브롬화 나트륨

브롬화 나트륨
브롬화 나트륨 구조식 이미지
카스 번호:
7647-15-6
한글명:
브롬화 나트륨
동의어(한글):
브롬소다;나트륨브롬화물(NABR);나트륨의브롬화물염;브로민화나트륨;브롬나트륨;브롬화나트륨;브롬화나트륨*;브롬화소다;브롬화나트륨;나트륨브롬화물;세도뉴랄;브롬나트륨;브로민화나트륨(SODIUMBROMIDE);브로민화 소듐;소듐 브로마이드 염;소듐의 브로민화 염;수용성 브로민화 소듐
상품명:
Sodium bromide
동의어(영문):
NaBr;BROMIDE;Natriumbromid;Sodium bromide (NaBr);BROMIDE STANDARD;sodium bromide solution;Hydrobromic acid sodium salt;Sedoneural;bromnatrium;SODIUM BROMID
CBNumber:
CB3181001
분자식:
NaBr
포뮬러 무게:
102.89
MOL 파일:
7647-15-6.mol

브롬화 나트륨 속성

녹는점
755 °C (lit.)
끓는 점
1390 °C
밀도
3,203 g/cm3
증기압
1 mm Hg ( 806 °C)
굴절률
1.6412
인화점
1390°C
저장 조건
Store at room temperature.
용해도
H2O: 1 M at 20 °C, 투명, 무색
물리적 상태
가루
색상
하얀색
Specific Gravity
3.21
수소이온지수(pH)
5.74 (430g/l, H2O, 22.5℃)
수용성
905g/L(20℃)
감도
Hygroscopic
최대 파장(λmax)
λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck
14,8594
BRN
3587179
Dielectric constant
6.3399999999999999
안정성
안정적인. 강산과 호환되지 않습니다. 흡습성.
InChIKey
JHJLBTNAGRQEKS-UHFFFAOYSA-M
LogP
0 at 25℃
CAS 데이터베이스
7647-15-6(CAS DataBase Reference)
NIST
Sodium bromide(7647-15-6)
EPA
Sodium bromide (7647-15-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 24/25-25-36-26-22
WGK 독일 1
RTECS 번호 VZ3150000
F 고인화성물질 3
TSCA Yes
HS 번호 28275100
유해 물질 데이터 7647-15-6(Hazardous Substances Data)
독성 LD50 orally in rats: 3.5 g/kg (Smith, Hambourger)
기존화학 물질 KE-31368
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
1
1 1

브롬화 나트륨 MSDS


Sodium bromide

브롬화 나트륨 C화학적 특성, 용도, 생산

화학적 성질

Sodiumbromide, NaBr,is a white, hygroscopic, crystalline solid with a bitter, saline taste.It is water soluble,with a melting point of 758°C (1400 OF). Sodium bromide is used in medicine as a sedative and in photography in the preparation of silver bromide emulsion on photographic plates or films.

물리적 성질

White crystalline powder or granules; saline and slight bitter taste; cubic structure; density 3.20 g/cm3; melts at 747° C; vaporizes at 1,390°C; vapor pressure 1 torr at 806°C and 5 torr at 903°; highly soluble in methanol, 16.7 g/100mL.
The dihydrate is a white crystalline solid; density 2.18 g/cm3; decomposes at 36°C; soluble in water; sparingly soluble in methanol.

출처

Sodium bromide occurs in seawater at an average concentration of 0.008%. It also is found naturally in some salt deposits. It is used in photography for preparing light-sensitive silver bromide emulsions. The salt also is used as a bleaching and disinfecting agent for water treatement in swimming pools, health spas, and hot tubs. Other uses are as a catalyst for partial oxidation of hydrocarbons, for increasing density of aqueous drillng fluids for oil wells, as an electrolyte component in sodium-halogen batteries, as a brominating agent in organic synthesis, in preparing bromide salts, and as a laboratory reagent. Sodium bromide is used in medicine as a sedative and hypnotic.

용도

Sodium Bromide is a high-tonnage chemical and one of the most important of the bromide salts (NaBr2). High-purity grades are required in the formulation of silver bromide emulsions for photography. The compound, usually in combination with hypochlorites, is used as a bleach, notably for cellulosics. The production of sodium bromide simply involves the neutralization of HBr with NaOH or with sodium carbonate or bicarbonate.

