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Arsenic(III) oxide

Arsenic(III) oxide

CAS:
1327-53-3
MF:
As2O3
MW:
197.84

Properties

Melting point:
312.3 °C
Boiling point:
465°C
Density 
3,738 g/cm3
vapor pressure 
0.033Pa at 25℃
Flash point:
465°C subl.
storage temp. 
Poison room
solubility 
37 g/L (20°C)
form 
Powder
Specific Gravity
3.738
color 
White
Water Solubility 
37 g/L (20 ºC)
Merck 
14,804
crystal system
Monoclinic
Space group
P21/n
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.79920.46450.91159078.3900.3313

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H300-H314-H318-H350-H400-H410
Precautionary statements 
P260h-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Hazard Codes 
T+,N
Risk Statements 
45-28-34-50/53
Safety Statements 
53-45-60-61
RIDADR 
UN 1561 6.1/PG 2
WGK Germany 
3
RTECS 
CG3325000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
28112990
Toxicity
LD50 in mice, rats (mg/kg): 39.4, 15.1 orally (Harrison)

Use

Arsenic(III) oxide reacts vigorously with fluorine at ordinary temperatures [Mellor 9:34 1946-47]. Dissolves in aqueous acids. Incompatible with tannic acid, infusions of cinchona and other vegetable astringent infusions and decoctions, and with iron in solution [Merck].

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