Welcome to chemicalbook!
400-158-6606
Try our best to find the right business for you.
Do not miss inquiry messages Please log in to view all inquiry messages.

Welcome back!

ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Oxime >Di-tert-Butyl azodicarboxylate

Di-tert-Butyl azodicarboxylate

Di-tert-Butyl azodicarboxylate Structure
  • ₹3160.9 - ₹12654.43
  • Product name: Di-tert-Butyl azodicarboxylate
  • CAS: 870-50-8
  • MF: C10H18N2O4
  • MW: 230.26
  • EINECS:212-796-9
  • MDL Number:MFCD00015001
  • Synonyms:Di-tert-butyl azodicarboxylate SynonyMs Azodicarboxylic acid di-tert-butyl ester;Bis(1,1-dimethylethyl)azodicarboxylate;NSC 109889;DI-TERT-BUTYL AZODICARBOXYALTE;Di-tert-butyl azodicarboxylate, 98% 5GR;Di-Tert-ButylAzodicarboxylate(Dbad);Di-(tert-butyl) diazene-1,2-dicarboxylate 98%;Di-tert-butyl azodicarboxylate purum, >=98.0% (GC)
6 prices
Selected condition:

Brand

  • ALFA India
  • Sigma-Aldrich(India)

Package

  • 5g
  • 25g
  • ManufacturerALFA India
  • Product numberALF-L00294-14
  • Product descriptionDi-tert-butyl azodicarboxylate, 98%
  • Packaging25g
  • Price₹12302
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L00294-06
  • Product descriptionDi-tert-butyl azodicarboxylate, 98%
  • Packaging5g
  • Price₹3262
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number11625
  • Product descriptionDi-tert-butyl azodicarboxylate purum, ≥98.0% (GC)
  • Packaging25G
  • Price₹12654.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number135992
  • Product descriptionDi-tert-butyl azodicarboxylate 98%
  • Packaging25G
  • Price₹11149.75
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number11625
  • Product descriptionDi-tert-butyl azodicarboxylate purum, ≥98.0% (GC)
  • Packaging5G
  • Price₹4438.25
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number135992
  • Product descriptionDi-tert-butyl azodicarboxylate 98%
  • Packaging5G
  • Price₹3160.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L00294-14 Di-tert-butyl azodicarboxylate, 98% 25g ₹12302 2022-05-26 Buy
ALFA India ALF-L00294-06 Di-tert-butyl azodicarboxylate, 98% 5g ₹3262 2022-05-26 Buy
Sigma-Aldrich(India) 11625 Di-tert-butyl azodicarboxylate purum, ≥98.0% (GC) 25G ₹12654.43 2022-06-14 Buy
Sigma-Aldrich(India) 135992 Di-tert-butyl azodicarboxylate 98% 25G ₹11149.75 2022-06-14 Buy
Sigma-Aldrich(India) 11625 Di-tert-butyl azodicarboxylate purum, ≥98.0% (GC) 5G ₹4438.25 2022-06-14 Buy
Sigma-Aldrich(India) 135992 Di-tert-butyl azodicarboxylate 98% 5G ₹3160.9 2022-06-14 Buy

Properties

Melting point :89-92 °C(lit.)
Boiling point :287.1±9.0 °C(Predicted)
Density :1.06±0.1 g/cm3(Predicted)
storage temp. :2-8°C
solubility :Chloroform (Sparingly), Methanol (Slightly)
form :Crystals or Crystalline Powder
color :Yellow
Water Solubility :Insoluble
Sensitive :Light Sensitive
BRN :1911434
InChI :InChI=1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3
InChIKey :QKSQWQOAUQFORH-VAWYXSNFSA-N
SMILES :N(C(OC(C)(C)C)=O)=NC(OC(C)(C)C)=O
CAS DataBase Reference :870-50-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning GHS hazard pictograms P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger GHS hazard pictograms
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

Description

Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions.

Related product price