정의

ChEBI: Sodium bromide is an inorganic sodium salt having bromide as the counterion. It is a bromide salt and an inorganic sodium salt. It is used in photographic processingand in analytical chemistry.

제조 방법

Sodium bromide can be prepared by several methods. Pure salt can be made by neutralizing sodium hydroxide or sodium carbonate with hydrobromic acid. The solution is evaporated for crystallization:NaOH + HBr → NaBr + H2O NaCO3 + HBr → NaBr + CO2 + H2O
Sodium bromide can be made by passing bromine through an aqueous solution of sodium hydroxide or carbonate in the presence of a reducing agent, such as ammonia, hydrazine, activated charcoal, or Fe2+ ion. A typical method involves adding iron to bromine water to form ferrosoferric bromide, Fe[FeBr5]. This double salt is dissolved in excess water followed by addition of sodium carbonate. The product mixture is filtered and the filtrate is evaporated to crystallize sodium bromide. The overall reaction may be written as follows: 3Fe + 4Br2 + 4Na2CO3 → 8NaBr + FeCO3 + Fe2(CO3)3
Another method involves adding excess bromine to a solution of sodium hydroxide. This forms sodium bromide and bromate. The product solution is evapoated to dryness. The bromate is reduced to bromide by heating with carbon: 3Br2 + 2NaOH + H2O → NaBr + NaBrO3 + 4HBr.

일반 설명

Sodium bromide is a brominating agent mainly used in organic synthetic reactions as a bromide source.

위험도

Toxic by inhalation and ingestion.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. Incompatible with acids, alkaloidal and heavy-metal salts. When heated to decomposition it emits toxic fumes of Brand NazO. See also BROMIDES.

Purification Methods

Crystallise the bromide from water (0.86mL/g) between 50o and 0o, and dry it at 140o under vacuum (this purification may not eliminate chloride ion).

비 호환성

Sodium bromide is compatible with most non-metallic materials of construction such as polypropylene, polyethylene, fiberglass reinforced plastic (FRP), cellulose, cloth, coatings, rubbers, etc. Metals can also be used provided the sodium bromide is kept dry. If the sodium bromide becomes wet, steel will suffer general corrosion and stainless steels and aluminum will suffer pitting attack. The rates of attack will depend upon the amount of oxygen present but in general will not be rapid.

브롬화 나트륨 준비 용품 및 원자재

원자재

준비 용품

2-[3-(2H-벤조트리아졸-2-yl)-4-하이드록시페닐]에틸 메타크릴레이트 3-Azetidinecarboxylic acid 4-Chloro-2-fluorophenylboronic acid 옥타코산산 Dyclonine hydrochloride 2-브로모-6-메틸벤조산 2-브로모에틸-2-에틸-1,3-디옥소란 2-Aminopyridin-4-ol 4-아미노벤조트리플로라이드 (S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE 2-브로모-5-니트로티아졸 1,1'-SPIROBIINDANE-7,7'-DIOL (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE 스티렌옥사이드 펜에틸알코올 1-n-프로필피페라진 디하이드로브로마이드 4-(브로모메틸)-3-니트로벤조산 4-부톡시아닐린 2-BROMO-5-METHYLBENZOIC ACID 4-브로모톨루엔 2-Amino-4-chloropyridine 14-METHYLPENTADECANOIC ACID 1,3-시클로헥사디엔 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride 4-클로로피리딘-2-카복사미드 토사노 산 3-카복시-4-클로로벤질렌붕산 6-ACETHYOXY-8-METHYL-8-AZABICYCLO(3.2.1)OCTAN-3-ONE 프로베네시드 N-(테트라히드로-2-푸로일카르보닐)피페라진브롬화수소산염 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE 테트라코산산 5-브로모-8-메톡시-2-메틸-퀴놀린 3-메틸글루타르산 (R)-7,7'-BIS(DIPHENYLPHOSPHINO)-1,1'-SPIROBIINDANE (S)-1,1'-SPIROBIINDANE-7,7'-DIOL

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