ChemicalBook > Product Catalog >Organic Chemistry >Ethers and derivatives >Ethers, ether-alcohols, ether phenol derivatives >Decabromodiphenyl oxide

Decabromodiphenyl oxide

Decabromodiphenyl oxide Structure
CAS No.
1163-19-5
Chemical Name:
Decabromodiphenyl oxide
Synonyms
BDE-209;DECABROMODIPHENYL ETHER;DECA;DecaBDE;dbdpo;DBDE;PBDE209;PENTABROMOPHENYL ETHER;BIS(PENTABROMOPHENYL) ETHER;br55n
CBNumber:
CB9705445
Molecular Formula:
C12Br10O
Molecular Weight:
959.17
MOL File:
1163-19-5.mol
MSDS File:
SDS
Modify Date:
2024/5/8 14:48:35

Decabromodiphenyl oxide Properties

Melting point >300 °C(lit.)
Boiling point 425°C
Density 3 g/cm3
vapor pressure 0Pa at 21℃
refractive index 1.5000 (estimate)
Flash point -12 °C
storage temp. 2-8°C
solubility <0.0001mg/l
form Solid
color White to Light Brown
Water Solubility <0.1 g/100 mL at 20 ºC
BRN 2188438
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey WHHGLZMJPXIBIX-UHFFFAOYSA-N
LogP 6.625 at 25℃
CAS DataBase Reference 1163-19-5(CAS DataBase Reference)
IARC 3 (Vol. 48, 71) 1999
EPA Substance Registry System Decabromodiphenyl oxide (1163-19-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08,GHS09,GHS05
Signal word  Danger
Hazard statements  H302-H312-H318-H351-H413-H320-H341-H225-H304-H315-H336-H361d-H373-H410
Precautionary statements  P305+P351+P338-P310a-P501a-P201-P210-P273-P301+P310-P331-P370+P378-P202-P260-P264-P280-P305+P351+P338+P337+P313-P308+P313-P405-P501
Hazard Codes  Xn,Xi,N,F
Risk Statements  20/21/22-67-65-63-50/53-48/20-38-11
Safety Statements  36/37-62-61-60-16
RIDADR  3152
WGK Germany  1
RTECS  KN3525000
Hazard Note  Irritant
TSCA  Yes
HazardClass  9
PackingGroup  II
HS Code  29093031
Toxicity Review IARC: Group 3 IMEMDT 48,73,90; Animal Limited Evidence IMEMDT 48,73,90. NTP Carcinogenesis Studies (feed); Some Evidence: rat NTPTR* NTP-TR-309,86; (feed); Equivocal Evidence: mouse NTPTR* NTP-TR-309,86. Polybrominated biphenyl compounds ar

Decabromodiphenyl oxide price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 89407 BDE No 209 solution ~50?μg/mL (Isooctane:Toluene 50:50), analytical standard 1163-19-5 1ML ₹20177.1 2022-06-14 Buy
Product number Packaging Price Buy
89407 1ML ₹20177.1 Buy

Decabromodiphenyl oxide Chemical Properties,Uses,Production

Chemical Properties

Decabromodiphenyl Oxide (DBDPO) is a white to off-white or light yellow powder. Almost insoluble in all solvents. Good thermal stability. Heated to 354 ℃, weight loss 5%. It is a non-toxic and non-polluting flame retardant.

Definition

ChEBI: Decabromodiphenyl ether is a polybromodiphenyl ether that is diphenyl ether in which all of the hydrogens have been replaced by bromines. It has a role as a neurotoxin.

Application

Decabromodiphenyl oxide is an unreactive, additive flame retardant widely used for its thermal stability and its low cost in thermoplastic resins, thermoset resins, textiles and adhesives. The major applications are in high impact polystyrene, glass reinforced thermoplastic polyester and moulding resins, low density polyethylene extrusion coatings, polypropylene (homo- and copolymers), acrylonitrile butadiene styrene rubber, nylon and polyvinyl chloride.

Preparation

Decabromodiphenyl ether can be synthesized by reacting diphenyl ether with bromine in the presence of halogenated catalyst (iron powder, etc.).
The diphenyl ether is dissolved in the solvent, the catalyst is added, and then bromine is added to carry out the reaction. After the reaction, filter, wash and dry to obtain decabromodiphenyl ether. Commonly used solvents are dibromoethane, dichloroethane, dibromomethane, carbon tetrachloride, tetrachloroethane and the like.

General Description

White to off-white powder with a chemical odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Decabromodiphenyl oxide is incompatible with strong oxidizers .

Fire Hazard

Flash point data for Decabromodiphenyl oxide are not available; however, Decabromodiphenyl oxide is probably combustible.

Safety Profile

Questionable carcinogen with experimental neoplastigenic data. Experimental reproductive effects. Used as a flame retardant for thermoplastics. When heated to decomposition it emits toxic fumes of Br-. See also ETHERS and BROMIDES

Potential Exposure

It is used as a fire retardant for thermoplastics and man-made fibers.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3152 Polyhalogenated biphenyls, solid or Polyhalogenated ter- phenyls, solid, Hazard class: 9; Labels: 9-Miscellaneous hazardous material.

Incompatibilities

Incompatible with strong oxidizers (chlo- rates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Ethers have a tendency to form unstable and explosive peroxides.

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1,1’-oxybis(2,3,4,5,6-pentabromo-benzen 1,1’-oxybis[2,3,4,5,6-pentabromo-benzen Decabromodiphenyl ether solution, Decabromodiphenyl oxide Benzene, 1,1-oxybis2,3,4,5,6-pentabromo- bde no 209solution decabromodiphenyl ether solution 1,1'-Oxybis (2,3,4,5,6-pentabromobenzol) Decabromodiphenyl ester berkflamb10e br55n bromkal82-0de bromkal82-ode DECABROMODIPHYNLY OXIDE Decabromodiphenylether~Pentabromophenylether DI-PENTABROMOBENZENEETHER DECABROMINATEDDIPHENYLETHER DECABDPE Pentabromophenyl ether,98% 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenoxy)benzene Decabromodiphenyl ether ,99% PBDE 209 (Decabromodiphenylether) Decabromodiphenyl oxide 10g [1163-19-5] Decabromodiphenyl ox DECABDE (BDE-209) Bromkal 81 1,1'-Oxybis(2,3,4,5,6-pentabromobenzene) DecabroModipheny DECABROMODIPHENYL OXIDE BDE NO 209 PERBROMODIPHENYL ETHER SAYTEX 102E SAYTEX(R) 102E FLAME RETARDANT 6,6'-Oxybis(1,2,3,4,5-pentabroMobenzene) DecabroModiphenyl ether 98% PBDE 209 (Deca Pentabromophenyl ether 1,1'-oxybis(2,3,4,5,6-pentabromo)-Benzene 1,1'-oxybis(2,3,4,5,6-pentabromobenzene) 1,1'-oxybis[2,3,4,5,6-pentabromo-benzen berkflam b 10e bis(pentabromophenyl) ether bromkal83-10de de83r decabrom decabromobiphenylether decabromobiphenyloxide decabromodiphenylether(dbdpe) decabromophenylether ether,bis(pentabromophenyl) ether,decabromodiphenyl FR-10 fr300 fr300ba frp53 nci-c55287 saytex102 tardex100 DODPO FR-RDO 1 DecabromodiphenylEtherSolution,1000mg/L,1mL Decabromodiphenyl Ether@50 μg/mL in Isooctane:Toluene (50:50) Decabromodiphenyl Ether > DecabromodiphenylEtherSolution,10mg/L,5mL