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Lithium

Lithium

CAS:
7439-93-2
MF:
Li
MW:
6.94

Properties

Melting point:
180 °C (lit.)
Boiling point:
1342 °C (lit.)
Density 
0.534 g/mL at 25 °C (lit.)
vapor pressure 
1 hPa (723 °C)
storage temp. 
water-free area
solubility 
reacts with H2O
form 
wire
color 
Silvery
Specific Gravity
0.534
Odor
Odorless
PH Range
>12
Resistivity
9.446 μΩ-cm, 20°C
Water Solubility 
REACTS
Sensitive 
air sensitive, moisture sensitive
Merck 
13,5542
Exposure limits
ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
Stability:
Stable, but reacts violently with water.
LogP
-0.77 at 25℃

Safety Information

Symbol(GHS) 

GHS02,GHS05
Signal word 
Danger
Hazard statements 
H260-H314
Precautionary statements 
P223-P231+P232-P280-P305+P351+P338-P370+P378-P422
Hazard Codes 
Xi,C,F
Risk Statements 
36/38-34-14/15-23
Safety Statements 
8-43-45-43C-36/37/39-26
RIDADR 
UN 3264 8/PG 3
WGK Germany 
2
RTECS 
OJ5540000
10
Autoignition Temperature
179oC
TSCA 
Yes
HS Code 
2805 19 90
HazardClass 
4.3
PackingGroup 
I
Toxicity
An element used clinically as one of its salts. It is effective against both mania and depression. Despite its effectiveness, there are no clear mechanisms that have been directly related to its therapeutic effectiveness although its inhibition of the formation of inositol from inositol phosphate is thought to be important. At therapeutic concentrations, lithium causes almost no discernible psychotropic effects in healthy humans. The major complaints when the serum concentrations of the drug are carefully monitored include slight muscular weakness, thirst, and excessive urination. The major difficulty with lithium is that a fairly high concentration of the ion is needed in the blood (0.5_x0002_1.0 mmol/L) for maintenance, higher for acute mania. Toxic symptoms (which can involve many physiological symptoms) may occur, however, at doses of 1.5 mmol/L or higher. This low therapeutic index is indicative of the need for regular monitoring of lithium concentrations in the serum.

Use

Lithium has numerous industrial applications. It is used to make highenergy lithium batteries. Lithium and its aluminum alloys are used as anodes in non-aqueous solid-state batteries. Also, many of its salts are used as electrolytes in these batteries. Another major application is in metallurgy. Lithium is alloyed with lead, magnesium, aluminum and other metals. Its alloy Bahnmetall is used for wheel bearings in railroad cars, and its magnesium alloy is used in aerospace vehicles. Probably the most important applications of lithium are in preparative chemistry. It is the starting material to prepare lithium hydride, amide, nitride, alkyls and aryls. Lithium hydrides are effective reducing agents. The alkyls are used in organic syntheses.

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Lithium carbonateMineral oilLithium nitrateLithium fluorideLidocaine hydrochlorideLithium hydroxide monohydrateLithium bromiden-ButyllithiumLithiumLithium Aluminum HydrideLithium chloride
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