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methoxy(cyclooctadiene)rhodium(i) dimer

methoxy(cyclooctadiene)rhodium(i) dimer Structure
  • ₹19469.4 - ₹51193.2
  • Product name: methoxy(cyclooctadiene)rhodium(i) dimer
  • CAS: 12148-72-0
  • MF: C18H22O2Rh2
  • MW: 476.18
  • EINECS:
  • MDL Number:MFCD08457639
  • Synonyms:Di-Methoxobis(1,5-cyclooctadiene)dirhodiuM(I),Min.98%;Di-μ-Methoxobis(1,5-cyclooctadiene)dirhodiuM(I),98%;Bis(1,5-cyclooctadiene)dimethoxydirhodium;Bis(cyclooctadiene)bis(methoxy)dirhodium;Bis(eta4-1,5-cyclooctadiene)-di-mu-methoxodirhodium;Bis(eta4-1,5-cyclooctadiene)-di-mu-methoxydirhodium;Bis[(1,5-cyclooctadiene)(methanolato)rhodium];Cyclooctadiene rhodium methoxide dimer
2 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number661058
  • Product descriptionMethoxy(cyclooctadiene)rhodium(I) dimer
  • Packaging250MG
  • Price₹19469.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number661058
  • Product descriptionMethoxy(cyclooctadiene)rhodium(I) dimer
  • Packaging1G
  • Price₹51193.2
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 661058 Methoxy(cyclooctadiene)rhodium(I) dimer 250MG ₹19469.4 2022-06-14 Buy
Sigma-Aldrich(India) 661058 Methoxy(cyclooctadiene)rhodium(I) dimer 1G ₹51193.2 2022-06-14 Buy

Properties

Melting point :192-225 °C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :yellow

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

A rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.

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