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Hexamethyleneimine

Hexamethyleneimine

CAS:
111-49-9
MF:
C6H13N
MW:
99.17

Properties

Melting point:
-37°C
Boiling point:
138 °C749 mm Hg(lit.)
Density 
0.88 g/mL at 25 °C(lit.)
vapor pressure 
7.4 mm Hg ( 21.1 °C)
refractive index 
n20/D 1.466(lit.)
Flash point:
65 °F
storage temp. 
Poison room
form 
Liquid
pka
pK1:11.07 (25°C)
color 
Clear colorless to light yellow
Odor
Ammonia-like.
explosive limit
1.6-9.9%(V)
Water Solubility 
soluble
BRN 
1084
LogP
1.7

Safety Information

Symbol(GHS) 

GHS02,GHS05,GHS06
Signal word 
Danger
Hazard statements 
H225-H300-H314-H331
Precautionary statements 
P210-P261-P264-P280-P301+P310-P305+P351+P338
Hazard Codes 
T,T+,F
Risk Statements 
10-20-25-34-28-11
Safety Statements 
26-36/37/39-45-28A-16-1
RIDADR 
UN 2493 3/PG 2
WGK Germany 
3
RTECS 
CM3150000
Autoignition Temperature
255 °C
TSCA 
Yes
HS Code 
2933 99 80
HazardClass 
3
PackingGroup 
II
Toxicity
LD50 orally in Rabbit: 410 mg/kg

Use

Hexamethyleneimine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.

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