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METHYLPHOSPHONIC DICHLORIDE

METHYLPHOSPHONIC DICHLORIDE

CAS:
676-97-1
MF:
CH3Cl2OP
MW:
132.91

Properties

Melting point:
31-34 °C
Boiling point:
163 °C(lit.)
Density 
1.468 g/mL at 25 °C(lit.)
vapor pressure 
760 mm Hg ( 163 °C)
Flash point:
>110°C
solubility 
Acetonitrile (Slightly), Chloroform
form 
solid
Water Solubility 
Soluble in water.
Sensitive 
Moisture Sensitive
BRN 
1071305
Stability:
Stable, but may decompose in the presence of water or moisture. Incompatible with water, strong bases, strong oxidizing agents.

Safety Information

Symbol(GHS) 

GHS05,GHS06
Signal word 
Danger
Hazard statements 
H314-H330
Precautionary statements 
P260-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+
Risk Statements 
14-26-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3390 6.1/PG 1
WGK Germany 
3
RTECS 
TA1840000
10
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I

Use

Methylphosphonic dichloride [676-97-1] M 132.9, m 33o, 33-37o, b 53-54o/10mm, 64-6 7o/20.5mm, 86o/44mm, 162o/760mm, d 4 1.4382. Fractionally redistil it until the purity as checked by hydrolysis and acidimetry for Clis correct and the distillate should solidify on cooling. [Kinnear & Perren J Chem Soc 3437 1952, Crofts & Kosolapoff J Am Chem Soc 75 3379 1952, for IR see McIvor et al. Can J Chem 34 1611 1956, Beilstein 4 IV 3509.]

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