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Chloroacetone

Chloroacetone

CAS:
78-95-5
MF:
C3H5ClO
MW:
92.52

Properties

Melting point:
-44.5 °C
Boiling point:
120 °C (lit.)
Density 
1.162 g/mL at 25 °C (lit.)
vapor pressure 
42 hPa (20 °C)
refractive index 
n20/D 1.432(lit.)
Flash point:
82 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
Liquid
color 
Clear yellow to yellow-brown
Specific Gravity
1.162
PH
4.3 (124g/l, H2O, 20°C)
explosive limit
3.4%(V)
Water Solubility 
124 g/L (20 ºC)
Sensitive 
Lachrymatory
Merck 
14,2114
BRN 
605369
Dielectric constant
29.8(20℃)
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases. May discolour on exposure to light. STENCH.
LogP
2.7 at 20℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06,GHS09
Signal word 
Danger
Hazard statements 
H226-H301-H310+H330-H315-H319-H335-H410
Precautionary statements 
P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+,N,T,F,Xi
Risk Statements 
10-24/25-26-36/37/38-50/53
Safety Statements 
16-23-36/37/39-45-60-61-38-28A-26
RIDADR 
UN 1695 6.1/PG 1
WGK Germany 
3
RTECS 
UC0700000
8-19
Autoignition Temperature
610 °C
Hazard Note 
Irritant/Flammable/Toxic/Lachrymatory
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
HS Code 
29147000
Toxicity
LD50 (14 day) in mice, rats (mg/kg): 127, 100 orally; LC50 (1 hr) in rats (ppm): 262 by inhalation (Sargent)

Use

CHLOROACETONE turns dark and resinifies on prolonged exposure to light [Merck]. This occurred in a bottle during storage for two years on a shelf in diffused light. A few days after the bottle was moved, Chloroacetone exploded [Ind. Eng. News 9: 184(1931)]. Is stabilized by addition of 0.1% water or 0.1% CaCO3.

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