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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Esters >Ethyl compound >Diethyl azodicarboxylate

Diethyl azodicarboxylate

Diethyl azodicarboxylate Structure
  • ₹2591 - ₹22509
  • Product name: Diethyl azodicarboxylate
  • CAS: 1972-28-7
  • MF: C6H10N2O4
  • MW: 174.15
  • EINECS:217-821-7
  • MDL Number:MFCD00009103
  • Synonyms:Diazenedicarboxylic acid, diethyl ester;Diethyl (E)-1,2-diazenedicarboxylate;Diethyl diazodicarboxylate;dlethylazodicarboxylate ;Ethyl azodicarboxylate;Formic acid, azodi-, diethyl ester;DIETHYL AZODIFORMATE;Dimethyl azodicarboxyate
4 prices
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Brand

  • ALFA India
  • ottokemi

Package

  • 5gm
  • 5g
  • 25gm
  • 100gm
  • ManufacturerALFA India
  • Product numberALF-L19348-06
  • Product descriptionDiethyl azodicarboxylate, 97%
  • Packaging5g
  • Price₹2591
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 1680
  • Product descriptionDiethyl azodicarboxylate 98%
  • Packaging5gm
  • Price₹2691
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 1680
  • Product descriptionDiethyl azodicarboxylate 98%
  • Packaging25gm
  • Price₹7659
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 1680
  • Product descriptionDiethyl azodicarboxylate 98%
  • Packaging100gm
  • Price₹22509
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L19348-06 Diethyl azodicarboxylate, 97% 5g ₹2591 2022-05-26 Buy
ottokemi D 1680 Diethyl azodicarboxylate 98% 5gm ₹2691 2022-05-26 Buy
ottokemi D 1680 Diethyl azodicarboxylate 98% 25gm ₹7659 2022-05-26 Buy
ottokemi D 1680 Diethyl azodicarboxylate 98% 100gm ₹22509 2022-05-26 Buy

Properties

Melting point :6°C
Boiling point :106°C (13 mmHg)
Density :1.106
refractive index :n20/D 1.47
Flash point :85°C
storage temp. :2-8°C
solubility :Miscible with dichloromethane, diethyl ether and toluene.
form :liquid
color :Clear, orange
Sensitive :Air Sensitive
BRN :908662
Stability :Stable, but may explode if heated under confinement. May be shock sensitive. Decomposes vigorously if heated above 100 C. Incompatible with strong acids, strong bases, strong oxidizing agents, strong reducing agents. Light sensitive.
InChI :InChI=1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3
InChIKey :FAMRKDQNMBBFBR-FPLPWBNLSA-N
SMILES :N(C(OCC)=O)=NC(OCC)=O
CAS DataBase Reference :1972-28-7(CAS DataBase Reference)
NIST Chemistry Reference :Diethyl azo diformate(1972-28-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H242 Heating may cause a fire Self-reactive substances and mixtures; and Organic peroxides Type C, D,Type E, F
Type G
Danger
Warning
GHS hazard pictograms P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.

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