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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Esters >Ethyl compound >Diethyl 1,3-acetonedicarboxylate

Diethyl 1,3-acetonedicarboxylate

Diethyl 1,3-acetonedicarboxylate Structure
  • ₹2890.28 - ₹14000
  • Product name: Diethyl 1,3-acetonedicarboxylate
  • CAS: 105-50-0
  • MF: C9H14O5
  • MW: 202.2
  • EINECS:203-302-2
  • MDL Number:MFCD00009200
  • Synonyms:Diethyl 1,3-acetonedicarboxylate ,94%;Diethyl 1,3-acetonedicarboxylate ,96%;Diethyl 1,3-acetonedicarboxylate,Diethyl 3-oxoglutarate;Diethyl-3-oxo-pentan;Diethyl β-ketoglutarate;Diethyl 3-oxopentane-1,5-dioate, Diethyl acetone-1,3-dicarboxylate;Diethyl 1,3-acetonedicarboxylate, 95% 50ML;3-Oxopentanedioic acid, diethyl ester
Price4 Properties Safety Information Description
4 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)

Package

  • 25ML
  • 50G
  • 250G
  • 500ML
  • ManufacturerSigma-Aldrich(India)
  • Product number165123
  • Product descriptionDiethyl 1,3-acetonedicarboxylate 96%
  • Packaging50G
  • Price₹2890.28
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number165123
  • Product descriptionDiethyl 1,3-acetonedicarboxylate 96%
  • Packaging250G
  • Price₹6473.35
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA0055
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate min. 95.0 %
  • Packaging500ML
  • Price₹14000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA0055
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate min. 95.0 %
  • Packaging25ML
  • Price₹3000
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 165123 Diethyl 1,3-acetonedicarboxylate 96% 50G ₹2890.28 2022-06-14 Buy
Sigma-Aldrich(India) 165123 Diethyl 1,3-acetonedicarboxylate 96% 250G ₹6473.35 2022-06-14 Buy
TCI Chemicals (India) A0055 Diethyl 1,3-Acetonedicarboxylate min. 95.0 % 500ML ₹14000 2022-05-26 Buy
TCI Chemicals (India) A0055 Diethyl 1,3-Acetonedicarboxylate min. 95.0 % 25ML ₹3000 2022-05-26 Buy

Properties

Melting point :125 °C
Boiling point :250 °C (lit.)
Density :1.113 g/mL at 25 °C (lit.)
refractive index :n20/D 1.440(lit.)
Flash point :187 °F
storage temp. :Sealed in dry,2-8°C
solubility :Chloroform (Slightly), Ethyl Acetate (Slightly)
pka :9.66±0.46(Predicted)
form :Liquid
color :Clear colorless to pale yellow
Water Solubility :10 g/L (20 ºC)
Sensitive :Moisture Sensitive
BRN :640146
InChIKey :ZSANYRMTSBBUCA-UHFFFAOYSA-N
CAS DataBase Reference :105-50-0(CAS DataBase Reference)
NIST Chemistry Reference :Pentanedioic acid, 3-oxo-, diethyl ester(105-50-0)
EPA Substance Registry System :Pentanedioic acid, 3-oxo-, diethyl ester (105-50-0)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

Description

Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

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Suppliers and manufacturers

SCINTELLI CLEARSYNTH LABS LTD. A.J Chemicals TCI Chemicals (India) Pvt. Ltd. Alfa Aesar Suntril Pharmaceuticals Pvt. Ltd. Sipra Lifesciences Pvt Ltd Anand Agencies Manus Aktteva Biopharma LLP Reax Chemicals