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DIPHENYLCARBAZONE

DIPHENYLCARBAZONE Structure
CAS No.
538-62-5
Chemical Name:
DIPHENYLCARBAZONE
Synonyms
1,5-DIPHENYLCARBAZONE;>60%(HPLC);DIPHENYLCARBAZONE;2-Phenylhydrazide;Diphneylcarbazone;DiphenylCarbazoneGr;S-DIPHENYLCARBAZONE;TIMTEC-BB SBB008715;DIPHENYLCARBAZONE TS;Diphenylcarbazone,AR
CBNumber:
CB9678822
Molecular Formula:
C13H12N4O
Molecular Weight:
240.26
MOL File:
538-62-5.mol
Modify Date:
2023/4/23 13:52:06

DIPHENYLCARBAZONE Properties

Melting point 119-123 °C(lit.)
Boiling point 382.98°C (rough estimate)
Density 1.19±0.1 g/cm3 (20 ºC 760 Torr)
refractive index 1.6120 (estimate)
storage temp. 2-8°C
solubility DMSO (Slightly), Methanol (Slightly)
form Powder
pka 9.83±0.43(Predicted)
color Orange
Water Solubility Soluble in acetone. Insoluble in water.
Merck 14,3322
CAS DataBase Reference 538-62-5(CAS DataBase Reference)
EPA Substance Registry System Diazenecarboxylic acid, phenyl-, 2-phenylhydrazide (538-62-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Risk Statements  22-36/37/38
Safety Statements  22-24/25-36/37/39-26
RIDADR  1325
WGK Germany  3
RTECS  LQ9420000
10-21
TSCA  Yes
HS Code  29280000
NFPA 704
1
0 0

DIPHENYLCARBAZONE price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 1.03087 1,5-Diphenylcarbazone (cont. 50% Diphenylcarbazid) ACS,Reag. Ph Eur 5G ₹7160 2022-06-14 Buy
Sigma-Aldrich(India) 1.03087 1,5-Diphenylcarbazone (cont. 50% Diphenylcarbazid) ACS,Reag. Ph Eur 538-62-5 5G ₹7160 2022-06-14 Buy
Sigma-Aldrich 1.03087 1,5-Diphenylcarbazone (cont. 50% Diphenylcarbazid) ACS,Reag. Ph Eur 25G ₹32960 2022-06-14 Buy
Sigma-Aldrich(India) 1.03087 1,5-Diphenylcarbazone (cont. 50% Diphenylcarbazid) ACS,Reag. Ph Eur 538-62-5 25G ₹32960 2022-06-14 Buy
ALFA India ALF-H60336-14 Phenylazoformic acid 2-phenylhydrazide 538-62-5 25g ₹14072 2022-05-26 Buy
Product number Packaging Price Buy
1.03087 5G ₹7160 Buy
1.03087 5G ₹7160 Buy
1.03087 25G ₹32960 Buy
1.03087 25G ₹32960 Buy
ALF-H60336-14 25g ₹14072 Buy

DIPHENYLCARBAZONE Chemical Properties,Uses,Production

Chemical Properties

orange powder

Uses

Indicator

Purification Methods

It crystallises from EtOH (ca 5mL/g), and dry the orange-red needles at 50o. A commercial sample, nominally sym-diphenylcarbazone (m 154-156o) was a mixture of diphenylcarbazide and diphenylcarbazone. The former was removed by dissolving 5g of the crude material in 75mL of warm EtOH, then adding 25g Na2CO3 dissolved in 400mL of distilled water. The alkaline solution was cooled and extracted six times with 50mL portions of diethyl ether (discarded). Diphenylcarbazone was then precipitated by acidifying the alkaline solution with 3M HNO3 or glacial acetic acid. It was filtered off, air dried, and stored in the dark [Gerlach & Frazier Anal Chem 30 1142 1958]. Other impurities are phenylsemicarbazide and diphenylcarbodiazone. Impurities can be detected by chromatography [Willems et al. Anal Chim Acta 51 544 1970]. It is used for detection and estimation of Hg, Zn, Cd, Cr, Cu, Fe and Mo [Cheng et al. Handbook of Organic Analytical Reagents, Boca Baton 277 1982, Beilstein 16 H 24, 16 IV 17.]

DIPHENYLCARBAZONE Preparation Products And Raw materials

Raw materials

Preparation Products

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Diphenylcarbazone Compound with s-Diphenylcarbazide, Reagent (E)-1,5-diphenylcarbazone 1-Phenyl-2-[hydroxy(phenylazo)methylene]hydrazine PhenylazoforMic acid 2-phenylhydrazide, suitable for coloriMetric analysis 10GR (contains Diphenylcarbazide) Diphenylcarbazone  Diphenylcarbazone, for analysis DIPHENYLCARBAZONE TS DIPHENYLCARBAZONE DIPHENYLCARBAZONE R. G. DiphenylCarbazoneGr 1,5-Diphenylcarbazone(contains Diphenylcarbazide) 1,5-Diphenylcarbazone(cont.50%Diphenylcarbazid)ACS,Reag.PhEur S-DIPHENYLCARBAZONE SYM-DIPHENYLCARBAZONE PHENYLAZOFORMIC ACID 2-PHENYLHYDRAZIDE TIMTEC-BB SBB008715 Phenylazoformicacid2-phenylhydrazine Phenylazoformic acid 2-phenylhydrazide, suitable for colorimetric analysis s-DIPHENYLCARBAZONE REAGENT (ACS) 2-Phenylhydrazide Phenyldiazenecarboxylic acid (phenylazo)-formicaci2-phenylhydrazide phenyl-diazenecarboxylicaci2-phenylhydrazide phenyldiazenecarboxylicacid2-phenylhydrazide Diazenecarboxylic acid, phenyl-, 2-phenylhydrazide DIPHENYLCARBAZONECOMPOUNDWITHS-DIPHENYLCARBAZIDE,REAGENT,ACS s-Diphenylcarbazone [for Determination of Chloride in Serum] Diphenylcarbazone (contains Diphenylcarbazide) Diphenylcarbazone, ACS s-Diphenylcarbazone (Reagent for Mercury Determination) s-DIPHENYLCARBAZONE, REAGENT (ACS)s-DIPHENYLCARBAZONE, REAGENT (ACS)s-DIPHENYLCARBAZONE, REAGENT (ACS) Diphenylcarbazone, tech Diphenylcarbazone,AR Diphenylcarbazone (contains Diphenylcarbazide)> 1,5-Diphenylcarbazone Compound With 1,5-Diphenylcarbazide Diazenecarboxylic acid, 2-phenyl-, 2-phenylhydrazide 1,5-DipHenylcarbazone, Extra Pure, SLR, Fisher Chemical 1-anilino-3-phenyliminourea 1,5-Diphenylcarbazone (mixture with Diphenylcarbazide) extrapure AR, ACS DIPHENYL CARBAZONE AR/ACS 1,5-DIPHENYLCARBAZONE Diphneylcarbazone >60%(HPLC) Diphenylcarbazone-bromophene blue mixed indicator 538-62-5 C6H5NHNHCONNC6H5 C26H26N8O2 C13H12N4O C6H5NNCONHNHC6H5 IR/UV/ VIS Nitrogen Compounds Organic Building Blocks Spectroscopy Reagents Analytical Reagents Building Blocks Analytical Chromatography Product Catalog Azo/Diazo Compounds