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NICKEL CARBONYL
NICKEL CARBONYL
- CAS:
- 13463-39-3
- MF:
- C4NiO4
- MW:
- 170.73
Properties
- Melting point:
- -19°C
- Boiling point:
- 43°C
- Density
- 1,32 g/cm3
- vapor pressure
- 321 mmHg at 20 °C
- Flash point:
- <-20°C
- solubility
- insoluble in H2O; soluble in ethanol, benzene,acetone, ctc
- form
- liquid
- color
- colorless
- Odor
- Sooty odor detectable at 0.5 to 3 ppm
- Water Solubility
- soluble in ~5000 parts air free H2O; soluble alcohol, benzene, chloroform, acetone, CCl4 [MER06]
- Sensitive
- heat sensitive
- Exposure limits
- TLV-TWA: 0.05 ppm (0.35 mg as Ni/m3)
(ACGIH)
PEL: 0.001 ppm (0.007 mg Ni/m3) (OSHA, MSHA and NIOSH)
IDLH: 0.001 ppm (NIOSH, OSHA).
- Stability:
- Stable. Highly flammable and highly reactive. Explosion hazard.
Safety Information
- Symbol(GHS)
GHS05,GHS07
- Signal word
- Danger
- Hazard statements
- H314-H335
- Precautionary statements
- P501-P261-P271-P264-P280-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P233-P405
- Hazard Codes
- F,T+,N
- Risk Statements
- 11-26-40-50/53-61
- Safety Statements
- 45-53-60-61
- RIDADR
- 1259
- OEB
- E
- OEL
- TWA: 0.001 ppm (0.007 mg/m3)
- Autoignition Temperature
- Explodes above 60 °C
- HazardClass
- 6.1(a)
- PackingGroup
- I
- Toxicity
- LD50 in rats (mg/kg): 39 i.p.; 63 s.c.; 66 i.v. (Hackett, Sunderman)
- IDLA
- 2 ppm
Use
The acute toxicity of nickel carbonyl by inhalation is high. Acute toxic effects occur in two stages, immediate and delayed. Headache, dizziness, shortness of breath, vomiting, and nausea are the initial symptoms of overexposure; the delayed effects (10 to 36 h) consist of chest pain, coughing, shortness of breath, bluish discoloration of the skin, and in severe cases, delirium, convulsions, and death. Recovery is protracted and characterized by fatigue on slight exertion. Nickel carbonyl is not regarded as having adequate warning properties. Repeated or prolonged exposure to nickel carbonyl has been associated with an increased incidence of cancer of the lungs and sinuses. Nickel carbonyl is listed by IARC in Group 2B ("possible human carcinogen"), is listed by NTP as "reasonably anticipated to be a carcinogen," and is classified as a "select carcinogen'' under the criteria of the OSHA Laboratory Standard.
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