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Sodium m-arsenite

Sodium m-arsenite

CAS:
7784-46-5
MF:
AsO2.Na
MW:
129.91

Properties

Melting point:
817 °C(lit.)
Boiling point:
613 °C(lit.)
Density 
5.727 g/mL at 25 °C(lit.)
storage temp. 
Store at +15°C to +25°C.
solubility 
H2O: soluble
form 
powder
color 
off-white to gray
PH
9.3 (H2O, 20°C)
Water Solubility 
Miscible with water. Slightly miscible with alcohol.
Merck 
13,8651
Stability:
Stable. Incompatible with strong oxidizing agents, strong acids. Protect from moisture. Absorbs carbon dioxide from air.

Safety Information

Symbol(GHS) 

GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H301+H331-H350-H410
Precautionary statements 
P201-P202-P261-P273-P301+P310-P304+P340+P311
Hazard Codes 
T,N
Risk Statements 
23/25-50/53-51/53-45-52/53-22-23/24/25-21-34
Safety Statements 
20/21-28-45-60-61-53-36/37-36/37/39-26
RIDADR 
UN 1558 6.1/PG 2
WGK Germany 
3
RTECS 
CG0525000
10
TSCA 
Yes
HS Code 
2842 90 80
HazardClass 
8
PackingGroup 
III
Toxicity
LD50 orally in rats: 0.041 g/kg (Smyth)

Use

Sodium m-arsenite may burn but does not ignite readily. When heated Sodium m-arsenite emits toxic fumes of arsenic and sodium oxide. Slowly converted in solution to arsenates by atmospheric oxygen; in dry state Sodium m-arsenite is decomposed by carbon dioxide.

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