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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Oxime >1,1'-(Azodicarbonyl)-dipiperidine

1,1'-(Azodicarbonyl)-dipiperidine

1,1'-(Azodicarbonyl)-dipiperidine Structure
  • ₹4000 - ₹20827.3
  • Product name: 1,1'-(Azodicarbonyl)-dipiperidine
  • CAS: 10465-81-3
  • MF: C12H20N4O2
  • MW: 252.31
  • EINECS:
  • MDL Number:MFCD00010111
  • Synonyms:Diphenylpiperidylcarboxylate;AZODICARBOXYLIC ACID DIPIPERIDYL ESTER;Azodicarboxylic;diazenedicarboxylic acid bis(N,N-piperidide);1,1-IAZODICARBONYL)DIPIPERIDINE;Azodicarboxylic acid dipiperidine,95%;1,1'-(Azodicarbonyl);1,1'-(Azodicarbonyl)dipiperidine(ADDP)
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberA1051
  • Product description1,1'-(Azodicarbonyl)dipiperidine
  • Packaging5G
  • Price₹4000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number255920
  • Product description1,1′-(Azodicarbonyl)dipiperidine 99%
  • Packaging5G
  • Price₹7642.45
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA1051
  • Product description1,1'-(Azodicarbonyl)dipiperidine
  • Packaging25G
  • Price₹16800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number255920
  • Product description1,1′-(Azodicarbonyl)dipiperidine 99%
  • Packaging25G
  • Price₹20827.3
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) A1051 1,1'-(Azodicarbonyl)dipiperidine 5G ₹4000 2022-05-26 Buy
Sigma-Aldrich(India) 255920 1,1′-(Azodicarbonyl)dipiperidine 99% 5G ₹7642.45 2022-06-14 Buy
TCI Chemicals (India) A1051 1,1'-(Azodicarbonyl)dipiperidine 25G ₹16800 2022-05-26 Buy
Sigma-Aldrich(India) 255920 1,1′-(Azodicarbonyl)dipiperidine 99% 25G ₹20827.3 2022-06-14 Buy

Properties

Melting point :132-136 °C(lit.)
Boiling point :366.4±25.0 °C(Predicted)
Density :1.29±0.1 g/cm3(Predicted)
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
solubility :DMSO (Slightly), Methanol (Slightly)
form :solid
pka :-0?+-.0.20(Predicted)
color :yellow
Water Solubility :Slightly soluble in water.
BRN :261917
InChI :InChI=1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2
InChIKey :OQJBFFCUFALWQL-UHFFFAOYSA-N
SMILES :N(C(N1CCCCC1)=O)=NC(N1CCCCC1)=O
CAS DataBase Reference :10465-81-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

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