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tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure
  • ₹7674.93 - ₹28707.9
  • Product name: tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • CAS: 112741-49-8
  • MF: C21H23NO4
  • MW: 353.41
  • EINECS:
  • MDL Number:MFCD00074955
  • Synonyms:CIVENTICHEM CV-2653;CIVENTICHEM CV-2654;TERT-BUTYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE;N-TERT-BUTOXYCARBONYL-(2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE;N-BOC(2R, 3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE;tert-butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morph;TERT-BUTYL (2R,3S)-(-)-6-OXO-2,3-DIPHENY L-4-MORPHOLINECARBOXYLATE, 99% (99% EE);(2R,3S)-6-Oxo-2,3-diphenyl-morpholine-4-carboxylic acid tert-butyl ester
Price2 Properties Safety Information Description
2 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number331848
  • Product description(2R,3S)-(−)-N-Boc-6-oxo-2,3-diphenylmorpholine 98%
  • Packaging1G
  • Price₹7674.93
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number331848
  • Product description(2R,3S)-(−)-N-Boc-6-oxo-2,3-diphenylmorpholine 98%
  • Packaging5G
  • Price₹28707.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 331848 (2R,3S)-(−)-N-Boc-6-oxo-2,3-diphenylmorpholine 98% 1G ₹7674.93 2022-06-14 Buy
Sigma-Aldrich(India) 331848 (2R,3S)-(−)-N-Boc-6-oxo-2,3-diphenylmorpholine 98% 5G ₹28707.9 2022-06-14 Buy

Properties

Melting point :206 °C (dec.)(lit.)
alpha :-87 º (c=5.5 in methylene chloride)
Boiling point :509.6±50.0 °C(Predicted)
Density :1.175±0.06 g/cm3(Predicted)
storage temp. :2-8°C
solubility :Acetone (Slightly, Heated, Sonicated), Chloroform (Slightly), DMSO (Slightly, Sonicated)
pka :-3.28±0.60(Predicted)
form :Solid
color :White to Off-White
optical activity :[α]25/D 87°, c = 5.5 in methylene chloride
InChIKey :MRUKRSQUUNYOFK-RBUKOAKNSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate is a reactant used in the preparation of (-)-Jorumycin, (-)-Renieramycin G, 3-epi-Jorumycin, and 3-epi-Renieramycin G and colla gen cross-link pyridinolines.

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