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trans-Methyl crotonate

trans-Methyl crotonate  Structure
CAS No.
623-43-8
Chemical Name:
trans-Methyl crotonate
Synonyms
METHYICROTONATE;METHYL CROTONATE;Methyl-2-Crotonate;Methyl E-crotonate;MethylCrotonate>METHYL BUT-2-ENOATE;Methylcrotonate,98%;Methyl-α-crotonate;Crotonic acid methyl;Methyl crotonate 98%
CBNumber:
CB9745331
Molecular Formula:
C5H8O2
Molecular Weight:
100.12
MOL File:
623-43-8.mol
MSDS File:
SDS
Modify Date:
2023/5/25 18:01:24

trans-Methyl crotonate Properties

Melting point -42°C
Boiling point 118-120 °C (lit.)
Density 0.944 g/mL at 25 °C (lit.)
refractive index n20/D 1.423(lit.)
Flash point 40 °F
storage temp. Flammables area
form Liquid
color Clear colorless
Odor at 1.00 % in dipropylene glycol. sharp green fruity
Odor Type green
Water Solubility IMMISCIBLE
Merck 14,2597
BRN 1720292
InChI InChI=1S/C5H8O2/c1-3-4-5(6)7-2/h3-4H,1-2H3/b4-3+
InChIKey MCVVUJPXSBQTRZ-ONEGZZNKSA-N
SMILES C(OC)(=O)/C=C/C
LogP 1.316 (est)
CAS DataBase Reference 623-43-8(CAS DataBase Reference)
NIST Chemistry Reference 2-Butenoic acid, methyl ester, (E)-(623-43-8)
EPA Substance Registry System Methyl trans-crotonate (623-43-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H319
Precautionary statements  P210-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  16-26-36-9-33
RIDADR  UN 3272 3/PG 2
WGK Germany  2
RTECS  GQ5710000
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29161980
NFPA 704
3
2 0

trans-Methyl crotonate price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 139459 Methyl crotonate 98% 623-43-8 5ML ₹1742.83 2022-06-14 Buy
Sigma-Aldrich(India) 139459 Methyl crotonate 98% 623-43-8 5ML ₹1742.83 2022-06-14 Buy
Sigma-Aldrich 139459 Methyl crotonate 98% 623-43-8 100ML ₹2543.88 2022-06-14 Buy
Sigma-Aldrich(India) 139459 Methyl crotonate 98% 623-43-8 100ML ₹2543.88 2022-06-14 Buy
Sigma-Aldrich 139459 Methyl crotonate 98% 623-43-8 500ML ₹9634.25 2022-06-14 Buy
Product number Packaging Price Buy
139459 5ML ₹1742.83 Buy
139459 5ML ₹1742.83 Buy
139459 100ML ₹2543.88 Buy
139459 100ML ₹2543.88 Buy
139459 500ML ₹9634.25 Buy

trans-Methyl crotonate Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).

General Description

Methyl crotonate undergoes vinylogous aldol reaction with enolizable aldehydes in the presence of aluminum tris(2,6-di-2-naphthylphenoxide).

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Godavari Biorefineries Limited 08066085808Ext 330 Mumbai, India 15 58 Inquiry
METHYICROTONATE trans-Methyl crotonate(E) Methyl crotonate ,99% Methyl crotonate 1g [623-43-8] trans-Methyl crotonate, 98% 100GR Methyl (E)-but-2-enoate Methyl E-propene-1-carboxylate trans-Methyl crotonate (E)-2-Butenoic acid methyl ester (2E)-2-Butenoic acid methyl ester (E)-2-Butenoic acid methyl Crotonic acid methyl trans-Methyl crotonate,98% Pent-3-enoic acid Methyl ester trans-Methyl crotonate, 2-Butenoic acid Methyl ester Methyl crotonate 98% (E)-2-Butenoic acid methyl ester TRANS-METHYL CROTONATE TRANS-2-BUTENOIC ACID METHYL ESTER METHYL BUT-2-ENOATE METHYL CROTONATE CROTONIC ACID METHYL ESTER Methylcrotonate,98% Methyl-2-Crotonate 2-Butenoic acid, methyl ester, (2E)- (E)-But-2-enoicacidmethylester (E)-CH3CH=CHC(O)OCH3 (E)-Crotonic acid methyl ester Crotonic acid, methyl ester, (E)- Methyl (2E)-2-butenoate methyl (E)-2-butenoate Methyl 2-butenoate, (E)- Methyl alpha-crotonate Methyl E-crotonate Methyl trans-2-butenoate Methyl trans-crotonate trans-but-2-enoicacidmethylester MethylCrotonate> Methyl-α-crotonate Remazolam impurity 1 Remimazolam Impurity 1 Methyl crotonate (gefitinib impurity) 623-43-8 623-43-8或18707-60-3 CH3CHCHCOOCH3 623438 Building Blocks C2 to C5 Carbonyl Compounds Organic Building Blocks Esters Fine Chemical Building Blocks C2 to C5 Carbonyl Compounds Chemical Synthesis Organic Building Blocks C2 to C5 Carbonyl Compounds