Methyl (triphenylphosphoranylidene)acetate
Methyl (triphenylphosphoranylidene)acetate
- CAS:
- 2605-67-6
- MF:
- C21H19O2P
- MW:
- 334.35
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Properties
- Melting point:
- 168-172 °C (lit.)
- Boiling point:
- 165～170℃
- Density
- 1.17±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Acetonitrile (Slightly), Chloroform (Slightly)
- form
- Powder
- color
- White to off-white
- Water Solubility
- insoluble
- Sensitive
- Air Sensitive
- BRN
- 618430
- InChIKey
- NTNUDYROPUKXNA-UHFFFAOYSA-N
- CAS DataBase Reference
- 2605-67-6(CAS DataBase Reference)
- EPA Substance Registry System
- Acetic acid, (triphenylphosphoranylidene)-, methyl ester (2605-67-6)
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H302-H315-H319-H335
- Precautionary statements
- P261-P305+P351+P338
- Hazard Codes
- T,Xi
- Risk Statements
- 36/37/38-25
- Safety Statements
- 22-24/25-36-26
- WGK Germany
- 3
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29319090
Use
(Methoxycarbonylmethylene)triphenylphosphorane is used in olefination reactions. Wittig reagent for the two-carbon homologation of aldehydes to ,-unsaturated esters. it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates. used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine. It is used in the preparation of (triphenylphosphoranylidene)-ketene. The Wittig reaction we performed in class involved the reaction of 2-nitrobenzaldehyde (1) with methyl (triphenylphosphoranylidene) acetate (2) to produce methyl (2E)-3-(2-nitrophenyl) acrylate (3) with a triphenylphosphine oxide (4) side product, and took place in a silica gel matrix to ensure even product dispersion for chromatography.
14 India supplier list of "Methyl (triphenylphosphoranylidene)acetate"
- Product Name:Methyl (triphenylphosphoranylidene)acetate
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:Methyltriphenylphosphoranylidene Acetate
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Hyderabad,INDIA
- Product Name:Methyl(triphenylphosphoranylidene) acetate
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Telangana,INDIA
- Product Name:Methyl 2-(triphenylphosphoranylidene)acetate
- Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Hyderabad,INDIA
- Product Name:Methyltriphenylphosphoranylidene Acetate
- Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
- Company Type: Manufacturer
- Country/Region: Hyderabad,INDIA
- Product Name:Methyl(triphenylphosphoranylidene)acetate
- Products Intro:Brand:sigma aldrich | Product Number:157929 | Purity:98%
- Company Type: Trader
- Country/Region: Bangalore,INDIA
- Product Name:Methyl (triphenylphosphoranylidene)acetate 98%
- Products Intro:Brand：Glrinnovations | OriginalID：GLRIN18009312
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:Methyl (triphenylphosphoranylidene)acetate
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:Methyl (triphenylphosphoranylidene)acetate
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:Methyl2-(triphenylphosphoranylidene)acetate
- Products Intro:Brand:ajchemicals | Product Number:JDH-32337 | Purity:98%
- Company Type: Trader
- Country/Region: New Delhi,INDIA