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1-Butyl-3-methylimidazolium hexafluorophosphate

1-Butyl-3-methylimidazolium hexafluorophosphate Structure
CAS No.
174501-64-5
Chemical Name:
1-Butyl-3-methylimidazolium hexafluorophosphate
Synonyms
BMIMPF6;1-butyl-3-methylimidazolium hexafluorophsphate;1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE;SKL1399;-3-methyL;ium hexafL;JACS-174501-64-5;1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPH;1-BUTYL-3-METHYL-IMIDAZOLIUM HEXAFLUOROP;Butylmethylimidazolium Hexafluorophosphate
CBNumber:
CB6203652
Molecular Formula:
C8H15F6N2P
Molecular Weight:
284.18
MOL File:
174501-64-5.mol
MSDS File:
SDS
Modify Date:
2024/7/26 17:49:17

1-Butyl-3-methylimidazolium hexafluorophosphate Properties

Melting point 6.5 °C
Boiling point >340°C
Density 1.38 g/mL at 20 °C (lit.)
refractive index n20/D 1.41
Flash point >350°C
storage temp. Store below +30°C.
solubility Acetone, Methanol
form Viscous Liquid
Specific Gravity 1.396
color Clear colorless to pale yellow
PH 5 (H2O, 20℃)
Water Solubility Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Merck 14,1581
InChIKey IXQYBUDWDLYNMA-UHFFFAOYSA-N
CAS DataBase Reference 174501-64-5(CAS DataBase Reference)
ECW 4.2 V

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  26-37/39
WGK Germany  3
3-10
TSCA  No
HazardClass  IRRITANT
HS Code  29339900
NFPA 704
1
2 1

1-Butyl-3-methylimidazolium hexafluorophosphate price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 70956 1-Butyl-3-methylimidazolium hexafluorophosphate ≥97.0% (HPLC) 174501-64-5 5G ₹9839.93 2022-06-14 Buy
Sigma-Aldrich(India) 70956 1-Butyl-3-methylimidazolium hexafluorophosphate ≥97.0% (HPLC) 174501-64-5 50G ₹15198.3 2022-06-14 Buy
Sigma-Aldrich(India) 70956 1-Butyl-3-methylimidazolium hexafluorophosphate ≥97.0% (HPLC) 174501-64-5 250G ₹41849.45 2022-06-14 Buy
Sigma-Aldrich(India) 18122 1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, ≥98.5% (T) 174501-64-5 5G ₹20773.18 2022-06-14 Buy
Sigma-Aldrich(India) 18122 1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, ≥98.5% (T) 174501-64-5 50G ₹91655.28 2022-06-14 Buy
Product number Packaging Price Buy
70956 5G ₹9839.93 Buy
70956 50G ₹15198.3 Buy
70956 250G ₹41849.45 Buy
18122 5G ₹20773.18 Buy
18122 50G ₹91655.28 Buy

1-Butyl-3-methylimidazolium hexafluorophosphate Chemical Properties,Uses,Production

Chemical Properties

Clear pale yellow oil

Uses

those consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs.

General Description

1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.

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1-Butyl-3-methylimidazolium hexafluorophosphate≥ 98.5%(HPLC) 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 1-BUTYL-3-METHYLIMIDAZOLIUM HEXFLUOROPHOSPHATE 1-Butyl-3-MethyliMidazoliuM hexafluorophosphate >=97.0% (HPLC) 1-butyl-3-methylimmidazolium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, >=98.5% (T) 1-Butyl-3-Methyl-1h-Imidazolium Hexafluorophosphate 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPH 1-Butyl-3-methylimidazolium hexafluorophosphate 97% 1-Butyl-3-methylimidazoliumhexafluorophosphate97% 1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 99% 1-n-Butyl-3-methylimidazolium hexafluorophosphate, 98+% 1-Butyl-3-methylimidazolium hexafluorophosphate ,99% Butylmethylimidazolium Hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate, 98+% 1-Butyl-3-methylimidazol-3-ium hexafluorophosphate 97% 1-Butyl-3-MethyliMidazoliuM hexafluorophosphate 25GR 1-Butyl-3-Methyl-1H-iMidazol-3-iuM hexafluorophosphate(V) 1-(But-1-yl)-3-methyl-1H-imidazol-3-ium hexafluorophosphate 97% JACS-174501-64-5 1-butyl-3-methyl-1H-imidazole-1,3-diium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate in stock Factory 1-Butyl-3-methylimidazolium Hexafluorophosphate > 1-Butyl-3-methylimidazolium hexafluorophosphate, 99%, for synthesis 1-BUTYL-3-METHYL-IMIDAZOLIUM HEXAFLUOROP ium hexafL -3-methyL SKL1399 1-Butyl-3-methyl-imidazol-3-ium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate, ≥98.5% 1-Butyl-3-methylimidazolium hexafluorophosphate, 97% (HPLC) 1-Butyl-3-Methylimidazolium Hexafluorophosphate (BMIM PF6) extrapure, 98% 1-Butyl-3-methylimidazolium hexafluorophosphate (HPLC) 1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE BMIMPF6 1-butyl-3-methylimidazolium hexafluorophsphate 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIm]PF6 1-Butyl-3-methylimidazole hexafluorophosphate 174501-64-5 C8H17F6N2P C8H15N2.F6P C8H15F6N2P C8H15N2PF6 C8H16F6N2P Imidazolium Imidazolium Compounds Ionic Liquids Imidazolium Salts (Ionic Liquids) Ionic liquid Imidazolium Compounds Imidazolium Salts (Ionic Liquids) Ionic Liquids Synthetic Organic Chemistry 174501-64-5