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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Chlorobis(ethylene)rhodium (I) dimer

Chlorobis(ethylene)rhodium (I) dimer

Chlorobis(ethylene)rhodium (I) dimer Structure
  • ₹12600 - ₹43711.8
  • Product name: Chlorobis(ethylene)rhodium (I) dimer
  • CAS: 12081-16-2
  • MF: C8H16Cl2Rh2
  • MW: 388.93
  • EINECS:235-145-0
  • MDL Number:MFCD00013206
  • Synonyms:mhu-dichlorotetraethylene dirhodium;Chlorobis(ethylene)rhodium dimer;Chlorobis(ethylene)r;Dichlorotetraethylene dirhodiuM(I) 100MG;RhodiuM, di-M-chlorotetrakis(h2-ethene)di-;Chlorobis(ethylene)rhodiuM(I) diMer,98% [Rh(C2H4)2Cl]2;á-Dichlorotetraethylene dirhodiuM(I);Bis[chlorobis(ethylene)rhodiuM]
3 prices
Selected condition:

Brand

  • Sigma-Aldrich
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 200MG
  • 1G
  • ManufacturerSigma-Aldrich
  • Product number656763
  • Product descriptionDi-μ-chlorotetraethylene dirhodium(I)
  • Packaging1G
  • Price₹43711.8
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC2461
  • Product descriptionChlorobis(ethylene)rhodium(I) Dimer
  • Packaging200MG
  • Price₹12600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number656763
  • Product descriptionDi-μ-chlorotetraethylene dirhodium(I)
  • Packaging1G
  • Price₹43711.8
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 656763 Di-μ-chlorotetraethylene dirhodium(I) 1G ₹43711.8 2022-06-14 Buy
TCI Chemicals (India) C2461 Chlorobis(ethylene)rhodium(I) Dimer 200MG ₹12600 2022-05-26 Buy
Sigma-Aldrich(India) 656763 Di-μ-chlorotetraethylene dirhodium(I) 1G ₹43711.8 2022-06-14 Buy

Properties

storage temp. :-20°C
solubility :Chloroform (Slightly, Heated, Sonicated), DMSO (Slightly, Heated, Sonicated), Me
form :Crystalline Powder or Chunks
color :Rust
Water Solubility :Sparingly soluble in ethanol, acetone, dioxane, chloroform and dichloromethane. Insoluble in water.
Sensitive :Air Sensitive
Exposure limits :ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 Stability :Air Sensitive
InChIKey :OOQJCPOXJFCGCR-UHFFFAOYSA-L

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Chlorobis(ethylene)rhodium(I) dimer is used as a precursor to rhodium(I) norbornadiene catalyst, which is used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. Further, it serves as an important organic intermediate. It catalyzes the dimerization of ethylene to 1-butene. It is also used in the preparation of homogeneous catalysts.

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