1-Butyl-3-methylimidazolium hexafluorophosphate
1-Butyl-3-methylimidazolium hexafluorophosphate
- CAS:
- 174501-64-5
- MF:
- C8H15F6N2P
- MW:
- 284.18
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Company Type
Properties
- Melting point:
- 6.5 °C
- Boiling point:
- >340°C
- Density
- 1.38 g/mL at 20 °C (lit.)
- refractive index
- n
20/D 1.41
- Flash point:
- >350°C
- storage temp.
- Store below +30°C.
- solubility
- Acetone, Methanol
- form
- Viscous Liquid
- Specific Gravity
- 1.396
- color
- Clear colorless to pale yellow
- PH
- 5 (H2O, 20℃)
- Water Solubility
- Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- Merck
- 14,1581
- InChIKey
- IXQYBUDWDLYNMA-UHFFFAOYSA-N
- ECW
- 4.2 V
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H315-H319
- Precautionary statements
- P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- F
- 3-10
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 29339900
Use
those consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs.
6 India supplier list of "1-Butyl-3-methylimidazolium hexafluorophosphate"
- Product Name:1-Butyl-3-methylimidazoliumhexafluorophosphate
- Products Intro:Brand:sigma aldrich | Product Number:18122 | Purity:forcatalysis,≥98.5%(T)
- Company Type: Trader
- Country/Region: Bangalore,INDIA
- Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
- Company Type: Reagent
- Country/Region: Maharashtra,INDIA
- Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
- Company Type: Reagent
- Country/Region: Hyderabad,INDIA
- Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
- Company Type: Reagent
- Country/Region: Maharashtra,INDIA
- Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
- Company Type: Reagent
- Country/Region: Maharashtra,INDIA