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1-Butyl-3-methylimidazolium hexafluorophosphate

1-Butyl-3-methylimidazolium hexafluorophosphate

CAS:
174501-64-5
MF:
C8H15F6N2P
MW:
284.18

Properties

Melting point:
6.5 °C
Boiling point:
>340°C
Density 
1.38 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.41
Flash point:
>350°C
storage temp. 
Store below +30°C.
solubility 
Acetone, Methanol
form 
Viscous Liquid
Specific Gravity
1.396
color 
Clear colorless to pale yellow
PH
5 (H2O, 20℃)
Water Solubility 
Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
14,1581
InChIKey
IXQYBUDWDLYNMA-UHFFFAOYSA-N
ECW
4.2 V

Safety Information

Symbol(GHS) 

GHS07
Signal word 
Warning
Hazard statements 
H315-H319
Precautionary statements 
P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-37/39
WGK Germany 
3
3-10
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29339900

Use

those consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs.

6 India supplier list of "1-Butyl-3-methylimidazolium hexafluorophosphate"

  • Product Name:1-Butyl-3-methylimidazoliumhexafluorophosphate
  • Products Intro:Brand:sigma aldrich | Product Number:18122 | Purity:forcatalysis,≥98.5%(T)
  • Company Type: Trader
  • Country/Region: Bangalore,INDIA
  • Product Name:1-Butyl-3-methyl-1H-imidazol-3-iumhexafluorophosphate(V)
  • Products Intro:Brand:ajchemicals | Product Number:JDH-6585 | Purity:98%
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:1-Butyl-3-methylimidazoliumHexafluorophosphate
  • Products Intro:Brand:tcichemicals | Product Number:B2320
  • Company Type: Reagent
  • Country/Region: New Delhi,INDIA
  • Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
  • Company Type: Reagent
  • Country/Region: Hyderabad,INDIA
  • Product Name:1-Butyl-3-MethylimidazoliumHexafluorophosphate(BMIMPF6)extrapure,98%
  • Products Intro:Brand:trivenichemical | Product Number:15748
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:1-butyl-3-methylimidazol-3-ium;hexafluorophosphate
  • Products Intro:Brand:thermofisher.in | Product Number:354170050 | Purity:98+%
  • Company Type: Trader
  • Country/Region: Maharashtra,INDIA
  • Product Name:1-Butyl-3-methylimidazoliumhexafluorophosphate
  • Products Intro:Brand:clearsynth | Product Number:CS-M-04686
  • Company Type: Trader
  • Country/Region: Hyderabad,INDIA
  • Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA

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