Linalyl acetate
Linalyl acetate
- CAS:
- 115-95-7
- MF:
- C12H20O2
- MW:
- 196.29
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Company Type
Properties
- Melting point:
- 85°C
- Boiling point:
- 220 °C(lit.)
- Density
- 0.901 g/mL at 25 °C(lit.)
- vapor density
- 6.8 (vs air)
- vapor pressure
- 0.1 mm Hg ( 20 °C)
- refractive index
- n
20/D 1.453(lit.)
- Flash point:
- 194 °F
- storage temp.
- -20°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- Odor
- at 100.00 %. sweet green citrus bergamot lavender woody
- Odor Type
- herbal
- Water Solubility
- 499.8mg/L(25 ºC)
- Merck
- 14,5496
- JECFA Number
- 359
- BRN
- 1724500
- InChIKey
- UWKAYLJWKGQEPM-LBPRGKRZSA-N
- LogP
- 3.9 at 25℃
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H315-H317-H319
- Precautionary statements
- P261-P264-P272-P280-P302+P352-P305+P351+P338
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-38
- Safety Statements
- 26-36-37-24/25
- RIDADR
- NA 1993 / PGIII
- WGK Germany
- 1
- RTECS
- RG5910000
- HS Code
- 29153900
- Toxicity
- LD50 orally in Rabbit: 13934 mg/kg
Use
Linalyl acetate is synthesized by two methods: 1) Esterification of linalool requires special reaction conditions since it tends to undergo dehydration and cyclization as it is an unsaturated tertiary alcohol. These reactions can be avoided as follows: esterification with ketene in the presence of an acidic esterification catalyst below 30 °C results in the formation of linalyl acetate without any by-products. Esterification can be achieved in good yield, with boiling acetic anhydride, whereby the acetic acid is distilled off as it is formed; a large excess of acetic anhydride must be maintained by continuous addition of anhydride to the still vessel. Highly pure linalyl acetate can be obtained by transesterification of tert-butyl acetate with linalool in the presence of sodium methylate and by continuous removal of the tert-butanol formed in the process. 2) Dehydrolinalool, obtained by ethynylation of 6-methyl-5-hepten-2-one, can be converted into dehydrolinalyl acetatewith acetic anhydride in the presence of an acidic esterification catalyst. Partial hydrogenation of the triple bond to linalyl acetate can be carried out with, for example, palladium catalysts deactivated with lead.
49 India supplier list of "Linalyl acetate"
- Product Name:Linalyl acetate
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Reagent
- Country/Region: Telangana,INDIA
- Product Name:Linalyl acetate
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg
- Company Type: Reagent
- Country/Region: Mumbai,INDIA
- Product Name:Linalyl acetate
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
- Company Type: Reagent
- Country/Region: Haryana,INDIA
- Product Name:Linalyl acetate
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Uttar Pradesh,INDIA
- Product Name:Linalyl acetate
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
- Company Type: Reagent
- Country/Region: Uttar Pradesh,INDIA
- Product Name:Linalyl acetate
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Reagent
- Country/Region: New Delhi,INDIA
- Product Name:Linalylacetate
- Products Intro:Brand:sigma aldrich | Product Number:49599 | Purity:analyticalstandard
- Company Type: Trader
- Country/Region: Bangalore,INDIA
- Product Name:Linalyl acetate 98.00%
- Products Intro:Brand：Glrinnovations | OriginalID：GLR19.088625
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:Linalyl acetate
- Company Type: Reagent
- Country/Region: Uttar Pradesh,INDIA
- Product Name:Linalyl acetate
- Company Type: Reagent
- Country/Region: Delhi,INDIA