRYLATE

METHYL ALPHA-CHLOROACRYLATE Structure
CAS No.
80-63-7
Chemical Name:
METHYL ALPHA-CHLOROACRYLATE
Synonyms
METHYL 2-CHLOROACRYLATE;METHYL 2-CHLORO-2-PROPENATE;Methyl 2-chloro-2-propenoate;Acryli;METHYL CHLOROACRYLATE;METHYL-A-CHLOROACRYLATE;chloro-2acrylatedemethyle;Methyl 2-chloropropenoate;METHYL ALPHA-CHLOROACRYLATE;methyl2-chloro-2-propenoate
CBNumber:
CB9436196
Molecular Formula:
C4H5ClO2
Molecular Weight:
120.53
MOL File:
80-63-7.mol
MSDS File:
SDS
Modify Date:
2024/3/14 15:18:32

METHYL ALPHA-CHLOROACRYLATE Properties

Melting point -37 °C
Boiling point 52 °C (50 mmHg)
Density 1.189
refractive index 1.442-1.444
Flash point 33 °C
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Liquid
color Clear colorless to slightly brown
EPA Substance Registry System Methyl 2-chloroacrylate (80-63-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H330-H301-H311-H314-H226
Precautionary statements  P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
Hazard Codes  T+
Risk Statements  34-26-24/25-10
Safety Statements  45-38-36/37/39-26-16
RIDADR  2927
HazardClass  6.1(a)
PackingGroup  II
HS Code  29161995

METHYL ALPHA-CHLOROACRYLATE Chemical Properties,Uses,Production

Chemical Properties

clear colorless to pale yellow liquid

Uses

Methyl 2-Chloroacrylate is used as a reagent in various coupling reactions.

General Description

Colorless liquid. Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers (e.g., aircraft glazing).

Air & Water Reactions

Insoluble in water.

Reactivity Profile

METHYL ALPHA-CHLOROACRYLATE is sensitive to prolonged exposure to light, moisture and heat. METHYL ALPHA-CHLOROACRYLATE is incompatible with oxidizers and polymerizers.

Health Hazard

METHYL ALPHA-CHLOROACRYLATE is a skin, eye, and lung irritant. The least trace on skin raises large blisters. It is also a respiratory poison; breathing the vapors can cause pulmonary edema.

Fire Hazard

Flash point data for METHYL ALPHA-CHLOROACRYLATE are not available; however, METHYL ALPHA-CHLOROACRYLATE is probably combustible.

Potential Exposure

Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers e.g., aircraft glazing). Corrosive. Lacrimator.

Shipping

UN2929 Toxic liquids, flammable, organic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, Technical Name Required.

Incompatibilities

apor may form explosive mixture with air. May hydrolyze upon contact with moisture. Incompatible with nitrates. Methyl 2-chloroacrylate is sensitive to prolonged exposure to light, moisture and heat. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and polymerizers. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). May be a polymerization hazard

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METHYL-A-CHLOROACRYLATE METHYL ALPHA-CHLOROACRYLATE METHYL CHLOROACRYLATE Methyl alpha-chloroacrylate, stabilized with hydroquinone, 98+% Methyl alpha-chloroacrylate, 98+%, stabilized with hydroquinone Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 25GR Methyl 2-Chloroacrylate (stabilized with HQ) Methyl alpha-chloroacrylate, 99%, stabilized α-Chloroacrylic acid methyl ester Methyl alpha-chloroacrylate,99%,stabilized with hydroquinone Acryli Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 2-chloro-2-propenoicacid,methylester 2-chloro-2-propenoicacimethylester 2-Chloroacrylic acid, methyl ester 2-chloroacrylicacid,methylester 2-chloro-acrylicacimethylester 2-Chloropropenoic acid, methyl ester 2-Propenoic acid, 2-chloro-, methyl ester Acrylic acid, 2-chloro-, methyl ester chloro-2acrylatedemethyle Methyl 2-chloropropenoate methyl2-chloro-2-propenoate Methylester kyseliny 2-chlorakrylove methylesterkyseliny2-chlorakrylove methylesterkyseliny2-chlorakrylove(czech) Methyl 2-Chloroacrylate (stabilized with HQ) > Methyl 2-chloroprop-2-enoate alpha-Chloroacrylic Acid Methyl Ester Methyl 2-Chloroacrylate (stabilized with hydroquinone) 80-63-7 METHYL ALPHA-CHLOROACRYLATE METHYL 2-CHLORO-2-PROPENATE METHYL 2-CHLOROACRYLATE Methyl 2-chloro-2-propenoate methyl ester 2-Chloroacrylicacid 80-63-7 monomer