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1,4-Dioxane

1,4-Dioxane

CAS:
123-91-1
MF:
C4H8O2
MW:
88.11

Properties

Melting point:
12 °C
Boiling point:
101 °C
Density 
1.034 g/mL at 25 °C(lit.)
vapor density 
3 (vs air)
vapor pressure 
27 mm Hg ( 20 °C)
refractive index 
n20/D 1.422(lit.)
Flash point:
54 °F
storage temp. 
room temp
solubility 
Soluble in acetone, alcohol, benzene, and ether (Weast, 1986). Miscible with most organic solvents (Huntress and Mulliken, 1941) including 2-methylpropanol, toluene, cychexanone, and cyclopentanone.
form 
Solution
color 
APHA: ≤20
Odor
Mild ether-like odor detectable at 0.8 to 172 ppm (mean = 12 ppm)
PH
6-8 (500g/l, H2O, 20℃)
explosive limit
1.7-25.2%(V)
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
λmax
λ: 220 nm Amax: ≤0.70
λ: 235 nm Amax: ≤0.50
λ: 250 nm Amax: ≤0.20
λ: 270 nm Amax: ≤0.10
λ: 295-400 nm Amax: ≤0.01
Merck 
14,3300
BRN 
102551
Henry's Law Constant
4.89(x 10-6 atm?m3/mol) (static headspace-GC, Welke et al., 1998)
Exposure limits
TLV-TWA 25 ppm (≈90 mg/m3) (ACGIH), 100 ppm (MSHA and OSHA); carcinogenicity: Animal Sufficient Evidence (IARC).
Dielectric constant
2.2(25℃)
Stability:
Stable. Incompatible with oxidizing agents, oxygen, halogens, reducing agents, moisture. Highly flammable - note wide explosive range. May form explosive peroxides in storage (rate of formation increased by heating, evaporation or exposure to light).
InChIKey
RYHBNJHYFVUHQT-UHFFFAOYSA-N
LogP
-0.42 at 20℃

Safety Information

Symbol(GHS) 

GHS02,GHS07,GHS08
Signal word 
Danger
Hazard statements 
H225-H304-H315-H319-H335-H340-H350-H372-H412
Precautionary statements 
P210-P273-P301+P310-P303+P361+P353-P305+P351+P338-P331
Hazard Codes 
Xn,F,T
Risk Statements 
45-46-11-36/38-48/23/24/25-65-66-40-36/37-19-41-37/38-39/23/24/25-23/24/25-48/20/22-38-22-36/37/38-10
Safety Statements 
9-16-36/37-46-45-53-7-62-26-24/25-23-S9-S46-S36/37-S16
OEL
Ceiling: 1 ppm (3.6 mg/m3) [30-minute]
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
JG8225000
8
Autoignition Temperature
180 °C
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29329990
Toxicity
LD50 in mice, rats (ml/kg): 5.7, 5.2 orally (Laug)
IDLA
500 ppm

Use

Industrial applications of 1,4-dioxane are extensive, for instance, as solvent for cellulose acetate, ethyl cellulose, benzyl cellulose, resins, oils, waxes, and some dyes; as a solvent for paper, cotton, and textile processing; and for various organic and inorganic compounds and products. it is also used in automotive coolant liquid and in shampoos and other cosmetics as a degreasing agent and as a component of paint and varnish.

94 India supplier list of "1,4-Dioxane"

  • Product Name:1,4-Dioxane, 99%
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Gujarat,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4 Dioxane
  • Products Intro:Purity: 99% | Package: 25kg;INR
  • Company Type: Manufacturer
  • Country/Region: Telangana,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 98% | Package: 20KG;INR
  • Company Type: Manufacturer
  • Country/Region: Hyderabad,INDIA
  • Product Name:1,4-Dioxane
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA

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