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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Silane >Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide Structure
  • ₹2299 - ₹26028
  • Product name: Sodium bis(trimethylsilyl)amide
  • CAS: 1070-89-9
  • MF: C6H18NNaSi2
  • MW: 183.37
  • EINECS:213-983-8
  • MDL Number:MFCD00009835
  • Synonyms:N-SODIUMHEXAMETHYLDISILAZANE;HEXAMETHYLDISILAZANE SODIUM SALT;HMN NA SALT;1,1,1,3,3,3-HEXAMETHYLDISILAZANE SODIUM SALT;SODIUM BIS(TRIMETHYLSILYL)AMIDE, ~1 M IN THF;SODIUM BIS(TRIMETHYLSILYL)AMIDE SOL., ~0 .6 M IN TOLUENE;SODIUM BIS(TRIMETHYLSILYL)AMIDE, 1.0M SO LUTION IN TETRAHYDROFURAN;SODIUM BIS(TRIMETHYLSILYL)AMIDE, 0.6M SO LUTION IN TOLUENE
Price19 Properties Safety Information Description
19 prices
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Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ALFA India
  • ottokemi

Package

  • 2g
  • 5G
  • 10g
  • 25G
  • 50g
  • 100G
  • 100ML
  • 4X25ML
  • 4X100ML
  • 500ML
  • 800ML
  • ManufacturerSigma-Aldrich(India)
  • Product number235083
  • Product descriptionSodium bis(trimethylsilyl)amide 95%
  • Packaging100G
  • Price₹25958.35
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number368059
  • Product descriptionSodium bis(trimethylsilyl)amide solution 0.6?M in toluene
  • Packaging800ML
  • Price₹19723.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number245585
  • Product descriptionSodium bis(trimethylsilyl)amide solution 1.0?M in THF
  • Packaging4X100ML
  • Price₹17928.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number245585
  • Product descriptionSodium bis(trimethylsilyl)amide solution 1.0?M in THF
  • Packaging800ML
  • Price₹12676.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number80631
  • Product descriptionSodium bis(trimethylsilyl)amide solution 40% in THF
  • Packaging500ML
  • Price₹12355.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number245585
  • Product descriptionSodium bis(trimethylsilyl)amide solution 1.0?M in THF
  • Packaging4X25ML
  • Price₹12103
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number235083
  • Product descriptionSodium bis(trimethylsilyl)amide 95%
  • Packaging25G
  • Price₹9168.78
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number771546
  • Product descriptionSodium bis(trimethylsilyl)amide solution 0.5?M in methyl tert-butyl ether
  • Packaging100ML
  • Price₹6490.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number368059
  • Product descriptionSodium bis(trimethylsilyl)amide solution 0.6?M in toluene
  • Packaging100ML
  • Price₹6251
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number245585
  • Product descriptionSodium bis(trimethylsilyl)amide solution 1.0?M in THF
  • Packaging100ML
  • Price₹2874.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number235083
  • Product descriptionSodium bis(trimethylsilyl)amide 95%
  • Packaging5G
  • Price₹2868.63
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberH0894
  • Product descriptionSodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L)
  • Packaging500ML
  • Price₹13800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberH0894
  • Product descriptionSodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L)
  • Packaging100ML
  • Price₹3700
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-033505-18
  • Product descriptionSodium bis(trimethylsilyl)amide, 98%
  • Packaging50g
  • Price₹26028
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L13352-AP
  • Product descriptionSodium bis(trimethylsilyl)amide, 2M soln. in THF
  • Packaging500mL
  • Price₹12938
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-033505-09
  • Product descriptionSodium bis(trimethylsilyl)amide, 98%
  • Packaging10g
  • Price₹8431
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 235083 Sodium bis(trimethylsilyl)amide 95% 100G ₹25958.35 2022-06-14 Buy
Sigma-Aldrich(India) 368059 Sodium bis(trimethylsilyl)amide solution 0.6?M in toluene 800ML ₹19723.9 2022-06-14 Buy
Sigma-Aldrich(India) 245585 Sodium bis(trimethylsilyl)amide solution 1.0?M in THF 4X100ML ₹17928.4 2022-06-14 Buy
Sigma-Aldrich(India) 245585 Sodium bis(trimethylsilyl)amide solution 1.0?M in THF 800ML ₹12676.2 2022-06-14 Buy
Sigma-Aldrich(India) 80631 Sodium bis(trimethylsilyl)amide solution 40% in THF 500ML ₹12355.7 2022-06-14 Buy
Sigma-Aldrich(India) 245585 Sodium bis(trimethylsilyl)amide solution 1.0?M in THF 4X25ML ₹12103 2022-06-14 Buy
Sigma-Aldrich(India) 235083 Sodium bis(trimethylsilyl)amide 95% 25G ₹9168.78 2022-06-14 Buy
Sigma-Aldrich(India) 771546 Sodium bis(trimethylsilyl)amide solution 0.5?M in methyl tert-butyl ether 100ML ₹6490.4 2022-06-14 Buy
Sigma-Aldrich(India) 368059 Sodium bis(trimethylsilyl)amide solution 0.6?M in toluene 100ML ₹6251 2022-06-14 Buy
Sigma-Aldrich(India) 245585 Sodium bis(trimethylsilyl)amide solution 1.0?M in THF 100ML ₹2874.9 2022-06-14 Buy
Sigma-Aldrich(India) 235083 Sodium bis(trimethylsilyl)amide 95% 5G ₹2868.63 2022-06-14 Buy
TCI Chemicals (India) H0894 Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L) 500ML ₹13800 2022-05-26 Buy
TCI Chemicals (India) H0894 Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L) 100ML ₹3700 2022-05-26 Buy
ALFA India ALF-033505-18 Sodium bis(trimethylsilyl)amide, 98% 50g ₹26028 2022-05-26 Buy
ALFA India ALF-L13352-AP Sodium bis(trimethylsilyl)amide, 2M soln. in THF 500mL ₹12938 2022-05-26 Buy
ALFA India ALF-033505-09 Sodium bis(trimethylsilyl)amide, 98% 10g ₹8431 2022-05-26 Buy
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Properties

Melting point :171-175 °C (lit.)
Boiling point :67°C
Density :0.904 g/mL at 25 °C
Flash point :43 °F
storage temp. :2-8°C
solubility :Soluble in hexane, toluene, ether,terahydrofuran, benzene and toluene.
form :Liquid
Specific Gravity :0.9
color :Clear orange to brown
Water Solubility :reacts
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3629917
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) CAS DataBase Reference :1070-89-9(CAS DataBase Reference)
EPA Substance Registry System :Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt (1070-89-9)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

Sodium bis(trimethylsilyl)amide is useful for the generation of carbenes, the amination of sulfonamides, and for the preparation of lanthanide complexes. It is significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis. It is used to deprotonate ketones and esters to generate enolate derivatives, phosphonium salts, generating Wittig reagents.

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Suppliers and manufacturers

GLR Innovations SURVIVAL TECHNOLOGIES LIMITED VASISTA LIFE SCIENCES PRIVATE LIMITED Oceanic Pharmachem Pvt Ltd JLS Laboratories Pvt Limited AMINO ORGANICS JSK Chemicals BASF India Limited Suparna Chemicals Ltd Nasense Labs Private Limited