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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Ethers >Boron trifluoride diethyl etherate

Boron trifluoride diethyl etherate

Boron trifluoride diethyl etherate Structure
  • ₹1305 - ₹98520.01
  • Product name: Boron trifluoride diethyl etherate
  • CAS: 109-63-7
  • MF: C4H10BF3O
  • MW: 141.93
  • EINECS:203-689-8
  • MDL Number:MFCD00013194
  • Synonyms:ether,diethyl,borofluoride ;Ethyl ether, compd. with boron fluoride (BF3 1:1);ethylether,cmpdwithboronfluoride(bf3)(1:1) ;trifluoroboranediethyletherate ;trifluoroboron-diethylethercomplex ;Boron trifluoride diethyl etherate, 46.5% BF{3} min, packaged under Argon in resealable ChemSeal^t b;Boron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSealTM bottles;Ethoxy-ethanetrifluoroborane
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Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ottokemi
  • SRL

Package

  • 5ML
  • 25ML
  • 100ML
  • 4X25ML
  • 250ML
  • 500ML
  • 800ML
  • 1lt
  • 1L
  • 2500ml
  • 5lt
  • 25KG
  • ManufacturerSigma-Aldrich(India)
  • Product number8.01647
  • Product descriptionBoron trifluoride-diethyl ether complex for synthesis
  • Packaging25KG
  • Price₹98520.01
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number216607
  • Product descriptionBoron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis
  • Packaging4X25ML
  • Price₹12048.23
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number216607
  • Product descriptionBoron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis
  • Packaging800ML
  • Price₹11961.63
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number175501
  • Product descriptionBoron trifluoride diethyl etherate for synthesis
  • Packaging4X25ML
  • Price₹11615.23
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.01647
  • Product descriptionBoron trifluoride-diethyl ether complex for synthesis
  • Packaging1L
  • Price₹10890
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number175501
  • Product descriptionBoron trifluoride diethyl etherate for synthesis
  • Packaging1L
  • Price₹6321.8
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.01647
  • Product descriptionBoron trifluoride-diethyl ether complex for synthesis
  • Packaging250ML
  • Price₹5399.99
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number216607
  • Product descriptionBoron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis
  • Packaging100ML
  • Price₹3366.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number175501
  • Product descriptionBoron trifluoride diethyl etherate for synthesis
  • Packaging5ML
  • Price₹2435.63
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number175501
  • Product descriptionBoron trifluoride diethyl etherate for synthesis
  • Packaging100ML
  • Price₹2035.1
  • Updated2022-06-14
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  • ManufacturerTCI Chemicals (India)
  • Product numberB0527
  • Product descriptionBoron Trifluoride - Ethyl Ether Complex
  • Packaging25ML
  • Price₹1500
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberB0527
  • Product descriptionBoron Trifluoride - Ethyl Ether Complex
  • Packaging100ML
  • Price₹2400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB0527
  • Product descriptionBoron Trifluoride - Ethyl Ether Complex
  • Packaging500ML
  • Price₹5000
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1978
  • Product descriptionBoron trifluoride diethyl etherate 99%
  • Packaging100mL
  • Price₹1305
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1980
  • Product descriptionBoron trifluoride etherate {48-50%BF3}
  • Packaging500mL
  • Price₹3492
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1978
  • Product descriptionBoron trifluoride diethyl etherate 99%
  • Packaging1lt
  • Price₹4005
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 8.01647 Boron trifluoride-diethyl ether complex for synthesis 25KG ₹98520.01 2022-06-14 Buy
Sigma-Aldrich(India) 216607 Boron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis 4X25ML ₹12048.23 2022-06-14 Buy
Sigma-Aldrich(India) 216607 Boron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis 800ML ₹11961.63 2022-06-14 Buy
Sigma-Aldrich(India) 175501 Boron trifluoride diethyl etherate for synthesis 4X25ML ₹11615.23 2022-06-14 Buy
Sigma-Aldrich(India) 8.01647 Boron trifluoride-diethyl ether complex for synthesis 1L ₹10890 2022-06-14 Buy
Sigma-Aldrich(India) 175501 Boron trifluoride diethyl etherate for synthesis 1L ₹6321.8 2022-06-14 Buy
Sigma-Aldrich(India) 8.01647 Boron trifluoride-diethyl ether complex for synthesis 250ML ₹5399.99 2022-06-14 Buy
Sigma-Aldrich(India) 216607 Boron trifluoride diethyl etherate purified by redistillation, ≥46.5% BF3 basis 100ML ₹3366.58 2022-06-14 Buy
Sigma-Aldrich(India) 175501 Boron trifluoride diethyl etherate for synthesis 5ML ₹2435.63 2022-06-14 Buy
Sigma-Aldrich(India) 175501 Boron trifluoride diethyl etherate for synthesis 100ML ₹2035.1 2022-06-14 Buy
TCI Chemicals (India) B0527 Boron Trifluoride - Ethyl Ether Complex 25ML ₹1500 2022-05-26 Buy
TCI Chemicals (India) B0527 Boron Trifluoride - Ethyl Ether Complex 100ML ₹2400 2022-05-26 Buy
TCI Chemicals (India) B0527 Boron Trifluoride - Ethyl Ether Complex 500ML ₹5000 2022-05-26 Buy
ottokemi B 1978 Boron trifluoride diethyl etherate 99% 100mL ₹1305 2022-05-26 Buy
ottokemi B 1980 Boron trifluoride etherate {48-50%BF3} 500mL ₹3492 2022-05-26 Buy
ottokemi B 1978 Boron trifluoride diethyl etherate 99% 1lt ₹4005 2022-05-26 Buy

Properties

Melting point :−58 °C(lit.)
Boiling point :126-129 °C(lit.)
Density :1.15 g/mL(lit.)
vapor density :4.9 (vs air)
vapor pressure :4.2 mm Hg ( 20 °C)
refractive index :n20/D 1.344(lit.)
Flash point :118 °F
storage temp. :Store below +30°C.
solubility :Miscible with ether and alcohol.
form :liquid
Specific Gravity :1.126 (20/4℃)
color :brown
explosive limit :5.1-18.2%(V)
Water Solubility :Reacts
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Merck :14,1350
BRN :3909607
Exposure limits :ACGIH: TWA 0.1 ppm; Ceiling 0.7 ppm
Stability :Stable. Highly flammable. May form explosive peroxides in contact with air or oxygen. Reacts exothermically with water to form extremely flammable diethyl ether and toxic, corrosive boron trifluoride hydrates. Also incompatible with bases, amines, alkali metals.
InChIKey :MZTVMRUDEFSYGQ-UHFFFAOYSA-N
CAS DataBase Reference :109-63-7(CAS DataBase Reference)
NIST Chemistry Reference :Boron trifluoride etherate(109-63-7)
EPA Substance Registry System :Boron, trifluoro[1,1'-oxybis[ethane]]-, (T-4)- (109-63-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth?s atmosphere.

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