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Tris(triphenylphosphine)rhodiu

Tris(triphenylphosphine)rhodiu

CAS:
14694-95-2
MF:
C54H45ClP3Rh
MW:
925.21

Properties

Melting point:
245-250 °C (dec.)
Boiling point:
>170°C
Density 
1.363; d 1.379
vapor pressure 
0Pa at 25℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form 
Crystalline Powder
color 
Red-brown to maroon
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Sensitive 
air sensitive
Merck 
14,9758
BRN 
4581440
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey
QEYYHUJFSQCTAE-UHFFFAOYSA-M
LogP
5.69 at 20℃

Safety Information

Symbol(GHS) 

GHS07
Signal word 
Warning
Hazard statements 
H317-H413
Precautionary statements 
P261-P272-P273-P280-P302+P352-P333+P313
Hazard Codes 
C,Xi
Risk Statements 
34-36/38
Safety Statements 
22-24/25-37/39-28A-26-15-45-36/37/39
RIDADR 
1759
WGK Germany 
1
8-10-23
TSCA 
Yes
HS Code 
28439090

Use

Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.

17 India supplier list of "Tris(triphenylphosphine)rhodiu"

  • Product Name:Rhodium(I) tris(triphenylphosphine)
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Gujarat,INDIA
  • Product Name:Chlorotris-(triphenylphosphino)-rhodium
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Hyderabad,INDIA
  • Product Name:Chlorotris-(triphenylphosphino)-rhodium
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:Chlorotris-(triphenylphosphino)-rhodium
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)CHLORIDE
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:Chlorotris-(triphenylphosphino)-rhodium
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg And 1MT
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:Tris(triphenylphosphine)rhodium(I) chloride
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Mumbai,INDIA
  • Product Name:Tris(triphenylphosphine)rhodium(I)chloride
  • Products Intro:Brand:sigma aldrich | Product Number:199982
  • Company Type: Trader
  • Country/Region: Bangalore,INDIA
  • Product Name:Chlorotris(triphenylphosphine)rhodium(I) 98%
  • Products Intro:Brand:Glrinnovations | OriginalID:GLR19.013721
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:Tris(triphenylphosphine)rhodiu
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA

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